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Mathematical Modeling of Degree of Hydration and Adiabatic Temperature Rise (콘크리트의 수화도 및 단열온도상승량 예측모델 개발)

  • 차수원
    • Journal of the Korea Concrete Institute
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    • v.14 no.1
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    • pp.118-125
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    • 2002
  • Hydration is the main reason for the growth of the material properties. An exact parameter to control the chemical and physical process is not the time, but the degree of hydration. Therefore, it is reasonable that development of all material properties and the formation of microstructure should be formulated in terms of degree of hydration. Mathematical formulation of degree of hydration is based on combination of reaction rate functions. The effect of moisture conditions as well as temperature on the rate of reaction is considered in the degree of hydration model. This effect is subdivided into two contributions: water shortage and water distribution. The former is associated with the effect of W/C ratio on the progress of hydration. The water needed for progress of hydration do not exist and there is not enough space for the reaction products to form. The tatter is associated with the effect of free capillary water distribution in the pore system. Physically absorption layer does not contribute to progress of hydration and only free water is available for further hydration. In this study, the effects of chemical composition of cement, W/C ratio, temperature, and moisture conditions on the degree of hydration are considered. Parameters that can be used to indicate or approximate the real degree of hydration are liberated heat of hydration, amount of chemically bound water, and chemical shrinkage, etc. Thus, the degree of heat liberation and adiabatic temperature rise could be determined by prediction of degree of hydration.

Temporal and Spatial Variations of Marine Meteorological Elements and Characteristics of Sea Fog Occurrence in Korean Coastal Waters during 2013-2017 (2013~2017년 연안해역별 해양기상요소의 시·공간 변화 및 해무발생시 특성 분석)

  • Park, So-Hee;Song, Sang-Keun;Park, Hyeong-Sik
    • Journal of Environmental Science International
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    • v.29 no.3
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    • pp.257-272
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    • 2020
  • This study investigates the temporal and spatial variations of marine meterological elements (air temperature (Temp), Sea Surface Temperature (SST), and Significant Wave Height (SWH)) in seven coastal waters of South Korea, using hourly data observed at marine meteorological buoys (10 sites), Automatic Weather System on lighthouse (lighthouse AWS) (9 sites), and AWS (20 sites) during 2013-2017. We also compared the characteristics of Temp, SST, and air-sea temperature difference (Temp-SST) between sea fog and non-sea-fog events. In general, annual mean values of Temp and SST in most of the coastal waters were highest (especially in the southern part of Jeju Island) in 2016, due to heat waves, and lowest (especially in the middle of the West Sea) in 2013 or 2014. The SWH did not vary significantly by year. Wind patterns varied according to coastal waters, but their yearly variations for each coastal water were similar. The maximum monthly/seasonal mean values of Temp and SST occurred in summer (especially in August), and the minimum values in winter (January for Temp and February for SST). Monthly/seasonal mean SWH was highest in winter (especially in December) and lowest in summer (June), while the monthly/seasonal variations in wind speed over most of the coastal waters (except for the southern part of Jeju Island) were similar to those of SWH. In addition, sea fog during spring and summer was likely to be in the form of advection fog, possibly because of the high Temp and low SST (especially clear SST cooling in the eastern part of South Sea in summer), while autumn sea fog varied between different coastal waters (either advection fog or steam fog). The SST (and Temp-SST) during sea fog events in all coastal waters was lower (and more variable) than during non-sea-fog events, and was up to -5.7℃ for SST (up to 5.8℃ for Temp-SST).

The Description of Near-Critical Region for the Non-Ideal Inter-Particle Interacting Molecules such as n-Alkane(linear) and Alkyl-Amine(dipolar) by using Generalized van der Waals Equation of States (일반화된 반데르발스 상태방정식을 이용한 비이상적 입자 상호작용을 갖는 알칸(선형성) 및 알킬 아민류(쌍극자성)에 대한 임계 영역 특성분석)

  • Kim, Jibeom;Lee, Sukbae;Jeon, Joonhyeon
    • Korean Chemical Engineering Research
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    • v.48 no.2
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    • pp.224-231
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    • 2010
  • In GvdW EOS, a recently presented paper, shows that the characteristic status for spherical non-linear particle, of which the mutual behavior is known to be vdWf(van der Waals force) only, could be described well enough in the critical region. However, in current papers, analysis has not been done on GvdW about whether it is accurate or not, even for the particles in the linear form or those with the additional mutual behavior such as static-electricity, so there's some argument about the wide use of that. Therefore, in this paper, for the simulation in the critical region of Normal-alkane group(R=methane, ethane, propane, butane) which are the particles that has a linear charateristic and Normal-amine group($RNH_2$, R=methyl-, ethyl-, propyl-amine) where static-electricity is extremely shown, GvdW parameter values about these particles are defined, and based on this simulation, we compared results to the current EOS presented recently, and analyzed them. Through the simulation, it was shown that in case of Normal-alkane group and Normal-amine group molecules, GvdW presents an accurate critical region characteristic which is far more close to the measurement compared to current EOSs. Especially for butane with big amount in molecules, we found out that only GvdW EOS can reach close enough to the critical point.

A Study on the Integrated Management System of Municipal Solid Waste from Seoul Metropolitan City (서울시 일반폐기물의 통합적 관리체계에 관한 연구)

  • 우세홍;홍상균
    • Journal of Environmental Health Sciences
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    • v.19 no.4
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    • pp.51-58
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    • 1993
  • The integrated solid waste management for Seoul Metropolitan city can be established on the basis of the following hierarchy of priorities: 1. Efforts for source reduction should be propelled by both government and citizens to achieve the effects of resource conservation. The adequate production and consumption which are environmentally amenable and sustainable can be induced by the reasonable imposition of deposit money for waste treatment to one-time use products. To accomplish source reduction effectively, the induction of legal and institutional regulation of producer and consumer participation is requisite. 2. For resource recovery, wastes generated should be recycled as far as practicable. Community residents are responsible to separate discharge, the authorities concerned have responsibility of separate collection, and recycling industry should be assissted through tax reduction and financing. Resource separation facilities can be constructed at Kimpo Metropolitan landfill site for wastes not separately collected due to some unavoidable circumstances. 3. Garbage should be composted. Garbage is uneconomical for incineration, because it has high moisture content and low calorie, thus there is no reason for the incineration of garbage even though garbage is classified into combustibles. Composting facilities can be located at sites which are not densely populated and easily accessible to transportation, for example, Kimpo Metropolitan landfill site. Compost produced can be managed by the authorities for the use of fertilizer to a green tract of suburban land and farms. 4. Nonhazardous combustible wastes not recyclable can be utilized for thermal recovery at the incinerators which are completely equipped with pollution control devices. According to the trend of local autonomy and the equity principle of local autonomous entities, incineration facilities of minimal capacity required can be constructed at each districts of Seoul Metropolitan city which have organized local assembly. In case of Yangcheon district, the economically combustible waste quantity is about 260 tons/day which exceeds 150 tons/day, the incineration capacity of existing facility. But, from now on, waste quantity can be reduced substantially by the intensive efforts of citizens for source reduction and recycling and the institutional support of administrative organizations. Especially, it is indispensable for the government to constitute institutional and technological bases that can recycle paper and plastics form 43% of waste generated. A good time for constructing of incineration facilities for municipal solid waste can be postponed to the time that pollution control technologies of domestic enterprises are fully developed to satisfy the standards of air pollution prevention, because the life expectancy of Kimpo Metropolitan landfill site is about 25 years. Within this period, institutional improvements and technological advancements can be attained, while the air qual. ity of Seoul Metropolitan city can be ameliorated to the level to afford incineration facilities. 5. For final disposal, incombustibles and ash are landfilled sanitarily at Kimpo Metropolitan landfill site.

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Recovery Process of Forest Edge Formed by Clear-cutting Harvest in Korean Red Pine (Pinus densiflora) Forest in Gangwondo, South Korea (강원도 남부 지역에서 소나무림 벌채 후 형성된 숲 가장자리의 회복 과정)

  • Kim, Jun-Soo;Cho, Yong-Chan;Bae, Kwan-Ho
    • Journal of Korean Society of Forest Science
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    • v.106 no.1
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    • pp.1-9
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    • 2017
  • Forest harvest as large scale artificial disturbance makes edge environment in both clear-cutted and forested habitat. To clarify the development and recovery process of forest edge after disturbances is essential to understand vegetation responses and landscape level consequences such as edge-distance. In Korea, after clear-cutting, edge-related changes of environment and vegetation was not clarified yet. In Korean red pine (Pinus densiflora) forest, by applying space-for-time approach (sites with undisturbed and 1, 3, 10, 16 yr after cutting), the edge-related change of plant abundance and abiotic factors were determined for 20 line-transect (60 m) and 340 ($1m{\times}5m$) quadrats, and clarified depth and duration of the disturbance. Immediately after edge formation, within 15m form the edge, biotic and abiotic factors such as cover, richness, canopy openness, temperature and moisture content exhibited larger changes compared to forest interior. Plant abundance and abiotic variables were stabilized at the level of forest inside within 16 yr and 10 yr after edge creation, respectively. Woody (tree and shrub) species generally was showed larger increment with proximity to edge than did herb or graminoid species. In addition, negative interactions between woody and herbaceous species were detected during the period of forest edge closure. Our results suggested that depth of forest edge formed by clear-cutting of Korean red pine forest was at least from 15 m to 20 m and edge effect were likely sustained more than 16 years. As the first empirical study on edge-distance between two contrast habitats of clear-cutted and adjacent forest in South Korea, the analytical reality on landscape structure and habitat patches can be improved.

- The Cultural Life Study of the Housekeeping Space of Chosun Dynasty Upperclass Housing - (조선조 상류주택의 가사공간에 관한 생활문화적 고찰)

  • 이길표
    • Journal of the Korean Home Economics Association
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    • v.31 no.1
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    • pp.225-239
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    • 1993
  • The purpose of this study is to look for the basic formative elements of housekeeping space of our cultural life which are worthy to succeed and develop by revaluating in modern view and to reveal what we should maintain form the women's view of the housework in those days. In this study, out look on Chosun Dynasty housekeeping is based on the norm of the women in those days. The research on the housekeeping space for norm of the women in those days. the research on the housekeeping space for Chosun Dynasty upperclass is focused on the house built from early till late Chosun Dynasty, which is now a cultural asset. As a result, norm of Chosun Dynasty have created a social wide atmosphere for women to devote herselves to the housekeeping. Moreover the constructions of Chosun Dynasty's upperclass are affected by Korea's natural environment and socio-cultural environment. Primary factors for natural environment are building materials and the change of seasons. Because of changeable seasons, there were places for storing massive commodities. The other primary factors for socio-cultural environment affecting housekeeping space were social positions, and extended family system, worshipping the ancestors standard of living, the theory of“Poong Soo”(風水, a kind of geomancy) and thought of“Yin and Yang, Five Elements”(陰陽五行) and popular belief of that time. Affected by these two environments, the characteristics of housekeeping space for Chosun Dynasty are ; the main building of the house was used as a diverted area for women to work, and was reconstructed for household affairs. There were inefficient points in the housekeeping space of that time and the space remained stagnant because of the restricted sex and the social position of housekeeping doer. But you could find some points that are efficient and functional to adjust in those living conditions. The storehouse, storage barn, shed and soyjar terrace are the specialized storing place, according to the kinds and characteristics of the commodities. the kitchen, for example, is the combinations of many abilities. It is not only for cooking or heating the room, but also for storing drinking water. The hall which was the storing place, housekeeping place and also the place for family events are used as a diverted place. The linked arrangement of kitchen, store house, boudoir and the other rooms. In addition, we can see that the construction of the kitchen for more than tow people could work in.

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Cloning and Expression of Thermostable $\beta$-Glycosidase Gene from Thermus filiformis Wai33 A1 in Escherichia coli and Enzyme Characterization

  • Kang, Sang-Kee;Cho, Kwang-Keun;Ahn, Jong-Kun;Kang, Seung-Ha;Han, Kyung-Ho;Lee, Hong-Gu;Choi, Yun-Jaie
    • Journal of Microbiology and Biotechnology
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    • v.14 no.3
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    • pp.584-592
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    • 2004
  • A thermostable $\beta$-glycosidase gene, tfi $\beta$-gly, was cloned from the genomic library of Thermus filiformis Wai33 A1. ifi $\beta$-gly consists of 1,296 bp nucleotide sequence and encodes a polypeptide of 431 amino acids. It shares a strong amino acid sequence similarity with the $\beta$-glycosidases from other Thermus spp. belonging to the glycosyl hydrolase family 1. In the present study, the enzyme was overexpressed in Escherichia coli BL21 (DE3) using the pET21b(+) vector system. The recombinant enzyme was purified to homogeneity by heat treatment and a $Ni^{2+}$-affinity chromatography. Polyacrylamide gel electrophoresis (PAGE) showed that the recombinant Tfi $\beta$-glycosidase was a monomeric form with molecular mass of 49 kDa. The temperature and pH range for optimal activity of the purified enzyme were 80- $90^{\circ}C$ and 5.0-6.0, respectively. Ninety-three percent of the enzyme activity was remained at $70^{\circ}C$ after 12 h, and its half-life at $80^{\circ}C$ was 6 h, indicating that Tfi $\beta$-glycosidase is highly thermostable. Based on its K_m$, or $K_{cat}K_m$, ratio, Tfi $\beta$-glycosidase appeared to have higher affinity for $\beta$-D-glucoside than for $\beta$-D-galactoside, however, $K_{cat} for \beta$-D-galactoside was much higher than that for $\beta$-D-glucoside. The activity for lactose hydrolysis was proportionally increased at $70^{\circ}C$ and pH 7.0 without substrate inhibition until reaching 250 mM lactose concentration. The specific activity of Tfi TEX>$\beta$-glycosidase on 138 mM lactose at $70{^\circ}C$ and pH 7.0 was 134.9 U/mg. Consequently, this newly cloned enzyme appears to have a valuable advantage of conducting biotechnological processes at elevated temperature during milk pasteurization in the production of low-lactose milk.

Personal Name Authority Control in Korean Public Libraries (국내 공공도서관의 인명 전거제어의 현황 및 발전 방향)

  • Shim, Kyung
    • Journal of the Korean Society for Library and Information Science
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    • v.40 no.4
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    • pp.221-244
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    • 2006
  • This research analyzes the current status of personal name authority control and its impact on the end user searching against OPACs in public libraries in Korea. Further it also suggests the ways to improve the recall ratio in author search with a minimal modification, system-wise and authority-wise. on the KOLISNET as a stepping stone for other public libraries. Finally, a long-term plan for establishing proper authority work in public libraries including the National Library of Korea is briefly proposed. In order to find out whether authority works are conducted and examine how variant written forms of the same foreign name and variant names of the same person are treated, OPACS of the National Library of Korea, KOLISNET, and ten randomly selected public libraries were searched. Findings indicate that while the National Library of Korea was performing authority control, even incomplete, the rest did not appear to conduct any form or authority control. As a spinoff of the research, it is observed that in many public libraries their bibliographic records and retrieval methods are inaccurate, lacking consistency, and incomplete. In sum. it is strongly recommended that (1) as a start for authority work among public libraries personal name authority control should be conducted to enhance the identifying and collocating functions in OPACs, (2) a shared authority database, for which the National Library of Korea's authority database might be used. should be built for Public libraries.

A Study on the Development of Transfer Papers -Focused on Tile Design for Remodeling- (전사지 개발에 대한 연구 -리모델링을 위한 타일디자인을 중심으로-)

  • 모인순
    • Archives of design research
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    • v.15 no.2
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    • pp.213-222
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    • 2002
  • A transfer paper, is needed in the third firing, is usually utilized for industrial ceramics in order to produce tablewares or promoting products. Products may have the same form, however; the price might be different by what kinds of design have transferred. We need to fully understand these methods in order to create high value and quality. Remodeling, the so-called second architecture, results from social Needs for renovation of structures and changing functions. Tile satisfying the need for a custom-made design which fits the features of a space. Most importantly, the remodeler must make an individual design ordered for the customer with an emphasis on economy and time efficiency. Tiles currently in the market are mass-produced using an automated system with a high-priced mold. It is difficult to find tiles of distinct design that are made in a small quantity. We need to develop a method for making various kinds of tile designs that would be marketed for the remodeling industry. In this study, after designing a certain wall with the tiffs in the space, 1 will talk about developing a method to make transfer paper to produce individual tiles for the space. 1 hope that the functional and aesthetic effect on remodeling will gain in popularity, and that we will foster a new demand for tiles in harmony with the other materials mentioned in this study.

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THE STUDY ABOUT THE MARGINAL FIT OF THE CASTING TITANIUM AND MACHINE-MILLED TITANIUM COPINGS (주조티타늄과 기계절삭티타늄 코핑의 변연적합성에 관한 연구)

  • Oh Su-Yeon;Vang Mong-Sook;Yang Hong-So;Park Sang-Won;Park Ha-Ok
    • The Journal of Korean Academy of Prosthodontics
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    • v.44 no.1
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    • pp.20-28
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    • 2006
  • Statement of problem: The titanium has advantages of a high biocompatibility, a corrosion resistence, low density, and cheep price, so it is focused as a substituted alloy But it is quite difficult to cast with the tranditional method due to the high melting point, reacivity with element at, elevated temperature. By using the CAD-CAM system for the crown construction, it is possible to reduce the errors while proceeding the wax-up, investing, and casting procedure Purpose: The purposes of this study were to measure the marginal adaptation of the casting titanium coping and machine-milled titanium coping according to the casting methods and the marginal configurations. Material and method: The marginal configurations were used chamfer shoulder, and beveled shoulder. The total 30 copings were used, and these are divided into 6 groups according to the manufacturing method and marginal configuration. The gap between margin of the model and the restoration was measured with 3-dimensional measuring microscope. Results: The following results were obtained; 1. casting gold coping demonstrated the best marginal seal, followed by casting titanium coping finally machine-milled titanium copings. 2. In casting titanium coping, chamfer demonstrated the best marginal seal, followed by shoulder and beveled shoulder. There was no significantly difference in shoulder and beveled shoulder. But all margin form has clinically acceptable 3. In machine-milled titanium copings, chamfer demonstrated the best marginal seal, followed by shoulder and beveled shoulder. Beveled shoulder show large and uneven marginal gap Conclusions: Above result revealed that marginal adaptation of the titanim coping is avail able in the clinical range, it can be used as an alternative metal and it is prefered especially in chamfer or shoulder margin during implant superstructure fabrication. But there should be more research on machine-milled titanium in order to use it in the clinics.