• Title/Summary/Keyword: surface state

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Modification of Silica Nanoparticles with Bis[3-(triethoxysilylpropyl)]tetrasulfide and Their Application for SBR Nanocomposite (Bis[3-(triethoxysilylpropyl)]tetrasulfide에 의한 실리카 입자의 표면개질 반응과 SBR 나노 복합체 응용)

  • Ryu, Hyun Soo;Lee, Young Seok;Lee, Jong Cheol;Ha, KiRyong
    • Polymer(Korea)
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    • v.37 no.3
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    • pp.308-315
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    • 2013
  • In this study, we performed surface modification of silica nanoparticles with bis[3-(triethoxysilylpropyl)]tetrasulfide (TESPT) silane coupling agent to study the effects of treatment temperature, treatment time, and amount of TESPT used on the silanization degree with Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), elemental analysis (EA) and solid state $^{13}C$ and $^{29}Si$ cross-polarization magic angle spinning (CP/MAS) nuclear magnetic resonance spectroscopy (NMR). We found peak area of isolated silanol groups at $3747cm^{-1}$ decreased, but peak area of $-CH_2$ asymmetric stretching of TESPT at $2938cm^{-1}$ increased with the amount of TESPT from FTIR measurements. We also used universal testing machine (UTM) to study mechanical properties of styrene butadiene rubber (SBR) nanocomposites with 20 phr (parts per hundred of rubber) of pristine and TESPT modified silicas, respectively. The tensile strength and 100% modulus of modified silica/SBR nanocomposite were enhanced from 5.65 to 9.38MPa, from 1.62 to 2.73 MPa, respectively, compared to those of pristine silica/SBR nanocomposite.

Sprouting and Emergence Properties of Eleocharis kuroguwai Ohwi (올방개 괴경(塊莖)의 맹아(萌芽) 및 출현(出現) 특성(特性))

  • Lee, H.K.;Lee, I.Y.;Ryu, G.H.;Lee, J.O.;Lee, E.J.
    • Korean Journal of Weed Science
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    • v.14 no.4
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    • pp.233-238
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    • 1994
  • The experiment on sprouting and emergence properties of Eleocharis kuroguwai was conducted at laboratory and greenhouse conditions in 1993. Most of tubers had the apical dominance of buds at sprouting and had the competitive relationship for mesocotyl elongation. When pyrazosulfuron was applied on soil surface, all of apical buds were killed, but the first and second lateral buds survived to 50% and 90%, respectively, and the third lateral buds were almost at presprouted state. The tubers at 10-15cm deep soil emerged 1 week late and 35% low in emergence rate compared with the tubers at 2-5cm deep. As the plants emerged from the deep soil, the mesocotyl and the roots were distributed at deep soil more or less. Among the tubers buried at 10cm and 15cm deep soil, 25% and 30% respectively were not emergerd due to the suspension of mesocotyl elongation. Although the roots and shoots were removed from the tubers at the stage of 20cm high, all of mother tubers emerged again even 2 weeks late.

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Analysis of Flood Inundation using GIS (GIS를 이용한 홍수범람 분석)

  • Shim, Soon-Bo;Kim, Joo-Hun;Lim, Gwang-Seop;Oh, Deuk-Keun
    • Journal of the Korean Association of Geographic Information Studies
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    • v.6 no.1
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    • pp.132-142
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    • 2003
  • A significant deficiency of most computer models used for stream floodplain analysis, is that the locations of structures impacted by flood waters, such as roads, buildings, and bridges, cannot be effectively compared to the floodplain location. The purpose of this study is the integration of the HEC River Analysis System(HEC-RAS) with ArcView geographic information system to develop a regional model for floodplain determination and representation. Also this study presents to enable two- and three-dimensional floodplain mapping and analysis in the ArcView. The methodology is applied to a Yeoju of Kyunggi-do, located in South Han River Basin. A digital terrain model is synthesized from HEC-RAS cross-sectional data and a digital elevation model of the study area. The flood plain data developed in ArcView was imported into HEC-RAS where it was combined with the field surveyed channel data in order to construct full floodplain cross sections that reflected accurate channel and overbank data for the HEC-RAS model. The flood plain limits could be expressed more accurately on ArcView by using water level data to be computed in HEC-RAS program. The computed water surface elevations and information of cross-section must be manually plotted in order to delineate floodplains. The resulting of this study provided a good representation of the general landscape and contained additional detail within the stream channel. Overall, the results of the study indicate that GIS combined with HEC-RAS is proven to be very useful and efficient for the automatic generation of flood maps, and an effective environment for floodplain mapping and analysis.

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ARPES Study of Quasi-Two Dimensional CDW System CeTe2 (준이차원 전하밀도파 CeTe2의 각분해 광전자 분광 연구)

  • Kim, D.H.;Lee, H.J.;Kang, J.S.;Kim, H.D.;Min, B.H.;Kwon, Y.S.;Kim, J.W.;Min, B.I.
    • Journal of the Korean Magnetics Society
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    • v.20 no.5
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    • pp.173-177
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    • 2010
  • The electronic structure of charge-density-wave (CDW) system $CeTe_2$ has been investigated by using angle-resolved photoemission spectroscopy (ARPES). The clearly dispersive band structures are observed in the measured ARPES spectra, indicating the good quality of the single-crystalline sample employed in this study. The four-fold symmetric patterns are observed in the constant energy (CE) mappings, indicating the $2{\times}2$ lattice deformation in the Te(1) sheets. The observed CE images are similar to those of $LaTe_2$, suggesting that Ce 4f states have the minor contribution to the CDW formation in $CeTe_2$. This study reveals that the carriers near the Fermi level should have mainly the Te(1) 5p and Ce 5d character, that the Te(1) 5p bands contribute to the CDW formation, and that the Ce 5d bands cross the Fermi level even in the CDW state.

The Experimental Study on the Bond behavior of High strength concrete (고강도 콘크리트의 부착거동에 관한 실험적 연구)

  • Lee, Joon-Gu;Kim, Woo;Park, Kwang-Su;Kim, Dae-Joung;Lee, Wong-Chan;Kim, Han-Joung
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.04a
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    • pp.774-780
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    • 1999
  • The study of bond behavior between concrete and rebar has been performed for a long time. On this study, we tried to analysed variation of bond behaviors quantitatively with varying the strength of concrete. Bond stress which observed below the neutral surface of beam and at connecting part of beam and column is affected by various bond parameters. Resistance of deformed bars which embedded in concrete to the pullout force is divided 1) chemical adhesive force 2) frictional force 3) mechanical resistance of ribs to the concrete and these horizontal components of resistance is being bond strength. We selected the most common and typical variable which is concrete strength among various variables. So we used two kinds of concrete strength like as 25MPa(NSC) and 65MPa(HSC). Tension Test was performed to verify how bond behavior varied with two kinds of concrete strength. Concentration of bond stress was observed at load-end commonly in Tension Test of the initial load stage. At this stage stress distribution was almost coincident at each strength. As tension load added, this stress distribution had difference gradually and movement of pick point of bond stress to free-end and central section was observed. This tendency was observed at first and moving speed was more fast in NSC. At the preceeding result the reason of this phenomenon is considered to discretion of chemical adhesion and local failure of concrete around rebar in load-end direction. Especially, when concrete strength was increased 2.6 times in tension test, ultimate bond strength was increased 1.45 times. In most recent used building codes, bond strength is proportioned to sqare root of concrete compressive strength but comparison of normalized ultimate bond strength was considered that the higher concrete strength is, the lower safety factor of bond strength is in each strength if we use existing building codes. In Tension Test, in case of initial tensile force state, steel tensile stress of central cross section is not different greatly at each strength but tensile force increasing, that of central cross section in NSC was increased remarkably. Namely, tensile force which was shared in concrete in HSC was far greater than that of concrete in NSC at central section.

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Condition Evaluation of the Pavement Foundations Using Multi-load Level FWD Deflections (다단계 하중 FWD를 사용한 도로기초 상태평가 연구)

  • Park, Hee-Mun;Kim, Richard Y.;Park, Seong-Wan
    • Journal of the Korean Geotechnical Society
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    • v.19 no.6
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    • pp.261-271
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    • 2003
  • A condition evaluation procedure for the pavement foundations using multi-load level Falling Weight Deflectometer(FWD) deflections is presented in this paper. A dynamic finite element program incorporating a stress-dependent material model, was used to generate the synthetic deflection database. Based on this synthetic database, the relationships between surface deflections and critical responses, such as stresses and strains in base and subgrade layers, have been established. FWD deflection data, Dynamic Cone Penetrometer(UP) data, and repeated load resilient modulus testing results used in developing this procedure were collected from the Long Term Pavement Performance (LTPP) and North Carolina Department of Transportation (NCDOT) database. Research effort focused on investigation of the effect of the FWD load level on the condition evaluation procedures. The results indicate that the proposed procedure can estimate the pavement foundation conditions. It is also found that structurally adjusted Base Damage Index (BDI) and Base Curvature Index (BCI) are good indicators for the prediction of stiffness characteristics of aggregate base and subgrade respectively. A FWD test with a load of 66.7 kN or less does not improve the accuracy of this procedure. Results from the study for the nonlinear behavior of a pavement foundations indicate that the deflection ratio obtained from multi-load level deflections can predict the type and quality of the pavement foundation materials.

The prospective preliminary clinical study of open reduction and internal fixation of mandibular angle fractures using 2 miniplates (하악 우각부 골절 시 2개의 miniplate를 이용한 관혈적 정복술에 대한 전향적 예비 임상연구)

  • Yang, Seung-Bin;Jang, Chang-Su;Kim, Ju-Won;Yim, Jin-Hyuk;Kim, Jwa-Young;Yang, Byoung-Eun
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.36 no.4
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    • pp.320-324
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    • 2010
  • Introduction: The placement of a single miniplate is not sufficient to achieve rigid fixation in mandibular angle fractures. It often causes difficulties in reducing the intermaxillary fixation (IMF) period. Consequently, the placement of 2 miniplates is preferable. The intraoral approach in an open reduction and internal fixation (ORIF) of a mandibular angle fracture with 2 miniplates is often challenging. Accordingly, an alternative of transbuccal approach is performed. However, this method leaves a scar on the face and can result in facial nerve injury. This clinical study suggests a protocol that can maintain rigid fixation without a transbuccal approach in mandibular angle fractures. Materials and Methods: The subjects were 7 patients who sustained fractures of the mandibular angle and treated at Department of Oral and maxillofacial surgery, Sacred Heart Hospital, Hallym University. ORIF under general anesthesia was done using the intraoral approach. One miniplate was inserted on external oblique ridge of the mandible, and the other was placed on lateral surface of the mandibular body with contra-angle drill and driver. A radiographic assessment and occlusal contact point examination was carried out before surgery, and 2, 4 and 6 weeks after surgery. Results: The mean operation time was 80 minutes. Regarding the occlusion state, the number of contact points increased after surgery. Paresthesia and infection were reported to be complications before surgery. Conclusion: The placement of 2 miniplates using contra-angle drill for ORIF of mandibular angle fractures allows early movement of the mandible without IMF. We propose this approach to reduce the patients’discomfort and simplify the surgical procedure.

REGIONAL ODONTODYSPLASIA : CASE REPORT (국소적 치아 이형성증(Regional odontodysplasia)에 대한 증례)

  • Lee, Jae-Ho;Cho, Jae-Hyun;Kim, Ki-Dug;Choi, Byung-Jai
    • Journal of the korean academy of Pediatric Dentistry
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    • v.28 no.1
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    • pp.175-179
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    • 2001
  • Regional odontodysplasia is a relatively rare condition in which both enamel and dentin are hypoplastic and hypocalcified. The result is localized arrest in tooth development. The etiology of regional odontodysplasia is uncertain, but, disturbance in vascular supply, somatic mutation, latent virus infection, trauma, hyperpyrexia, irradiation, nutrition, metabolic disorders and hereditary transmission are supported to be etiologic factors. Females are more often affected than males. (1.4 : 1). The maxillary arch is more often affected than the mandibular arch with the maxillary left quadrant being the most commonly involved. Affected teeth are hypoplastic, typically discolored yellow or yellowish brown, smaller in size and display a variety of surface marking including pitting and grooving. Radiographically, the teeth affected have been described to have a "ghost like" appearance or "fuzzy" appearance. Pulp calcification and denticles may be present within the pulp chambers of the affected teeth. In it's case, a 2 years old male visited for a treatment of uneruption of lower right teeth. Partial eruption of lower right deciduous central incisor and unerupted deciduous lateral incisor, deciduous canine and deciduous first molar showed severly delayed eruption state. On radiographic appearance, "Ghost like appearance", shortened root and opened apexes on lower right region were observed. It was suspected regional odontodysplasia with clinical and radiographic condition.

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A Constitutive Model for Soil Using Mohr-Coulomb Criteria (Mohr-Coulomb식(式)을 사용한 흙의 구성(構成)모델)

  • Lee, Hyung Soo;Lee, Byung Dae
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.14 no.6
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    • pp.1405-1415
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    • 1994
  • The soil on the behavior of the nonlinear elastic work-hardening plasticity has a variety of stress paths due to the state of soil and the test conditions. The soil with a specific volume ${\upsilon}$ in principal stress space (${\sigma}_1$, ${\sigma}_2$, ${\sigma}_3$, and ${\upsilon}$v) displays the shape of an irregular hexagonal pyramid with an end cap. With variations of ${\upsilon}$ the size of the cap is changed but its shape remains unchanged and the movement of the cap is controlled by the increase or decrease of the plastic volumetric strain. By reflecting such a property of soil various cap models have been developed by researchers. In this thesis, a constitutive model of soil with a combination of the nonlinear elastic work-hardening plastic cap and the failure surfaces of Mohr-Coulomb (M-C cap model) has been developed. According to the the results of analyses using the work-hardening plastic cap model, the normally consolidated soil under shearing has experienced the work-hardening and plastic flow (movement of the cap). But in the shearing of the overconsolidated soil the elastic behavior is shown until the stress path has reached the failure surface and the cap does not move.

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Goral(Nemorhaedus caudatus) Habitat Suitability Model based on GIS and Fuzzy set at Soraksan National Park. (GIS와 퍼지집합을 이용한 산양(Nemorhaedus caudatus)의 서식지적합성모형 개발: 설악산 국립공원을 대상으로)

  • 최태영;양병이;박종화;서창완
    • Proceedings of the Korean Association of Geographic Inforamtion Studies Conference
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    • 2003.04a
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    • pp.472-477
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    • 2003
  • 멸종위기종의 서식지를 효율적으로 관리하기 위해서는 해당 종의 서식 가능한 지역의 분포를 알아야 한다. 본 연구의 목적은 GIS와 퍼지집합을 이용하여 산양(Nemorhaedus caudatus)의 서식지적합성모형을 개발하여 멸종 위기종의 서식지를 관리하기 위한 정보를 제공하는 것이다. 산양의 서식지적합성모형 개발을 위한 본 연구의 주요내용은 다음과 같다. 첫째, 산양 서식지 이용에 관한 기존 연구를 바탕으로 산양의 잠재적 서식지 환경변수를 분류하였으며, 분석 대상지의 산양 흔적 조사를 통해 서식지 환경변수의 재분류 및 x²검정(Chi-square test)을 통한 변수들의 유용성을 파악하고, 쌍체비교를 통한 환경변수별 가중치를 계산하였다. 둘째, 기존 부울논리(boolean logic)의 단점을 보완하기 위해 현장 조사의 결과를 바탕으로 퍼지논리(fuzzy logic)에 의한 산양 서식지의 각 환경변수별 주제도를 작성하고, 주제도들의 상관관계를 분석하여 상호 관련성이 높은 변수들의 중복을 피하였다. 셋째, 환경변수별 주제도와 변수별 가중치를 바탕으로 다기준평가기법(MCE, Multi-Criteria Evaluation)을 이용하여 분석대상지의 산양 서식지적합성모형을 개발하였다. 마지막으로, 개발된 서식지적합성모형의 타당성을 검증하기 위해 분석대상지 외부 지역을 대상으로 검증을 실시하였다. 분석 결과 분석대상지의 분류정확도는 서식가능성 0.5를 기준으로 93.94%의 매우 높은 분류정확도를 나타내었으며, 검증대상지에서는 95.74%의 분류정확도를 나타내어 본 모형의 분류정확도는 일관성이 높은 것으로 판단되었다. 또한 전체 공원구역에서 서식가능성 0.5이상의 면적은 59%를 차지하였다.퇴적이 우세한 것으로 관측되었다.보체계의 구축사업의 시각이 행정정보화, 생활정보화, 산업정보화 등 다양한 분야와 결합하여 보다 큰 시너지 효과와 사용자 중심의 서비스 개선을 창출할 수 있는 기반을 제공할 것을 기대해 본다.. 이상의 결과를 종합해볼 때, ${\beta}$-glucan은 고용량일 때 직접적으로 또는 $IFN-{\gamma}$ 존재시에는 저용량에서도 복강 큰 포식세로를 활성화시킬 뿐 아니라, 탐식효율도 높임으로써 면역기능을 증진 시키는 것으로 나타났고, 그 효과는 crude ${\beta}$-glucan의 추출조건에 따라 달라지는 것을 알 수 있었다.eveloped. Design concepts and control methods of a new crane will be introduced in this paper.and momentum balance was applied to the fluid field of bundle. while the movement of′ individual material was taken into account. The constitutive model relating the surface force and the deformation of bundle was introduced by considering a representative prodedure that stands for the bundle movement. Then a fundamental equations system could be simplified considering a steady state of the process. O

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