• Title/Summary/Keyword: tandem structure

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Towards Thermally Stable Tandem Organic Solar Cells

  • Yang, Feng;Wang, Sihan;Kim, Ji-Hwan;Kim, Yong-Sang
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.410.2-410.2
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    • 2016
  • Tandem structure is promising in organic solar cells because of its double open-circuit voltage (VOC) and efficient photon energy conversion. In a typical tandem device, the two single sub-cells are stacked and connected by an interconnecting layer. The fabrication of two sub-cells are usually carried out in a glovebox filled with nitrogen or argon gas, which makes it expensive and laborious. We report a glovebox-free fabricated inverted tandem organic solar cells wherein the tandem structure comprises sandwiched interconnecting layer based on p-doped hole-transporting, metal, and electron-transporting materials. Complete fabrication process of the tandem device was performed outside the glove box. The tandem solar cells based on poly(3-hexylthiophene) (P3HT) and (6,6)-phenyl C61-butyric acid methyl ester (PCBM) can realize a high VOC, which sums up of the two sub-cells. The tandem device structure was ITO/ZnO/P3HT:PCBM/PEDOT:PSS/MoO3/Au/Al/ZnO-d/P3HT:PCBM/PEDOT:PSS/Ag. The separate sub-cells were morphologically and thermally stable up to 160 oC. The high stability of the active layer benefits in the fabrication processes of tandem device. The performance of tandem organic solar cells comes from the sub-cells with an 50 nm thick active layer of P3HT:PCBM, achieving an average power conversion efficiency (PCE) of 2.9% (n=12) with short-circuit current density (JSC) = 4.26 mA/cm2, VOC = 1.10 V, and fill factor (FF) = 0.62. Based on these findings, we propose a new method to improve the performance and stability of tandem organic solar cells.

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Thin Film Si-Ge/c-Si Tandem Junction Solar Cells with Optimum Upper Sub- Cell Structure

  • Park, Jinjoo
    • Current Photovoltaic Research
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    • v.8 no.3
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    • pp.94-101
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    • 2020
  • This study was trying to focus on achieving high efficiency of multi junction solar cell with thin film silicon solar cells. The proposed thin film Si-Ge/c-Si tandem junction solar cell concept with a combination of low-cost thin-film silicon solar cell technology and high-efficiency c-Si cells in a monolithically stacked configuration. The tandem junction solar cells using amorphous silicon germanium (a-SiGe:H) as an absorption layer of upper sub-cell were simulated through ASA (Advanced Semiconductor Analysis) simulator for acquiring the optimum structure. Graded Ge composition - effect of Eg profiling and inserted buffer layer between absorption layer and doped layer showed the improved current density (Jsc) and conversion efficiency (η). 13.11% conversion efficiency of the tandem junction solar cell was observed, which is a result of showing the possibility of thin film Si-Ge/c-Si tandem junction solar cell.

A Study on Effects of Piston Pumping Phase on Vibration and Noises of Tandem Swash Plate Type Axial Piston Pump(1) (피스톤 펌핑 위상이 텐덤형 사판식 액셜 피스톤 펌프의 진동 ${\cdot}$ 소음에 미치는 영향에 관한 연구(1))

  • Park, Sung-Hwan;Lee, Jin-Kul
    • Journal of the Korean Society for Precision Engineering
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    • v.16 no.5 s.98
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    • pp.74-82
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    • 1999
  • To meet the needs of the hydraulic excavator of large capacity, tandem axial type piston pump which is high pressure and high speed have been developed. But inevitably we can not help facing the problem of noise at that time. In order to reduce the noise of this pump, many researchers have been studying the problem of oil distribution manner. But they are not interested in the symmetric structure of tandem type pump. So, focusing on the symmetric structure of tandem type pump, this paper analyzed unbalanced force developed in the pump chamber and verified the effect of the pumping phase of the piston on vibration and noise of the tandem axial type piston pump theoretically.

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[ $a-Si:H/{\mu}c-Si:H$ ] thin-film tandem solar cells (비정질/마이크로 탠덤 구조형 실리콘 박막 태양전지)

  • Lee, Jeong-Chul;Song, Jin-Soo;Yoon, Kyung-Hoon
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.06a
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    • pp.228-231
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    • 2006
  • This paper briefly introduces silicon based thin film solar cells: amorphous (a-Si:H), microcrystalline ${\mu}c-Si:H$ single junction and $a-Si:H/{\mu}c-Si:H$ tandem solar cells. The major difference of a-Si:H and ${\mu}c-Si:H$ cells comes from electro-optical properties of intrinsic Si-films (active layer) that absorb incident photon and generate electron-hole pairs. The a-Si:H film has energy band-gap (Eg) of 1.7-1.8eV and solar cells incorporating this wide Eg a-Si:H material as active layer commonly give high voltage and low current, when illuminated, compared to ${\mu}c-Si:H$ solar cells that employ low Eg (1.1eV) material. This Eg difference of two materials make possible tandem configuration in order to effectively use incident photon energy. The $a-Si:H/{\mu}c-Si:H$ tandem solar cells, therefore, have a great potential for low cost photovoltaic device by its various advantages such as low material cost by thin-film structure on low cost substrate instead of expensive c-Si wafer and high conversion efficiency by tandem structure. In this paper, the structure, process and operation properties of Si-based thin-film solar cells are discussed.

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Photovoltaic Properties of Tandem Structure Consisting of Quantum Dot Solar cell and Small Molecule Organic Solar cell

  • Jang, Jinwoong;Choi, Geunpyo;Yim, Sanggyu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.249.2-249.2
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    • 2015
  • Connecting two or more sub-cells is a simple and effective way of improving power conversion efficiency (PCE) of solar cells, and the theoretical efficiency of this tandem cell is known to reach 85~88% of the sum of the sub-cell's efficiencies. There are two ways of connecting sub-cells in the tandem structure, i.e. parallel and series connection. The parallel connection can increase the short circuit current (Jsc) and the series connection can increase the open circuit voltage (Voc). Although various tandem structures have been studied, the full use of incident light and optimization of cell efficiency is still limited. In this work, we designed series tandem solar cells consisting of lead sulfide (PbS) quantum dots/zinc oxide-based QDSC and zinc phthalocyanine (ZnPc)/C60-based small molecule OSCs. It is expected that the loss of the incident light is minimized because the absorption range of the PbS quantum dots and ZnPc is significantly different, and the Voc increases according to the Kirchhoff's law.

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Interface Study of the Intermediate Connectors in Tandem Organic Devices

  • Tang, Jian-Xin;Fung, Man-Keung;Lee, Chun-Sing;Lee, Shuit-Tong
    • Journal of Information Display
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    • v.11 no.1
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    • pp.1-7
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    • 2010
  • The intermediate connectors play crucial roles in the performance of tandem organic light-emitting diodes (OLEDs) because they are required to facilitate charge carrier transport and to guarantee transparency for light transmission and deposition compatibility. Understanding the physical properties of the intermediate connector is not only fundamentally important but is also crucial to developing high-efficiency organic devices with a tandem structure. In this study, several effective intermediate connectors in tandem OLEDs using a doped or non-doped organic p-n heterojunction were systematically investigated by studying their interfacial electronic structures and corresponding device characteristics. The working mechanisms of the intermediate connectors are discussed herein by referring to their relevant energy levels with respect to those of the neighboring organic layers. The factors affecting the operation of the intermediate connectors in tandem OLEDs, as demonstrated herein, provide guidance for the identification of new materials and device architectures for high-performance devices.

White Organic Light-emitting Diodes using the Tandem Structure Incorporating with Organic p/n Junction

  • Lee, Hyun-Koo;Kwon, Do-Sung;Lee, Chang-Hee
    • Journal of Information Display
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    • v.8 no.2
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    • pp.20-24
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    • 2007
  • Efficient white organic light-emitting diodes are fabricated with the blue and red electroluminescent (EL) units electrically connected in a stacked tandem structure by using a transparent doped organic p/n junction. The blue and red EL units consist of the light-emitting layer of 1,4-bis(2,2-diphenyl vinyl)benzene (DPVBi) and 4-dicyanomethylene-2-methyl-6-[2-(2,3,6,7-tetrahydro-1H,5H-benzo[i,j] quinolizin-8-yl)vinyl]-4H-pyran) (DCM2) doped tris(8-hydroxyquinoline) aluminum $(Alq_3)$, respectively. The organic p-n junction consists of ${\alpha}-NPD$ doped with $FeCl_3$ (15 % by weight ratio) and $Alq_3$ doped with Li (10 %). The EL spectra exhibit two peaks at 448 and 606 nm, resulting in white light-emission with the Commission Internationale d'Eclairage (CIE) chromaticity coordinates of (0.36, 0.24). The tandem device shows the quantum efficiency of about 2.2 % at a luminance of 100 $cd/m^2$, higher than individual blue and red EL devices.

V-band CPW 3-dB Directional Coupler using Tandem Structure (Tandem구조를 이용한 V-band용 CPW 3-dB 방향성 결합기)

  • Moon Sung-Woon;Han Min;Baek Tae-Jong;Kim Sam-Dong;Rhee Jin-Koo
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.42 no.7 s.337
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    • pp.41-48
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    • 2005
  • We design and fabricate 3-dB tandem directional coupler using the coplanar waveguide structure which is applicable to balanced amplifiers and mixers for 60 GHz wireless local area network system. The coupler comprises the multiple-sectional parallel-coupled lines to facilitate the fabrication process, and enable smaller device size and higher directivity than those of the conventional 3-dB coupler employing the edge-coupled line. In this study, we adopt the structure of two-sectional parallel-coupled lines of which each single-coupled line has a coupling coefficient of -8.34 dB and airbridge structure to monolithically materialize the uniplanar coupler structure instead of using the conventional multilayer or bonded structure. The airbridge structure also supports to minimize the parasitic components and maintain desirable device performance in V-band (50$\~$75 GHz). The measured results from the fabricated couplers show couplings of 3.S$\~$4 dB and phase differences of 87.5$^{\circ}{\pm}1^{\circ}$ in V-band range and show directivities higher than 30 dB at a frequency of 60 GHz.

Thin Film Amorphous/Bulk Crystalline Silicon Tandem Solar Cells with Doped nc-Si:H Tunneling Junction Layers

  • Lee, Seon-Hwa;Lee, Jun-Sin;Jeong, Chae-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.257.2-257.2
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    • 2015
  • In this paper, we report on the 10.33% efficient thin film/bulk tandem solar cells with the top cell made of amorphous silicon thin film and p-type bulk crystalline silicon bottom cell. The tunneling junction layers were used the doped nanocrystalline Si layers. It has to allow an ohmic and low resistive connection. For player and n-layer, crystalline volume fraction is ~86%, ~88% and dark conductivity is $3.28{\times}10-2S/cm$, $3.03{\times}10-1S/cm$, respectively. Optimization of the tunneling junction results in fill factor of 66.16 % and open circuit voltage of 1.39 V. The open circuit voltage was closed to the sum of those of the sub-cells. This tandem structure could enable the effective development of a new concept of high-efficiency and low cost cells.

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High Performance Tandem OLEDs for Large Area Full Color AM Displays and Lighting Applications

  • Hatwar, T.K.;Spindler, J.P.;Slyke, S.A. Van
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1577-1582
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    • 2006
  • Tandem OLED structures formed by connecting two or more low-voltage electroluminescent units (stacks) are effective for achieving high efficiency at low current density as well as long operational lifetime. We have fabricated white emitting tandem structures with two or three low-voltage white-emitting stacks using transparent organic "PN"-type connectors. Three- stack white tandem structures with efficiency greater than 24 cd/A at D65 and operational stability of about 110,000 h. (extrapolated) at $1000\;cd/m^2$ have been demonstrated. With a stacked structure, the power consumption for displays using an RGBW format can be reduced by 25% compared to previously described formulations. We have also fabricated advanced white tandem structures where the color gamut (NTSC x,y ratio) has been improved to greater than 70% using standard color filters. The white OLEDs can also be used to increase the colorrendering index CRI (>80%), an important consideration for solid-state lighting.

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