• Title/Summary/Keyword: synthetic solution

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A Synthesis of Mullite and Cordierite Ceramics by Solution-Polymerzation Route Based on PVA (PVA를 이용한 Solution-Polymerzation 합성법에 의한 Mullite, Cordierite 세라믹스의 합성)

  • 이용석;이병하
    • Journal of the Korean Ceramic Society
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    • v.41 no.2
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    • pp.151-157
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    • 2004
  • Because of the excellent thermal and chemical properties of mullite and cordierite as the stable oxide ceramic materials, they were widely used from engineering materials to electronic materials. Notwithstanding of their high demands, mullite was synthesised because it is not existed in nature. It is also difficult to produce cordierite of fine powder with high purity due to the narrow range of synthetic temperature. Mullite was synthesised by solid state reaction. However, synthesized mullite has been inhomogeneous. Because of the facts, various synthetic methods have been studied so far including sol-gel method. The purpose of this study is to synthesis mullite and cordierite of fine powder with high purity at the lower temperature by solution-polymerization route using PVA as a polymer carrier, which is an economical method by using low cost materials. As a result, mullite and cordierite were produced with mono crystal phase at 1200$^{\circ}C$ and 1250$^{\circ}C$, respectively, and their surface area over 20 ㎡/g.

Preparation of $TiO_2$ Powder by Sol-Gel Method and Their Photocatalytic Decomposition Effect of Synthetic Detergents for Kitchen Use (졸-겔법에 의한 $TiO_2$ 분체 합성 및 주방용 합성세제의 광분해 효과)

  • Chung, Young-Joon;Roo, Wan-Ho;Yang, Chun-Hoe
    • Journal of the Korean Applied Science and Technology
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    • v.21 no.2
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    • pp.140-147
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    • 2004
  • An aqueous solution of a commercial liquid synthetic detergent for kitchen use was photodecomposed in the presence of titanium dioxides powder under an atmosphere of air at room temperature. Titanium dioxides were prepared by sol-gel method from titanium iso-propoxide at different R ratio($H_2O$/titanium iso-propoxide) and calcined at $500^{\circ}C$. All titanium dioxides were characterized by XRD, BET surface area analyzer and UV-VIS spectrometer. The surface area of titanium dioxides prepared at R ratio=6 appeared higher volume about 20% than commercial $TiO_2$ catalysts. XRD patterns of titania particles were observed mixing phase together with rutile and anatase type. Titanium dioxides prepared by sol-gel method show higher activity about 6% than commercial $TiO_2$ catalysts on the photocatalytic degradation of a commercial liquid synthetic detergent for kitchen. The concentration of the detergent decreased to about 90% of its initial value at illumination times of 2 hour. Illumination for 30 minutes decreased the concentration of oxygen to about one-fifth of the initial value.

A Photocatalytic Degradation of Synthetic Detergent over $TiO_2$ Catalysts Prepared by Sol-Gel Method (졸-겔법으로 제조된 $TiO_2$촉매에 의한 합성세제의 광분해)

  • 양천회;홍필선
    • Journal of the Korean Society of Safety
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    • v.16 no.3
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    • pp.76-82
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    • 2001
  • An aqueous solution of a commercial liquid synthetic detergent for kitchen use was photodecomposed in the presence of titanium dioxides ponder under an atmosphere of air at room temperature. Titanium dioxides were prepared by sol-gel method from titanium iso-propoxide at different R R ratio($H_2O$/titanium iso-propoxide) and calcined at $500^{\circ}C$. All titanium dioxides m characterized by XRD, BET surface area analyzer and UV-VIS spectrometer. The surface mea of titanium dioxides prepared at R ratio=6 appeared higher volume about 20% than commercial $TiO_2$ catalyses. XRD patterns of titania particles were observed mixing phase together with rutile and anatase type. Titanium dioxides prepared by sol-gel method show higher activity about 6% than commercial $TiO_2$ catalysts on the Photocatalytic foundation of a commercial liquid synthetic detergent for kitchen. The concentration of the detergent decreased to about 90%, of its initial value at illumination times of 2 hour. illumination for 30 minutes decreased the concentration of oxygen to about one-fifth of the initial value.

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A hybrid neutronics method with novel fission diffusion synthetic acceleration for criticality calculations

  • Jiahao Chen;Jason Hou;Kostadin Ivanov
    • Nuclear Engineering and Technology
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    • v.55 no.4
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    • pp.1428-1438
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    • 2023
  • A novel Fission Diffusion Synthetic Acceleration (FDSA) method is developed and implemented as a part of a hybrid neutronics method for source convergence acceleration and variance reduction in Monte Carlo (MC) criticality calculations. The acceleration of the MC calculation stems from constructing a synthetic operator and solving a low-order problem using information obtained from previous MC calculations. By applying the P1 approximation, two correction terms, one for the scalar flux and the other for the current, can be solved in the low-order problem and applied to the transport solution. A variety of one-dimensional (1-D) and two-dimensional (2-D) numerical tests are constructed to demonstrate the performance of FDSA in comparison with the standalone MC method and the coupled MC and Coarse Mesh Finite Difference (MC-CMFD) method on both intended purposes. The comparison results show that the acceleration by a factor of 3-10 can be expected for source convergence and the reduction in MC variance is comparable to CMFD in both slab and full core geometries, although the effectiveness of such hybrid methods is limited to systems with small dominance ratios.

천연방부제를 이용한 신기능성 화장품의 개발

  • Gang, Hwan-Yeol;Jo, Han-Yeong;Baek, Hyeon;Ju, U-Hong;Ha, Bae-Jin;Jeong, Yeong-Gi
    • 한국생물공학회:학술대회논문집
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    • 2001.11a
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    • pp.796-797
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    • 2001
  • The $Ag^{2+}$ solution was constructed by supplying pure metal silver in filtrated distilled with constant voltage. The solution at the $Ag^{2+}$ concentration of 10 ppm showed specific activity against Gram positive and negative bacteria. More than 90% activity showed against Candida albicans ATCC 102321 at the same concentration. The addition of DASA, $Ag^{2+}$ and artemisia mixture, in the EVLN had same activity by comparison with chemical synthetic antiseptic.

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Solution-Phase Strategies for the Design, Synthesis, and Screening of Libraries Based on Natural Products

  • Kim, Sang-Hee
    • Proceedings of the PSK Conference
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    • 2003.10a
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    • pp.88-88
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    • 2003
  • The syntheses of different types of stilbenoid libraries have been studied recently. In these courses, the screening of the generated natural product-mimic focused libraries led to the identification of the novel lead compounds for human cytochrome P450 (CYP) lAs, melanin production, and sortase A. A library of trans-stilbene derivatives was prepared through a new efficient solution pahse synthetic pathway and their inhibitory activities were evaluated on human cytochrome P450s(CYP) 1A1, 1A2, and 1B1 to find a potent and selective CYP1 inhibitor. (omitted)

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Spectrophotometric Determination of Trace Lead(II) After Extraction of Lead-Thiosulfate Complex into Aliquat336-CHCl$_3$ and Replacement by Cu (납-티오황산 착물생성과 구리치환에 의한 미량 납(II)의 비색분석에 관한 연구)

  • Lee, Seok-Ki;Joung, Chang-Ung
    • Journal of Environmental Health Sciences
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    • v.24 no.3
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    • pp.1-5
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    • 1998
  • A spectrophotometric method was developed for the acidic solution stripped after an extraction of 0.5 to 2.5 ppm of Lead(II) from 50 mL of $Na_2S_2O_3$ solution into chloroform as the ion-pairs formed between their thiosulfate complexes and alkylamine, Aliquat336. Pb(II) in the stripped solution forms an complex with DDTC in pH 7.3 buffer solution, and was developed in yellow by copper replacement. The ydlow-colored solution have the maximum absorbance at 435 nm in the measurement of absorbance by UV-Visible spectrophotometer. The interference ions such as Fe(III), Hg (II), Al(III), Co, Cu, Ni, Zn, Ca, Sn, have great effects on the extraction, but they were overcomed by the usage of adequate masking agents before an extraction. At last, a good result was obtained in applying this method to synthetic water.

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The Optimum Condition Analysis of Vanadium Solvent Extraction by Alamine336 from the Synthetic Vanadium Sulfate Solution. (황산바나듐 모의용액으로부터 Alamine336에 의한 바나듐 용매추출의 최적조건 연구)

  • Ahn, Jong-Gwan;Ahn, Jae-Woo
    • Korean Journal of Metals and Materials
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    • v.46 no.12
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    • pp.823-829
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    • 2008
  • The solvent extraction process for the recovery of vanadium from leaching solution of SCR(selective catalytic reduction) spent catalyst was investigated by using Alamine336 as an extractant. The effects of experimental conditions, such as initial pH and concentration of sulfate ion, and ammonia concentration of stripping solution were studied. The extraction percentage of vanadium were increased with the increase of initial pH of leaching solution and decreased with the increase of sulfate ion. More than 99% of vanadium in leaching solution were extracted and stripped at the A/O ratio of 1.0 in 2 stages. On the basis of these results, an optimum solvent extraction process which vanadium was effectively recovered from SCR spent catalyst was proposed.