• Title/Summary/Keyword: surface-modification technology

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Production and Application of Nanoparticles by the Chemical Vapor Condensation Process (화학기상 응축법에 의한 나노분말의 제조 및 응용)

  • Kim Jin-Chun;Ha Gook-Hyun;Choi Chul-Jin;Kim Byoung-Kee
    • Journal of Powder Materials
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    • v.12 no.4 s.51
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    • pp.239-248
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    • 2005
  • 1990년도 초반에 개발되어 나노분말의 제조 공정으로 집중적으로 연구되어온 화학기상응축공정은 고강도용 나노분말 소재이외에 기능성 자성재료로의 응용에 주로 이용되어 왔다. 최근에는 이러한 응용이외에 나노분말의 표면을 다양한 이종 소재로 응용하고자하는 나노캡슐(혹은 core/shell)화 제조 공정으로 진보되어 다양한 합금 시스템으로 발전하게 되었다. 특히 최근 Particles 2005, Surface Modification in Particle Technology 학회에서는 나노금속 혹은 세라믹 분말에 PMMA, PE등 polymer의 유기화합물의 코팅하여, DNA나 RNA를 부착하거나 추출해내는 나노캡슐화 공정 연구가 매우 활발하게 진행됨을 보여주고 있으며, 이들 나노 캡슐의 개발은 약물전달계(Drug delivery system), 온열치료용 및 MRI 조영제 등의 바이오재료로의 응용가능성이 크게 기대되어 이에 대한 연구들이 활발하게 진행될 것으로 예상된다.

A Method for Operational Safety Assessment of a Deep Geological Repository for Spent Fuels

  • Jeong, Jongtae;Cho, Dong-Keun
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.spc
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    • pp.63-74
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    • 2020
  • The operational safety assessment is an important part of a safety case for the deep geological repository of spent fuels. It consists of different stages such as the identification of initiating events, event tree analysis, fault tree analysis, and evaluation of exposure doses to the public and radiation workers. This study develops a probabilistic safety assessment method for the operational safety assessment and establishes an assessment framework. For the event and fault tree analyses, we propose the advanced information management system for probabilistic safety assessment (AIMS-PSA Manager). In addition, we propose the Radiological Safety Analysis Computer (RSAC) program to evaluate exposure doses to the public and radiation workers. Furthermore, we check the applicability of the assessment framework with respect to drop accidents of a spent fuel assembly arising out of crane failure, at the surface facility of the KRS+ (KAERI Reference disposal System for SNFs). The methods and tools established through this study can be used for the development of a safety case for the KRS+ system as well as for the design modification and the operational safety assessment of the KRS+ system.

Improved Sensitivity of a Glucose Sensor by Encapsulation of Free GOx in Conducting Polymer Micropillar Structure

  • Jung, Shin-Hwan;Lee, Young-Kwan;Son, Yong-Keun
    • Journal of Electrochemical Science and Technology
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    • v.2 no.2
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    • pp.124-129
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    • 2011
  • A simple process of fabricating micropillar structure and its influence upon enhancing electrochemical biosensor response were studied in this work. Conducting polymer PEDOT was used as a base material in formulating a composite with PVA. Micro porous PC membrane filter was used as a template for the micropillar of the composite on ITO electrode. This structure could provide plenty of encapsulating space for enzyme species. After dosing enzyme solution into this space, Nafion film tent was cast over the pillar structure to complete the micropillar cavity structure. In this way, the encapsulation of enzyme could be accomplished without any chemical modification. The amount of enzyme species was easily controllable by varying the concentration of the dosing solution. The more amount of enzyme is stored in the sensor, the higher the electrochemical response is produced. One more reason for the sensitivity improvement comes from the large surface area of the micropillar structure. Application of 0.7 V produced the best current response under the condition of pH 7.4. This biosensor showed linear response to the glucose in 0.1~1 mM range with the average sensitivity of $14.06{\mu}A/mMcm^2$. Detection limit was 0.01 mM based on S/N = 3.

Diurnal Modification of a Red-Tide Causing Organism, Chattonella antiqua (Raphidophyceae) from Korea

  • Kim, So-Young;Seo, Kyung-Suk;Lee, Chang-Gyu;Lee, Yoon
    • ALGAE
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    • v.22 no.2
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    • pp.95-106
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    • 2007
  • Blooms of Chattonella species are normally during summer in inland seas with high nutrients from the land and inflowing water. These blooms cause mass fish kills worldwide. We isolated a Chattonella strain from the south coast of Korea and identified it as C. antiqua. It is known that the morphological changes of phytoplankton correspond to the diurnal vertical migrations that follow an intrinsic biological clock and a nutrient acquisition mechanism during the day and night. In electron micrographs, C. antiqua clearly showed a radial distribution of lipid bodies in subcellular regions and plastids composed in which thylakoid layers were perpendicular to the surface. A single pyrenoid was present in each plastid and it was found at the end of the plastid towards the center of the cell. Throughout the day, plastids of C. antiqua cells appeared as an expanded net-like recticulum. During the night, however, the plastids changed their shape and contracted toward the cell periphery. The electron density of pyrenoids was increased in cells harvested during the night.

Numerical Analysis for Hull Cleaning ROV Resistance Performance (선저청소로봇 저항성능 전산해석)

  • Seo, Jang-Hoon;Yoon, Hyun-Sik;Chun, Ho-Hwan;Kim, Su-Hu;Kim, Tae-Hyung;Woo, Jong-Sik;Joo, Young-Sock
    • Journal of Ocean Engineering and Technology
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    • v.22 no.6
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    • pp.64-74
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    • 2008
  • The flaw around a ROV (Remotely Operated Vehicle) has been numerically investigated to improve resistance performance by modifying the hull form of the ROV. For the base hull form considered in this study, the form drag rather than the friction drag is dominant to the total drag Subsequently, the surfaces on which the local pressure highly acts have been modified to produce the streamlined-shape. Based on the surface modification, seven different hull forms have been chosen as candidates for drag reduction. Among the candidates, the semi-sphericalized housing and the streamlined-bow achieved greatest drag reduction comparing with the others. Consequently, the hull form combined with the semi-sphericalized housing and the streamlined-bow gave approximately 17% drag reduction at the design velocity of 3 knots.

The Surface Modification of Electrode with Solid Electrolyte Interphase for Hybrid Supercapacitor

  • Choi, Min-Geun;Kang, Soo-Bin;Yoon, Jung Rag;Lee, Byung Gwan;Jeong, Dae-Yong
    • Journal of Electrical Engineering and Technology
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    • v.10 no.3
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    • pp.1102-1106
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    • 2015
  • A hybrid supercapacitor (HS) is an energy storage device used to enhance the low weight energy density (Wh/kg) of a supercapacitor. On the other hand, a sudden decrease in capacity has been pointed out as a reliability problem after many charge/discharge cycles. The reliability problem of a HS affects the early aging process. In this study, the capacity performance of a HS was observed after charge/discharge. For detailed analysis of the initial charge/discharge cycles, the charge and discharge curve was measured at a low current density. In addition, a solid electrolyte interphase (SEI) layer was confirmed after the charge/discharge. A HC composed of a lithium titanate (LTO) anode and active carbon cathode was used. The charge/discharge efficiency of the first cycle was lower than the late cycles and the charge/discharge rate was also lower. This behavior was induced by SEI layer formation, which consumed Li ions in the LTO lattice. The formation of a SEI layer after the charge/discharge cycles was confirmed using a range of analysis techniques.

Current Research Trends in Water Treatment Membranes Based on Nano Materials and Nano Technologies (나노 기술을 이용한 수처리 분리막 소재의 최근 연구동향)

  • Lee, Hee Dae;Cho, Young Hoon;Park, Ho Bum
    • Membrane Journal
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    • v.23 no.2
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    • pp.101-111
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    • 2013
  • Nano materials having large surface area, uniform dimensions or pores can be utilized in various membrane applications. Recently, many studies have been focused on the application of nano materials and nano technologies in membrane applications by the help of the discovery and development of nano technologies. in terms of mass transport channels or functional modification. However, there have been several technological limitations for commercialization. Nano materials and nano technologies can improve 1) permeability, selectivity, 2) mechanical, chemical, thermal stability or fouling tolerance of conventional membranes and even 3) introduce new functionalities such as specific affinity and reactivity.

반도체 산업용 나노기공 함유 유기실리카 박막

  • 차국헌;윤도영;이진규;이희우
    • Proceedings of the Korea Crystallographic Association Conference
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    • 2002.11a
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    • pp.48-48
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    • 2002
  • It is generally accepted that ultra low dielectric interlayer dielectric materials (k < 2.2) will be necessary for ULSI advanced microelectronic devices after 2003, according to the International Technology Roadmap for Semiconductors (ITRS) 2000. A continuous reduction of dielectric constant is believed to be possible only by incorporating nanopores filled with air (k = 1.0) into electrically insulating matrices such as poly(methyl silsesquioxane) (PMSSQ). The nanopo.ous low dielectric films should have excellent material properties to survive severe mechanical stress conditions imposed during the advanced semiconductor processes such as chemical mechanical planarization process and multilayer fabrication. When air is incorporated into the films for lowering k, their mechanical strength has inevitably to be sacrificed. To minimize this effect, the nanopores are controlled to exist in the film as closed cells. The micromechanical properties of the nanoporous thin films are considered more seriously than ever, particularly for ultra low dielectric applications. In this study, three approaches were made to design and develop nanoporous low dielectric films with improved micromechanical properties: 1) wall density increase of nanoporous organosilicate film by copolymerization of carbon bridged comonomers; 2) incorporation of sacrificial phases with good miscibility; 3) selective surface modification by plasma treatment. Nanoporous low-k films were prepared with copolymerized PMSSQ and star-shaped sacrificial organic molecules, both of which were synthesized to control molecular weight and functionality. The nanoporous structures of the films were observed using field emission scanning electron microscopy, cross-sectional transmission electron microscopy, atomic force microscopy, and positronium annihilation lifetime spectroscopy(PALS). Micromechanical characterization was performed using a nanoindentor to measure hardness and modulus of the films.

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Compensation Design to Reduce Springback in Sheet Metal Forming of 1.2GPa Ultra High Strength Steel (1.2GPa급 강판 판재 성형에서 스프링백 감소를 위한 금형 보상 설계)

  • Kwon, S.H.;Lee, H.S.;Lee, Y.S.;Kim, S.W.;Jung, C.Y.;Hong, S.
    • Transactions of Materials Processing
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    • v.25 no.5
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    • pp.301-305
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    • 2016
  • The manual modification of stamping die has widely been used in order to reduce springback after sheet metal forming. When UHSS (Ultra High Strength Steel) is used in sheet metal forming, the die design considering springback compensation is more difficult because higher strength sheet has more springback. In this study, the optimization method was used in order to design die geometry considering springback compensation after forming of 1.2GPa UHSS. Die geometries were defined as design variables and the springback distance from the die surface was conducted as object function in optimization process. The optimized die geometry considering springback compensation was performed using finite element and optimization analysis. The simulation results such as thickness distribution and springback amount were compared with measured data using 3D optical measurement system (GOM ARGUS, ATOS). And the prediction of springback amount showed a good agreement within test results.

Performance Evaluation of a Solar Tracking PV System with Photo Sensors (포토센서를 이용한 태양위치 추적기의 성능분석에 관한 연구)

  • Jeong, Byeong-Ho;Cho, Geum-Bae;Lee, Kang-Yeon
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.27 no.5
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    • pp.67-73
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    • 2013
  • The conversion of solar radiation into electrical energy by Photo-Voltaic (PV) effect is a very promising technology, being clean, silent and reliable, with very small maintenance costs and small ecological impact. The output power produced by the PV panels depends strongly on the incident light radiation. The continuous modification of the sun-earth relative position determines a continuously changing of incident radiation on a fixed PV panel. The point of maximum received energy is reached when the direction of solar radiation is perpendicular on the panel surface. Thus an increase of the output energy of a given PV panel can be obtained by mounting the panel on a solar tracking device that follows the sun trajectory. Tracking systems that have two axes and follow the sun closely at all times during the day are currently the most popular. This paper presents research conducted into the performance of Solar tracking system with photosensors. The results show that an optimized dual-axis tracking system with photosensor performance and analysis. From the obtained results, it is seen that the sun tracking system improves the energy and energy efficiency of the PV panel.ti-junction CPV module promises to accelerate growth in photovoltaic power generation.