• 제목/요약/키워드: surface state effect

검색결과 738건 처리시간 0.027초

백금촉매의 표면반응에 미치는 압력의 영향에 관한 실험 및 이론적 연구 (Experimental and Theoretical Study on the Effect of Pressure on the Surface Reaction over Platinum Catalyst)

  • 김형만
    • 한국연소학회지
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    • 제5권1호
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    • pp.1-6
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    • 2000
  • Surface reaction occurs at a certain surface temperature when a catalyst is heated up in a reactive mixture. If homogeneous ignition does not occur, a steady state is observed because the heat produced by the surface reaction is balanced with the heat loss caused by convection, conduction and radiation. The present paper treats the effects of pressure on the surface temperature at the steady state. Hydrogen and oxygen are used as reactants and nitrogen as an inert gas. A spherical platinum catalyst of 1.5 mm in diameter is sustained in the chamber with two wires of 0.1 mm in diameter. As results, there exists a maximum steady temperature at a certain relative hydrogen concentration which increases with total pressure. At the steady state, it can be approximated that the heat release is estimated by the mass transfer considering the effect of natural convection. The experimental results are explained qualitatively by the approximation.

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Townsend 방전영역의 불꽃전압에 미치는 음극표면상태의 영향 (The Influence of the Cathode Surface State on the Spark Voltage in the Townsend Discharge Domain)

  • 백용현
    • 전기의세계
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    • 제28권1호
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    • pp.73-82
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    • 1979
  • There are a great number of papers on the Townsend discharge in gases, and many of them are concerned with the effect of the cathode. It has been regarded that there are two kinds of effect of the electrodes, especially of the cathode; (a) the effect caused by the difference of the cathode material and (b) the effect by the change of the cathode surface state even in the same material. Both of them may change the secondary coefficient following after the change of the work function, and the atter may further change the primary ionization coefficient as foreign atoms on the surface may be dseorbed in sparks to decrease the purity of the gas. Thus the two effects must be investigated independently to study the roles of the cathode in gas discharges. In this report the effect of the cathode material on the sparking voltage is described. The experiment is also carried out under the condition that the desorption of impurities from the cathode be negligible. From these the new correlativity between the work function of the cathode and the sparking voltage is obtained. In addition, the interesting character of the minimum point of the Paschen's curve can be found.

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The Differential Effect of Emotional Labour on Boundary Spanners

  • MUPARANGI, Simbarashe;SIZIBA, Singirai;MAKUDZA, Forbes
    • 웰빙융합연구
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    • 제4권1호
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    • pp.1-10
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    • 2021
  • Purpose: The study sought to uncover the effect of emotional labour strategies (surface acting and deep acting) on job satisfaction and emotional exhaustion. The study also purposed to analyse the moderating effect of organisational support (supervisory support and co-worker support) and the role of gender on emotional labour connotations. Research design, data and methodology: A conceptual framework was developed using extant literature which led to the examination of deep acting and surface acting, which are the two main strategies of emotional labour. The outcome variables were emotional exhaustion and job satisfaction. Data was collected from front line employees of banks and was analysed using SEM-AMOS version 21. Results: It was revealed, in this study, that surface acting is inversely related to job satisfaction and positively related to emotional exhaustion, whereas deep acting was positively related to job satisfaction and inversely related to emotional exhaustion. The roles of gender and organisational support were also confirmed. Conclusions: The study therefore concluded that deep acting is the most ideal strategy of emotional labour as it leads to job satisfaction and reduced emotional exhaustion. Surface acting is a harmful emotional labour strategy.

A Defect Free Bistable C1 SSFLC Devices

  • Wang, Chenhui;Bos, Philip J.
    • Journal of Information Display
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    • 제4권1호
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    • pp.1-8
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    • 2003
  • Recent progress in both low pretilt and high pretilt defect free C1 surface stabilized ferroelectric liquid crystal (SSFLC) devices is reviewed. First, by numerical calculation to investigate the balance between surface azimuthal anchoring energy and bulk elastic energy within the confined chevron layer geometry of C1 and C2, it is possible to achieve a zigzag free C1 state by low azimuthal anchoring alignment with a low pretilt angle. The critical azimuthal anchoring coefficient for defect free C1 state is calculated. Its relationship with elastic constant, chevron angle as well as surface topography effect are also discussed. Second, using $5^{\circ}$ oblique SiO deposition alignment method a defect free, large memory angle, high contrast ratio and bistable C1 SSFLC display, which has potential for electronic paper applications has also been developed. The electrooptical properties and bistability of this device have been investigated. Various aspects of defect control are also discussed.

표층수의 월류를 통한 소수력빌전소 수차터빈측의 유동안정화 연구 (Studies on the flow stabilization around the turbine suction with utilizing the surface water overflow at small-hydraulic power plant)

  • 이성명;김철환;유근종;김원석
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2011년도 추계학술대회 초록집
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    • pp.165.2-165.2
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    • 2011
  • Flow with suction to water turbine must be in stable state at small hydraulic power plant. But because of water level fluctuation and water gate effect according to irregular supply of cooling water, it would happen to produce bubble and vortex and finally lead to problems in power-plant system. With utilizing the concept design of double size gate, surface water overflowed the overhead of gate for stable flow at suction. We developed the overflow condition and analyzed the design factor with existed one such as water level(overflow amount) and overhead of water gate(overflow figure). Flow test and CFD simulation say that flow have stable state around suction and 20% of wave reduction effect at surface layer after surface water overflow.

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Suppressing Erwinia carotovora Pathogenicity by Projecting N-Acyl Homoserine Lactonase onto the Surface of Pseudomonas putida Cells

  • Li, Qianqian;Ni, Hong;Meng, Shan;He, Yan;Yu, Ziniu;Li, Lin
    • Journal of Microbiology and Biotechnology
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    • 제21권12호
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    • pp.1330-1335
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    • 2011
  • N-Acyl homoserine lactones (AHLs) serve as the vital quorum-sensing signals that regulate the virulence of the pathogenic bacterium Erwinia carotovora. In the present study, an approach to efficiently restrain the pathogenicity of E. carotovora-induced soft rot disease is described. Bacillus thuringiensis-derived N-acyl homoserine lactonase (AiiA) was projected onto the surface of Pseudomonas putida cells, and inoculation with both strains was challenged. The previously identified N-terminal moiety of the ice nucleation protein, InaQ-N, was applied as the anchoring motif. A surface display cassette with inaQ-N/aiiA was constructed and expressed under the control of a constitutive promoter in P. putida AB92019. Surface localization of the fusion protein was confirmed by Western blot analysis, flow cytometry, and immunofluorescence microscopy. The antagonistic activity of P. putida MB116 expressing InaQ-N/AiiA toward E. carotovora ATCC25270 was evaluated by challenge inoculation in potato slices at different ratios. The results revealed a remarkable suppressing effect on E. carotovora infection. The active component was further analyzed using different cell fractions, and the cell surface-projected fusion protein was found to correspond to the suppressing effect.

Lattice Boltzmann Method을 이용한 적혈구의 정적인 모양과 동적변형에 대한 연구 (SINGLE-PHASE MULTI-COMPONENT SIMULATION OF STATIC SHAPE AND DYNAMIC DEFORMATION OF RED BLOOD CELLS USING LATTICE BOLTZMANN METHOD)

  • ;김용현;이준상
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2008년도 학술대회
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    • pp.186-196
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    • 2008
  • The dependence of the rheological properties of blood on shape, aggregation, and deformability of red blood cells (RBCs) has been investigated using hybrid systems by coupling fluid with solid models. We present a simple approach for simulating blood as a multi-component fluid, in which RBCs are modeled as droplets of acquired biconcave shape. We used lattice Boltzmann method (LBM) due to its excellent numerical stability as a simulation tool. The model enables us to control the droplet static shape by imposing non-isotropic surface tension force on the interface between the two components. The use of the proposed non-isotropic surface tension method is justified by the Norris hypothesis. This hypothesis states that the shape of the RBC is due to a non-uniform interfacial surface tension force acting on the RBC periphery. This force is caused by the unbalanced distribution of the lipid molecules on the surface of the RBC. We also used the same concept to investigate the dynamic shape change of the RBC while flowing through the microvasculature, and to explore the physics of the Fahraeus, and the Fahraeus-Lindqvist effects.

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Lattice Boltzmann Method을 이용한 적혈구의 정적인 모양과 동적변형에 대한 연구 (SINGLE-PHASE MULTI-COMPONENT SIMULATION OF STATIC SHAPE AND DYNAMIC DEFORMATION OF RED BLOOD CELLS USING LATTICE BOLTZMANN METHOD)

  • ;김용현;이준상
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2008년 추계학술대회논문집
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    • pp.186-196
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    • 2008
  • The dependence of the rheological properties of blood on shape, aggregation, and deformability of red blood cells (RBCs) has been investigated using hybrid systems by coupling fluid with solid models. We present a simple approach for simulating blood as a multi-component fluid, in which RBCs are modeled as droplets of acquired biconcave shape. We used lattice Boltzmann method (LBM) due to its excellent numerical stability as a simulation tool. The model enables us to control the droplet static shape by imposing non-isotropic surface tension force on the interface between the two components. The use of the proposed non-isotropic surface tension method is justified by the Norris hypothesis. This hypothesis states that the shape of the RBC is due to a non-uniform interfacial surface tension force acting on the RBC periphery. This force is caused by the unbalanced distribution of the lipid molecules on the surface of the RBC. We also used the same concept to investigate the dynamic shape change of the RBC while flowing through the microvasculature, and to explore the physics of the Fahraeus, and the Fahraeus-Lindqvist effects.

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Theoretical Studies of Surface Diffusion : Multidimensional TST and Effect of Surface Vibrations

  • 곽기정;신석민;이상엽;신국조
    • Bulletin of the Korean Chemical Society
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    • 제17권2호
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    • pp.192-198
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    • 1996
  • We present a theoretical formulation of diffusion process on solid surface based on multidimensional transition state theory (TST). Surface diffusion of single adatom results from hopping processes on corrugated potential surface and is affected by surface vibrations of surface atoms. The rate of rare events such as hopping between lattice sites can be calculated by transition state theory. In order to include the interactions of the adatom with surface vibrations, it is assumed that the coordinates of adatom are coupled to the bath of harmonic oscillators whose frequencies are those of surface phonon modes. When nearest neighbor surface atoms are considered, we can construct Hamiltonians which contain terms for interactions of adatom with surface vibrations for the well minimum and the saddle point configurations, respectively. The escape rate constants, thus the surface diffusion parameters, are obtained by normal mode analysis of the force constant matrix based on the Hamiltonian. The analysis is applied to the diffusion coefficients of W, Ir, Pt and Ta atoms on the bcc(110) plane of W in the zero-coverage limit. The results of the calculations are encouraging considering the limitations of the model considered in the study.

구름계의 구름저항 및 표면파손현상의 실험적 고찰 (Investigation of rolling resistance and surface damage of rolling elements)

  • 차금환;김대은
    • 대한기계학회논문집A
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    • 제21권12호
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    • pp.2019-2028
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    • 1997
  • It has been well established that resistant force and wear that occur during rolling motion depend on several factors such as material type, hardness, subsurface microstructure, applied load, and speed. The purpose of this work is to investigate the effect of microstructure and the state of deformed layer on the rolling contact characteristics in dry and lubricated rolling contacts. The results of this work show that the rolling resistance behavior depends on the state of the deformed layer. Also, lubrication can reduce the plastic flow at the surface but may still have an effect on the subsurface strain. The cross-sectional view of the microstructure shows that surface traction has a difinite effect on the morphology of the surface region. That is, significant slip seems to have taken place between the ball than those of the dry rolling case. The surface generation effects were significantly less compared to the case of dry rolling contact.