• Title/Summary/Keyword: tandem structure

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Characterization of Modified Peptides by Tandem Mass Spectrometry

  • Chang, Yoon-Seok;Jang, Jung-Suk
    • Analytical Science and Technology
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    • v.8 no.4
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    • pp.849-854
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    • 1995
  • A series of biologically active phosphopeptides were synthesized and their behavior in tandem mass spectrometry have been investigated. The structure identifications of other unusual peptides such as sulphated, glycosylated, lipoidal, and backbone modified peptides have been carried out. For all tested peptides, the structural modification could be determined directly by measurement of the absolute molecular weight in combination with collision-induced-dissociation in tandem mass spectrometry.

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Emission Characteristics of Blue Fluorescence Tandem OLED Using MoOx (MoOx를 사용한 청색 형광 Tandem OLED의 발광 특성)

  • Kwak, Tea-Ho;Ju, Sung-Hoo
    • Journal of the Korean institute of surface engineering
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    • v.47 no.3
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    • pp.104-108
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    • 2014
  • To improve emission efficiency of organic light emitting devices (OLEDs), we fabricated the tandem OLED of ITO / 2-TNATA / NPB / SH-1: 3 vol.% BD-2 / Bphen / Liq / Al / $MoO_x$ (X nm) / 2-TNATA / NPB / SH-1: 3 vol.% BD-2 / Bphen / Liq / Al structure. And emission properties of single OLED and tandem OLED with $MoO_x$ thickness as charge generation layer (CGL) were measured. The current emission efficiency and quantum efficiency of tandem OLED with $MoO_x$ of 3 nm thickness were improved compare with single OLED from 7.46 cd/A and 5.39% to 22.57 cd/A and 11.76%, respectively. In case of thicker or thinner than $MoO_x$ of 3~5 nm, the current emission efficiency and quantum efficiency were decreased, because balance of electron and hole in emission layer was not matching. The driving voltage was increased from 8 V of single OLED to 15 V of tandem OLED by thickness increase of OLED. As a result, it was possible to improve the emission efficiency of OLEDs by optimized $MoO_x$ thickness.

A study on the characteristic of Dye-sensitized solar cell with mesh structure of counter electrode (Mesh구조의 상대전극을 갖는 염료감응형태양전지의 특성연구)

  • Jang, Jin-Ju;Seo, Hyun-Woong;Son, Min-Kyu;Lee, Kyoung-Jun;Hong, Ji-Tae;Kim, Hee-Je
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.10a
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    • pp.131-133
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    • 2008
  • A serious problem of the 21st century is the supply of energy resources. Reserves of fossil fuels are facing depletion: renewable energy resources must be developed in this era. Dye sensitized solar cell (DSC) has been very economical and easy method to convert solar energy to electricity. Recently a novel tandem cell structure is proposed to improve photocurrent of DSC. To fabricated a tandem cell, the mesh structure of counter electrode is essential for the improvement in transmittance. In this study, we conducted the experiment to get the characteristic of DSC with mesh counter electrode. Under the standard test condition (AM 1.5, 100mW/$cm^2$), we obtained the maximum efficiency of 3.41% and the transmittance of 72% in the DSC with mesh counter electrode.

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Structure and Characteristics of Tandem Solar Cell Composed of Dye-sensitized Solar Cell and Thermoelectric Generator (염료감응형 태양전지와 열전발전소자를 결합한 복합 태양전지의 구조 및 특성)

  • Lee, Dong-Yoon;Song, Jae-Sung;Lee, Won-Jae;Kim, In-Sung;Jeong, Soon-Jong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.4
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    • pp.357-362
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    • 2005
  • The tandem solar cell composed of a dye-sensitized solar cell (DSC) and a thermoelectric generator (TEG) was designed. In such new cell, the characteristics of DSC and TEG were investigated. DSC uses the wavelength range of 380∼750 nm and has the maximum efficiency of below 10 %. If the solar light transmitted through DSC can be converted to heat energy, TEG can generate electric energy using this heat energy. By this means, it is possible to utilize most of solar energy in the wavelength range of 350∼3000 nm for electric generation and it can be expected to obtain higher solar energy conversion efficiency exceeding the known limit of maximum efficiency. For this purpose we suggest the tandem solar cell constructed with DSC and TEG. In this structure, DSC has a carbon nanotube film as a counter electrode of DSC in order to collect the solar light and convert it to heat energy. We measured the I-V characteristics of DSC and TEG, assembled to the tandem cell. As a result, it was shown that DSC with carbon nanotube and TEG had the efficiency of 9.1 % and 6.2 %, respectively. From this results, it is expected that the tandem solar cell of the new design has the possibility of enhanced conversion efficiency to exceed above 15 %.

An efficient transcoding algorithm for AMR and G.723.1 speech coders and performance evaluation (AMR과 G.723.1 음성부호화기를 위한 효율적인 상호부호화 알고리듬 및 성능평가)

  • 최진규;윤성완;강홍구;윤대희
    • Journal of the Institute of Electronics Engineers of Korea SP
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    • v.41 no.4
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    • pp.121-130
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    • 2004
  • In the application requiring the interoperability of different networks such as VoIP and wireless communication system, two speech codecs must work together with the structure of cascaded connection, tandem. Tandem has several problems such as long delay, high complexity and quality degradation due to twice complete encoding/decoding process. Transcoding is one of the best solutions to solve these problems. Transcoding algorithm is varied with the structure of source and target coder. In this paper, transcoding algorithm including the LSP conversion, the pitch estimation and new perceptual weighting filter for reducing complexity and improving qualify is proposed. These algorithms are applied to the pair of AMR md G.723.1. By employing the proposed algorithms in the transcoder, the complexity is reduced by about 20%-58% and quality is improved compared to tandem.

Production and Amyloid fibril formation of tandem repeats of recombinant Yeast Prion like protein fragment

  • Kim, Yong-Ae;Park, Jae-Joon;Hwang, Jung-Hyun;Park, Tae-Joon
    • Journal of the Korean Magnetic Resonance Society
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    • v.15 no.2
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    • pp.175-186
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    • 2011
  • Amyloid fibrils have long been known to be the well known ${\alpha}$-helix to ${\beta}$-sheet transition characterizing the conversion of cellular to scrapie forms of the prion protein. A very short sequence of Yeast prion-like protein, GNNQQNY (SupN), is responsible for aggregation that induces diseases. KSI-fused tandem repeats of SupN vector are constructed and used to express SupN peptide in Escherichia coli (E.Coli). A method for a production, purification, and cleavage of tandem repeats of recombinant isotopically enriched SupN in E. coli is described. This method yields as much as 20 mg/L of isotope-enriched fusion proteins in minimal media. Synthetic SupN peptides and $^{13}C$ Gly labeled SupN peptides are studied by Congo Red staining, Birefringence and transmission electron microscopy to characterize amyloid fibril formation. To get a better understanding of aggregation-structure relationship of 7 residues of Yeast prion-like protein, the change of a conformational structure will be studied by $^{13}C$ solid-state nmr spectroscopy as powder of both amorphous and fibrillar forms.

Applications of Tandem Mass Spectrometry in the Structure Determination of Permethylated Sialic Acid-containing Oligosaccharides

  • Yoo, Eun-Sun;Yoon, In-Mo
    • Bulletin of the Korean Chemical Society
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    • v.26 no.9
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    • pp.1347-1353
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    • 2005
  • Sets of sialic acid-containing trisaccharides having different internal and terminal linkages have been synthesized to develop a sensitive method for analysis of the reducing terminal linkage positions. The trisaccharides, sialyl($\alpha$ 2-3)Gal($\beta$ 1-3)GalNAc and sialyl($\alpha$ 2-3)Gal($\beta$ 1-X)GlcNAc where X=3, 4 and 6, were synthesized and examined using electrospray ionization (ESI)-collision induced dissociation (CID) tandem mass spectrometry (MS/MS). The compounds chosen for this study are related to terminal groups likely to be found on polylactosamine-like glycoproteins and glycolipids which occur on the surface of mammalian cells. The purpose of this study is to develop tandem mass spectrometral methods to determine detailed carbohydrate structures on permethylated or partially methylated oligosaccharides for future applications on biologically active glycoconjugates and to exploit a faster method of synthesizing a series of structural isomeric oligosaccharides to be used for further mass spectrometry and instrumental analysis.

Noninteracting and Loop-Shaping LQ Controller Design for Tandem Cold Mills (연속 냉간압연 시스템을 위한 비간섭 루프형성 LQ제어기 설계)

  • 김종식;김철민
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.10
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    • pp.2629-2639
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    • 1994
  • A robust multivariable controller is synthesized for tandem cold mills. A blocked-noninteracting control method is applied for simplifying the structure of rolling control systems. And, a loop-shaping LQ control method is applied for maintaining the variation of the thickness and tension of each rolling stand as small as possible. In this paper, the effects of the design parameter on loop-shaping and the number of control inputs are evaluated. The simulation results show that the thickness and tension control accuracy of tandem cold mills can be improved by the blocked-noninteracting and compensated loop-shaping LQ controller.

Optimal Dynamic Operating Policies for a Tandem Queueing Service System

  • Hwang, Dong-Joon
    • Journal of the Korean Operations Research and Management Science Society
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    • v.4 no.1
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    • pp.51-67
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    • 1979
  • This paper considers the problem of determining an optimal dynamic operating policy for a two-stage tandem queueing service system in which the service facilities (or stages) can be operated at more than one service rate. At each period of the system's operation, the system manager must specify which of the available service rates is to be employed at each stage. The cost structure includes an operating cost for running each stage and a service facility profit earned when a service completion occurs at Stage 2. We assume that the system has a finite waiting capacity in front of each station and each customer requires two services which must be done in sequence, that is, customers must pass through Stage 1 and Stage 2 in that order. Processing must be in the order of arrival at each station. The objective is to minimize the total discounted expected cost in a two-stage tandem queueing service system, which we formulate as a Discrete-Time Markov Decision Process. We present analytical and numerical results that specify the form of the optimal dynamic operating policy for a two-stage tandem queueing service system.

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Characteristics of 3-dB Coupler using Broadside Slot Coupled Lines (Broadside 슬롯 결합 선로를 이용한 3 dB 결합기 특성)

  • Young Kim
    • Journal of Advanced Navigation Technology
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    • v.27 no.4
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    • pp.417-422
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    • 2023
  • This paper presents various methods for implementing 3-dB coupler using a broadside slot coupled lines and analyze its characteristics. The ideal coupler of the tandem structure is analyzed on the premise that both the reflection coefficient and the isolation coefficient of the first and second coupler connections are zero. However, since the reflection and isolation coefficients of most couplers are not zero, the S-parameter cascade calculation method was used to check how to the characteristics of the coupler change due to this. In order to confirm that these characteristics appear, a 3-dB coupler was fabricated with one stage and two and three stages of a tandem structure using a broadside slot coupled lines at a center frequency of 2 GHz, and it was confirm that the characteristics of tandem coupler change due to the non-zero reflection coefficient and isolation coefficient of the connection part of the coupler.