• Title/Summary/Keyword: tackiness

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Interfacial Tacky and Adhesive Characteristics between Tire Tread Compounds and Rubber Cement (타이어 트레드 컴파운드와 고무 시멘트 계면의 점착과 접착 특성)

  • Song, Yo Soon;Kim, Kun Ok
    • Applied Chemistry for Engineering
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    • v.29 no.4
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    • pp.399-404
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    • 2018
  • This study compared the tackiness and adhesion of different tire tread compounds and rubber cements before and after vulcanization. The tackiness of natural rubber (NR) cement was the highest for all tread compounds before vulcanization, and the decrease in tackiness of NR cements over time was smaller than that of synthetic rubber cements. The tackiness before vulcanization was affected by the glass transition temperature of the rubber used in the cement and the decrease in tackiness over time of NR was smaller compared to that of using the synthetic rubber. The adhesion of NR-based cements after vulcanization was high for NR tread compounds but low for synthetic rubber tread compounds. On the contrary, the adhesion of emulsion (SBR) and solution SBR cements was high on all tread compounds which was shown to be higher when the rate of vulcanization of cement rubber was lower.

Surface Modification of Silicone EVD Tube by Low Temperature Plasma (저온 플라스마를 이용한 실리콘 EVD 튜브의 표면개질)

  • Lee, Y.D.;Cho, D.L.
    • Elastomers and Composites
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    • v.34 no.4
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    • pp.315-320
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    • 1999
  • Surface modification of silicone rubber by low temperature plasma process was investigated to improve quality of silicone EVD tube by reducing tackiness and hydrophobicity. Treatment with nonpolymer-forming plasmas and thin film deposition with polymer-forming plasmas were tried. Tackiness could significantly be reduced, especially by thin film deposition. As a result, the tube became slippery and less vulnerable to contamination in laboratory environment. Inner as well as outer surface of the tube could be changed to be hydrophilic if the plasma contained oxygen. As a result, initial hydrodynamic resistance was reduced. The surface modification did not give any bad influence on mechanical properties of the silicone tube in most cases. Rather, some properties such as Young's modulus, ultimate tensile strength and elongation at break were improved.

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A Study on the resistance of acrylic rubber pressure sensitive adhesives with curing agents and tackifiers (경화제와 점착부여제가 아크릴 고무점착제의 내열성에 미치는 영향)

  • Nam, Kyong min;Kim, Chul Yong;Kim, Eun Seon;Kim, Kwang-Je;Choi, Woo Jin;Kim, Ki-Tae;Park, Myung-Chul
    • Journal of Adhesion and Interface
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    • v.18 no.4
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    • pp.166-170
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    • 2017
  • In this study, acrylic rubber pressure sensitive adhesives was polymerized with 2-ethylhexyl acrylate, styrene, butadiene, 2-hydroxyethyl acrylate, and acrylic acid by controlling the initiator content. The initial tackiness, peel strength, holding power, and heat resistance of the PSAs were investigated by changing the content of tackifier and curing agent. The results showed that the initial tackiness and peel strength increased as the content of tackifier increased, whereas the holding power decreased. Also, the results exhibited that that the initial tackiness, peel strength, and heat resistance decreased as the content of curing agent increased, whereas the holding power and decreased.

A Study on Starch-acrylic Graft Copolymerization by Emulsion Polymerization (유화중합에 의한 전분-아크릴 그래프트 공중합에 관한 연구)

  • Hwang, Ju-Ho;Ryu, Hoon;Cho, Ur-Ryong
    • Elastomers and Composites
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    • v.43 no.4
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    • pp.221-229
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    • 2008
  • Starch as matrix polymer was used to do graft copolymerization with 2-ethylhexylacrylate, methyl methacrylate and acrylic acid. The polymerization was carried out by radical emulsion polymerization with increasing contents of starch. When 0.174% of $\alpha$-amylase as enzyme for starch was added, it was found that it made the best stable emulsion. The glass transion temperature of the polymerized material was increased with starch contents. The particle size and viscosity of the emulsion increased with starch contents due to the increased hydroxy group. Peel strength also increased with contents of starch because the enhanced hydroxy group caused to increase affinity between substrate surface and polymer materials. However, the initial tackiness decreased with starch contents owing to film hardness by higher glass transion temperature.

A Study on the Synthesis and Properties of Environmental Friendly Pressure Sensitive Adhesive for Manufacturing Electronic Products (전자제품 제조용 친환경 점착제의 합성과 물성에 대한 연구)

  • Cho, Ur Ryong;Oh, Ji Hwan;Kim, Ji Hyun;Jung, Hyeon Jeong
    • Journal of the Semiconductor & Display Technology
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    • v.15 no.1
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    • pp.12-16
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    • 2016
  • Toluene-free pressure sensitive adhesives were synthesized by using butyl acrylate (BA), 2-hydroxy ethyl acrylate, methyl methacrylate, acrylic acid (AA) as monomers and ethyl acetate as a solvent. The polymerization recipes were designed by changing 1, 3, 5 part per hundreds monomer (phm) of AA content on the basis of 100 BA parts. Two crosslinking agents, ethyl glycol diglycidyl ether (EDGE) and isophorone diisocyanate (IPDI) were added to the synthesized polymers to increase adhesion due to crosslinking. In the measurement of properties, holding power, peel strength, and initial tackiness increased with AA content due to crosslinking between carboxyl group in AA and epoxy group in EDGE and isocyanate group in IPDI. In the comparison of two crosslinking agents, EDGE showed better in the three properties than IPDI by better reaction of epoxy group of EDGE to carboxyl group of AA.

Polyurethane-coated Fabric for RF Welding (RF 접합용 폴리우레탄 코팅 직물)

  • Park, Jong-Cheol;Lee, Jin-Uk;Yun, Nam-Sik;;Kim, Hong-Je
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2008.10a
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    • pp.103-104
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    • 2008
  • Radio-frequency(RF) weldable polyurethane-coated fabric was prepared by knife coating of presetted and cire-finished nylon fabric using optimized coating formulation including RF-sensitive commercial polyurethane resins. The physical properties, adhesion strength, peeling strength, abrasion strength, flexibility, and hydrostatic water resistance of the prepared coated fabric were good enough to show no significant difference with regular coating. Additionally the prepared coated fabric had silky and soft touch without tackiness.

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Pressure Sensitive Adhesive Properties of Blends of Acrylic Quarternary Copolymer with Vinyl Chloride-Vinyl Propionate Copolymers (아크릴계 4원 공중합체와 염화비닐-비닐프로피오네이트 공중합체와의 블렌드의 점착물성)

  • Oh, Dae-Hee;Seo, Kwan-Ho
    • Elastomers and Composites
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    • v.34 no.4
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    • pp.360-365
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    • 1999
  • In this study, the blends of acrylic quaternary polymer (PEBEV) which was co- polymerized from 2-ethylhexyl acrylate (2-EHA), n-butyl acrylate (BA) and ethyl acrylate (EA), vinyl acetate (VAc), and poly(vinyl chloride-co-vinyl propionate) (PVCVP) were prepared by solution blending. Pressure sensitive adhesive (PSA) properties of PEBEV/PVCVP blends were compared with those of PEBEV/poly(vinyl chloride-co-vinyl acetate) (PVCVAc) blends. Compatibility of PEBEV/PVCVP was better than that of PEBEV/PVCVAc. Tackiness of both blend systems were similar, but holding power began to decrease at 15wt% or higher PVCVAc contents in PEBEV/PVCVAc blends. On the other hands, holding power of PEBEV/PVCVP increased as the contents of PVCVP increased. Failure modes of the blends were adhesive failure except 5wt% of PVCVP was blended.

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The Development of UV Blocking Type Pressure-Sensitive Adhesive Sheet for Window (자외선이 차단되는 창문용 점착시트 개발에 관한 연구)

  • Kim, Sung-Ho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.1
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    • pp.559-564
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    • 2011
  • The UV blocking type pressure-sensitive adhesive sheet was developed by mixing UV blocking reagent with adhesive material, instead of conventional method in which the reagent was mixed with PVC substrate. The blocking performance of the sheet was evaluated by measuring the absorbance in 280-400 nm region. Both organic and inorganic type blocking reagents were examined. The blocking ability of the former is better than that of the later. Only 1% addition of blocking reagents is effective to block UV light without affecting to visibility and tackiness of adhesive tapes.

The Effect of MBS on the Compatibility of Scrap PVB/PMMA Blends (Scrap PVB/PMMA 블렌드에 미치는 MBS의 상용화효과(相溶化效果))

  • Choi, Hyeong-Ki;Lee, Yong-Moo;Yoon, Ju-Ho;Choi, Sei-Young
    • Elastomers and Composites
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    • v.31 no.1
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    • pp.23-32
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    • 1996
  • PVB was blended with PMMA in order to recycle scraped PVB material which recovered in the safety glass manufactories. The purpose of this research on PVB/PMMA blend was applied with excellent tackiness and transparency of PVB as a material of high strength to make the maximum use. Also, the blending of PVB with PMMA was aimed at the increase of impact strength of PMMA because the elastic property of PVB might decrease the brittleness of PMMA due to the lack of inner impact resistance. Izod impact resistance was propotional to increase the content of PVB, which was predominantly increased in the addition of 10phr above MBS. High rate impact resistance showed a tendency to Increase but it showed a tendency to decrease maximum load and energy if the contents of PVB increased. On the other hand total energy and ductile index showed a tendency to increase excellent impact resistance in the addition of MBS contents. As a result of observed surface of PVB/PMMA blends, the size of PVB domain increased distribution homogenuously, in the addited MBS contents increased it showed distribution homogeneously and partially a wetability.

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