• Title/Summary/Keyword: suspension structure

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Preparation and Properties of Soybean Lecithin Liposome using Supercritical Reverse Phase Evaporation Method (초임계 역상 증발법을 이용한 대두 레시틴 리포좀의 제조 및 특성)

  • Lee, Mi-Jin;Jeong, Noh-Hee;Jeang, Boo-Sick
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.4
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    • pp.391-398
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    • 2010
  • Soybean lecithin liposomes composed phosphatidyl choline, phosphatidyl ethanolamine, phosphatidyl inositol and phosphatidic acid were prepared by using the previously developed supercritical reverse phase evaporation method. The effect of phospholipid composition on the formation of liposomes and physicochemical properties were examined by means of trapping efficiency measurements, transmission electron microscopy, dynamic light scattering and zeta potential measurements. The trapping efficiency of liposomes for D-(+)-glucose made of CNA-Ⅰ which contains approximately 95% phosphatidyl choline is higher than that of CNA-II and CNA-O which contain approximately 32% phosphatidyl choline. However there is no any difference between the trapping efficiency of liposomes for D-(+)-glucose made of CNA-II which has saturated hydrocarbons tails and that of liposomes made of CNA-O which has unsaturated hydrocarbon chains. The electron micrographs of liposomes made of CNA-II and CNA-O show small spherical liposomes with diameter of $0.1\sim0.25{\mu}m$, while that of CNA-I shows large unilamellar liposomes with diameter of $0.2\sim1.2{\mu}m$. These results clearly show that phospholipid structure of phosphatidylcholine allows an efficient preparation of large unilamellar liposomes and a high trapping efficiency for water soluble substances. Liposomes made of CNA-II and CNA-O remained well-dispersed for at least 14 days, while liposome suspension made of CNA-I separated in two phase at 14 days due to aggregation and fusion of liposomes. The dispersibility of liposomes made of CNA-I is lower than that of CNA-II and CNA-O due to the smallar zeta potential of CNA-I.

Basic Study of the Hysteresis of a Nano Shock Absorbing Damper by Employing Mixed Lyophobic Coating Silica Gel (실리카 겔의 소수화 코팅 혼합 정도에 따른 나노 충격 흡수 장치의 이력 현상에 대한 기초적 연구)

  • 문병영;김흥섭
    • Journal of the Earthquake Engineering Society of Korea
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    • v.7 no.2
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    • pp.59-66
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    • 2003
  • A novel application of nano-technology in the field of engineering, called colloidal damper, is investigated. This device is complementary to the hydraulic damper, having a cylinder-piston construction. Particularly for colloidal damper, the hydraulic oil is replacedby a colloidal suspension, which is consisted from a nano-porous matrix with controlled architecture and a lyophobic fluid. In this experimental work, the porous matrix is composed from silica gel, with labyrinth architecture, coated by organo-silicones substances in order to achieve a hydrophobic surface. Water is considered as associated lyophobic fluid. The colloidal damper test rig and the measuring technique of the hysteresis are described. the influence of the hydrophobicity level upon the colloidal damper hysteresis is investigated, for silica gels with similar pores distribution. A certain desired shape of the hysteresis can be achieved by employing mixture of silica gels with different level of hydrophobicity and/or architecture. With these results, it is believed that the proposed damper can be designed and be applied to the desired structure.

A Study on the Characterization of the Mixed-Oxide Prepared from Monazite (모나자이트로부터 파생된 희토류 혼합산화물의 특성)

  • Kwon, Young Sik;Kim, Yeun Sik;Kim, Dong Su
    • Journal of the Korean Chemical Society
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    • v.39 no.12
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    • pp.946-954
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    • 1995
  • The physico-chemical nature of the rare earth oxide which was produced by the caustic fritting of monazite was studied to furnish fundamental data that are required for its efficient use and processing. It was found that the material which was mainly constituted of light rare earths and thorium was a solid solution phase of oxide whose structure was fluorite-type face centered cubic. Its density was 6.75 g/$cm^3$ and it had a uniform particle size distribution at around 1 ${\mu}m.$ The crystallinity improved by heating to elevated temperatures, whereas the solubility in HCl decreased as the crystallinity improved. Complete dissolution in conc. HCl solution in short time (30 min.) was attained by heating to 70$^{\circ}C$. The measurement of zeta potential showed its I.E.P. to be at pH 8.6 of the suspension.

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Photocatalytic Degradation of Methylene Blue by ACF/TiO2 and ACF/ZnO Composites under UV Light

  • Zhang, Kan;Oh, Won-Chun
    • Korean Journal of Materials Research
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    • v.20 no.1
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    • pp.31-36
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    • 2010
  • Methylene blue (MB) was degraded by $TiO_2$ and ZnO deposited on an activated carbon fiber (ACF) surface under UV light. The ACF/$TiO_2$ and ACF/ZnO composites were characterized by BET, SEM, XRD, and EDX. The BET surface area was related to the adsorption capacity for composites. The SEM results showed that titanium dioxide and zinc oxide are distributed on the ACF surface. The XRD results showed that the ACF/$TiO_2$ and ACF/ZnO composites contained a unique anatase structure for $TiO_2$ and a typical hexagonal phase for ZnO respectively. These EDX spectra showed the presence of peaks of Ti element on ACF/$TiO_2$ composite and peaks of Zn element on the ACF/ZnO composite. The blank experiments for either illuminating the MB solution or the suspension containing ACF/$TiO_2$ or ACF/ZnO in the dark showed that both illumination and the catalyst were necessary for the mineralization of organic dye. Additionally, the ACF/$TiO_2$ composites proved to be efficient photocatalysts due to degradation of MB at higher reaction rates. The addition of an oxidant $([NH_4]_2S_2O_8)$ led to an increase of the degradation rate of MB for ACF/$TiO_2$ and ACF/ZnO composites.

A Study on the Factors Affecting the High Fluid Mortar Containing Ground Granulated Blast-furnace Slag (고로슬래그 미분말을 함유한 고유동 모르터의 유동성상에 미치는 영향 요인에 관한 연구)

  • Kim, Jae-Hun;Yoon, Sang-Chun;Jee, Nam-Yong
    • Journal of the Korea Institute of Building Construction
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    • v.2 no.4
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    • pp.145-152
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    • 2002
  • High fluid concrete unlike OPC concrete is made with various material, and the phase of fresh concrete is considerably different. In order to understand fluidity phase and mix properties of high fluid concrete, concrete is required to access as suspension structure which consists of aggregate and paste. The focus of this paper is to analyze the test results and quantify the effect of mix proportions of mortar and fineness modulus of sand on the properties of fresh mortar. The effect of water-binder ratio. sand-binder ration. contents of ggbs (by mass of total cementitious materials). and various contents of water reducing agent on the yield stress and plastic viscosity of the mix is studied. Based on the experimental results, the fellowing conclusions can be drawn: (1) The mixing time needed for high fluid mortar was approximately two times more than that of ordinary portland mortar. (2) The fluidity phase of mortar could be explained by yield stress of mix and the fluidity of mortar. (3) As the content of ggbs increased, yield stress of mortar was decreased and plastic viscosity of it was increased. (4) For the high fluid mortar, it was appeared that sand-binder ratio should be below 1.5.

Relationship Analysis of Break-up Mode and Heat Transfer of Micro-Speaker Diaphragm (마이크로 스피커 진동판에 대한 분할진동 모드와 열전달의 관계 분석)

  • Kim, Hyun-Kab;Kim, Hie-Sik
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.41 no.4
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    • pp.333-336
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    • 2017
  • A speaker diaphragm generates a divided vibration. The influence of the break-up mode is sufficient to cause a shape change in the diaphragm. In this paper, is widely used in ultra-thin multi-media devices, including smart phones is the advance guard of the IT sector, the micro-speakers and its target. Micro-speakers are different from general speakers. The plate has structural form and space constraints. In particular, they utilize a closed-type drive space. It is difficult to provide cooling for the auxiliary suspension structure because of the heat generated in the moving coil. The present study considered the relationship between the break-up mode and the heat transfer of the diaphragm. An experiment was conducted in two stages to compare the embodiment of the break-up mode and heat transfer in a certain frequency range. The changes in the heat were determined through measurements and thermal imaging of the break-up mode. The break-up mode tendency of the diaphragm could be rapidly predicted based on the imaging results using the thermal imaging camera. This will help in the optimal design of micro-speakers.

A vision-based system for dynamic displacement measurement of long-span bridges: algorithm and verification

  • Ye, X.W.;Ni, Y.Q.;Wai, T.T.;Wong, K.Y.;Zhang, X.M.;Xu, F.
    • Smart Structures and Systems
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    • v.12 no.3_4
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    • pp.363-379
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    • 2013
  • Dynamic displacement of structures is an important index for in-service structural condition and behavior assessment, but accurate measurement of structural displacement for large-scale civil structures such as long-span bridges still remains as a challenging task. In this paper, a vision-based dynamic displacement measurement system with the use of digital image processing technology is developed, which is featured by its distinctive characteristics in non-contact, long-distance, and high-precision structural displacement measurement. The hardware of this system is mainly composed of a high-resolution industrial CCD (charge-coupled-device) digital camera and an extended-range zoom lens. Through continuously tracing and identifying a target on the structure, the structural displacement is derived through cross-correlation analysis between the predefined pattern and the captured digital images with the aid of a pattern matching algorithm. To validate the developed system, MTS tests of sinusoidal motions under different vibration frequencies and amplitudes and shaking table tests with different excitations (the El-Centro earthquake wave and a sinusoidal motion) are carried out. Additionally, in-situ verification experiments are performed to measure the mid-span vertical displacement of the suspension Tsing Ma Bridge in the operational condition and the cable-stayed Stonecutters Bridge during loading tests. The obtained results show that the developed system exhibits an excellent capability in real-time measurement of structural displacement and can serve as a good complement to the traditional sensors.

Biocontrol Potential of a Lytic Bacteriophage PE204 against Bacterial Wilt of Tomato

  • Bae, Ju Young;Wu, Jing;Lee, Hyoung Ju;Jo, Eun Jeong;Murugaiyan, Senthilkumar;Chung, Eunsook;Lee, Seon-Woo
    • Journal of Microbiology and Biotechnology
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    • v.22 no.12
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    • pp.1613-1620
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    • 2012
  • Bacterial wilt caused by Ralstonia solanacearum is a devastating disease of many economically important crops. Since there is no promising control strategy for bacterial wilt, phage therapy could be adopted using virulent phages. We used phage PE204 as a model lytic bacteriophage to investigate its biocontrol potential for bacterial wilt on tomato plants. The phage PE204 has a short-tailed icosahedral structure and double-stranded DNA genome similar to that of the members of Podoviridae. PE204 is stable under a wide range of temperature and pH, and is also stable in the presence of the surfactant Silwet L-77. An artificial soil microcosm (ASM) to study phage stability in soil was adopted to investigate phage viability under a controlled system. Whereas phage showed less stability under elevated temperature in the ASM, the presence of host bacteria helped to maintain a stable phage population. Simultaneous treatment of phage PE204 at $10^8$ PFU/ml with R. solanacearum on tomato rhizosphere completely inhibited bacterial wilt occurrence, and amendment of Silwet L-77 at 0.1% to the phage suspension did not impair the disease control activity of PE204. The biocontrol activities of phage PE204 application onto tomato rhizosphere before or after R. solanacearum inoculation were also investigated. Whereas pretreatment with the phage was not effective in the control of bacterial wilt, post-treatment of PE204 delayed bacterial wilt development. Our results suggested that appropriate application of lytic phages to the plant root system with a surfactant such as Silwet L-77 could be used to control the bacterial wilt of crops.

Development Status of Korea Accelerated Loading and Environment Simulator (KALES) (한국형 포장가속시험시설의 개발현황)

  • Yang, Seong-Cheol;Yu, Tae-Seok;Eom, Ju-Yong
    • International Journal of Highway Engineering
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    • v.2 no.2
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    • pp.139-148
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    • 2000
  • Currently existing Accelerated Pavement Testing (APT) systems developed in several countries have been employed mainly to test the performance of asphalt pavement. Meanwhile, the length of concrete pavement is similar to that of asphalt pavement in expressways of Korea. and is expected to increase due to its durability and compatibility to our weather condition. To meet the society's demand of having our own APT system which can examine the long-term performance of concrete pavement, a contract study to develop Korea Accelerated Loading and Environment Simulator (KALES) for concrete pavement has been performed for 3 years from 1997 through 1999. Through the project, a detailed design was Peformed for the KALES system in which the entire structure of KALES, loading mechanism, wandering mechanism, suspension system, driving system were proposed. Also in advance to design a full-scale KALES system, a sample scale model was manufactured and tested for operating motion and force distribution. It is evident that the proposed prototype KALES system will provide higher degree of traffic simulation and durable operation, based on the satisfactory fatigue analysis.

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Fabrication of EPDM Rubber/Organo-bentonite Composites: Influence of Hydrochloric Acid on the Characteristics of Modified Bentonite and Final Products (EPDM 고무/유기 벤토나이트 복합체의 제조: 개질된 벤토나이트와 최종 생성물의 특성에 대한 염산의 영향)

  • Ge, Xin;Li, Mei-Chun;Cho, Ur Ryong
    • Polymer(Korea)
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    • v.38 no.1
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    • pp.62-68
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    • 2014
  • To improve the compatibility of bentonite with rubber matrix, organo-modified bentonite was synthesized with a silane coupling agent, [3-(2-aminoethylamino)propyl]trimethoxysilane (AEAPTMS) in the suspension of bentonite. The structure and characteristics of organo-modified bentonite were investigated using FTIR-spectroscopy, thermogravimetric analysis (TGA) and X-ray diffraction (XRD). Ethylene-propylene-diene monomer (EPDM) rubber/organo-bentonite composites were compounded by a two-roll mill. The vulcanization and mechanical properties were studied. Results showed that the concentration of hydrochloric acid and $H_2O$ in the synthesis had significant influence on the modification of bentonite, which further contributed to the properties of the composites. Filled with 20 phr modified bentonite, the tensile strength and elongation at break of the rubber increased from 1.95 to 4.8 MPa and 300% to 500%, respectively.