• Elastomers and Composites
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• 제45권1호
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• pp.2-6
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• 2010

탄소섬유/나일론 수지 복합재료의 계면결합력의 향상을 위해 폴리아크릴로니트릴(PAN)계 탄소섬유의 표면에 실란계, 설파이드계, 이미드계 계면결합제를 이용해서 사이징 처리를 수행하였으며, 사이징 처리된 탄소섬유의 젖음성과 표면자유에너지는 접촉각을 통해 확인하였다. 사이징 처리되어 제조된 복합재료의 기계적 계면물성은 임계응력세기인자를 통하여 확인하였으며, 파단실험 후 파단면은 주사전자현미경을 통해 관찰하였다. 실험결과 실란계로 사이징 처리된 탄소섬유가 다른 사이징 처리에 비해 표면자유에너지가 큰 것을 접촉각 측정을 통해 관찰하였다. 한편 사이징 처리된 탄소섬유 강화 나일론 복합재의 경우 미처리 탄소섬유를 이용한 복합재에 비해 높은 기계적 계면강도를 보였다. 이러한 결과는 섬유의 표면자유에너지가 탄소섬유와 나일론6 기지 사이의 계면결합력의 증대를 유도하여 복합재료의 기계적 계면강도가 증가된 것으로 판단된다.

• 폴리머
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• 제24권3호
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• pp.326-332
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• 2000

유리섬유/불포화 폴리에스터 복합재료에서 섬유에 처리된 사이징제가 복합재료의 최종 물성에 미치는 영향을 상온에서의 접촉각 측정을 통해 고찰하였다. 본 연구에서는 폴리비닐알코올, 폴리에스터, 그리고 에폭시계 사이징제를 사용하여 유리섬유의 표면을 처리하였으며 각각의 물성을 비교하였다. 유리섬유의 접촉각은 증류수와 diiodomethane을 젖음액으로 사용하여 Washburn식을 기본으로 한 wicking법으로 측정하였다. 결과적으로 접촉각 측정에 의해 구한 표면자유에너지는 에폭시계 사이징제로 치리된 유리섬유에서 최대값을 나타내었다. 복합재료의 층간 전단 강도 (ILSS)와 파괴 인성 ( $K_{IC}$ )의 측정 결과로부터 사이징제의 처리에 따라 계면 결합력이 증진되며 결과적으로 복합재료의 기계적 강도가 증가함을 알 수 있었다. 이것은 복합재료에서 유리섬유의 표면 자유에너지 증가에 기인한다고 사료된다.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2004년도 제30회 국제세미나
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• pp.19-42
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• 2004

Sizing properties in paper are generally developed through the application of both internal and surface sizes. Rosin, wax, and synthetic sizes including ASA, AKD, and stearic anhydride are and have been used to provide wet-end sizing to paper. In many cases, the use of some of these sizes leads to runnability problems that are inherent in the wet-end operation. Variability in furnish, fines, broke, filler, water chemistry, conductivity, and pH control impacts the wet-end operation. Size press chemicals including starch and polymers such as styrene-acrylic, styrene-maleic, and styrene acrylate emulsions are used in conjunction with internal sizes to improve the paper surface for printing and strength properties, porosity, and opacity improvement. This paper will discuss results from a new, proprietary formulation and process that allows application of sizing chemistry more totally at the size press with reduced emphasis on wet end sizing. Runnability issues are thus minimized at the wet-end, chemical usage is more efficient, and significant cost savings can be realized. Case histories will be presented illustrating the advantages of this new application in commercial trials.

• 펄프종이기술
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• 제40권3호
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• pp.9-14
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• 2008

Agar-agar extracted from red algae was used as a surface sizing material for paper after filtering, bleaching, and viscosity adjustment by oxidative depolymerization. Oxidized starches from corn and tapioca were compared to agar-based surface size in the respects of paper surface modification, strength improvement, and printability. Agar-based surface size showed high strength improvement and good printability as much as starch-based ones except film forming ability, which may be improved by adding additives, and demonstrated its great potential to be used as inexpensive and high quality surface size in future.

• 펄프종이기술
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• 제45권4호
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• pp.21-26
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• 2013

The effect of esterified starch as surface sizing agent for inkjet printing paper has been evaluated and compared with oxidized starch. Also the influence of various additives including cationic poly-DADMAC, stearic acrylic copolymer, calcium chloride, and GCC was examined. Results showed that starch ester gave higher ink density than oxidized starch. Addition of poly-DADMAC improved water fastness. In general, low molecular weight poly-DADMAC performed better than high molecular weight one, and it was attributed to the fact that it gave more uniform film forming characteristics in surface sizing. Use of styrene acrylic acid copolymer increased hydrophobicity of the paper surface, but it did not increase the ink density. Use of GCC and calcium chloride had only marginal effect on printing quality.

• 한국농공학회지
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• 제42권4호
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• pp.67-75
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• 2000

A simulation model for reservoir sizing was developed to be applied in a region with insufficient hydrological data. Reservoir storage balance equation was formulated on a monthly basis. Gajiyama equation was generalized to estimate monthly reservoir inflow more accurately. Monthly evaporation equation on a reservoir water surface was introduced , which was functioned with monthly mean temperature. Generalized Gajiyama equation was applied to estmate reservoir inflow of the Sayeon dam. Nash-Sutcliffe's model efficiency was 0.793. Using developed model for reservoir sizing, water supply capacity was analyzed with 118.000㎥/day on the Sayeon dam. This showed a reasonable result as compared with 110000㎥/day in other technical report. For general application of developed model, a virtual reservoir was considered and its dta of surface area and volume by elevation was prepared using DEM. Using the model, size of reservoir was determined and water supply capacity was anlayzed on a virtual reservoir.

• 보존과학회지
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• 제35권1호
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• pp.1-10
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• 2019

This study provides a comprehensive evaluation of general characteristics of sized silk fabrics for the painting purpose. Two particular types of silk fabrics used for painting background were compared: a recreation of historical material and a mass produced material of present day. The sizing process made the surface characteristics of the silk fabrics more suitable for painting. The dyeing properties of the fabrics were related to the surface area of the fabrics, and had no significant effect on their mechanical properties. The antibacterial activity of the tannin-based natural dyestuffs were maintained after the sizing. The performance assessment by the KES-FB system showed that the fabrics are more prone to deteriorate after the sizing because the glue layer receives the most of the physical stresses.

• Composites Research
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• 제31권6호
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• pp.299-303
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• 2018

탄소섬유 강화 PA6 복합재료의 탄소섬유-메트릭스간 계면결합력과 반응중합도 향상을 위해서 기존 탄소섬유의 에폭시 사이징제를 디사이징처리하여 에폭시를 제거한 후 우레탄계, 나일론계, 페녹시계 사이징제로 재처리해주었으며, 리사이징처리된탄소섬유의표면을관찰하였다. 리사이징처리된탄소섬유의계면결합력은 IFSS(Interfacial shear strength)를 통해서 확인하였으며, 계면 결합 강도 측정 후 파단면은 주사전자현미경을 통해서 관찰하였다. 나일론계와 페녹시계 사이징제로 처리된 탄소섬유가 우레탄계 사이징에 비해 계면 결합력이 상승한 것을 확인하였다. 우레탄계 리사이징 처리된 탄소섬유는 기존 에폭시 사이징 탄소섬유보다 계면 결합력이 감소한 것으로 확인되었다. 이 결과는 기존 탄소섬유의 저활성과 평활성을 제거하여 탄소섬유와 나일론6 사이의 계면 결합력이 향상된 것으로 판단된다.

• 펄프종이기술
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• 제44권2호
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• pp.18-28
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• 2012

This study was to develop a novel automatic system for measuring St$\ddot{o}$ckigt sizing degree and contact angle at a time. The conventional methods to measure sizing degree had serious problems in obtaining significant differences according to different dosages of a sizing agent, and moreover they disclosed unique limitation due to liquid types used and tester's subjectivity. However, the newly developed system could get reproducible results through total automation of all procedures including liquid dropping, image acquisition and measurement of both St$\ddot{o}$ckigt sizing degree and contact angle. For the St$\ddot{o}$ckigt sizing test, the automatic system could measure sizing degree with more definite differences according to different dosage of AKD, compared to the conventional method. For the contact angle test, the automatic system showed a similar trend to the conventional method but had smaller contact angles due to distortion of an image focus by a sheet curl than the conventional testing machine. The problem from the image out of focus due to specimen curl will be overcome with adopting a new specimen holder for the future system.

• 펄프종이기술
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• 제37권4호통권112호
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• pp.52-59
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• 2005

Most of printing paper market today have been occupied by western paper and some machine-made Hanji used don't show the characteristic advantages for traditional hand-made Hanji. Although hand-made Hanji has an aesthetic and qualitative value, it has limited uses because of poor printability as printing paper. Unlike western paper, conventional Hanji cannot be used as Printing paper because it is impossible to make the clear formation of printed dot and to develop a high level of sizing and picking problem occurs during printing. Improvements of physical and optical properties such as roughness, smoothness, air permeability, contact angle, opacity, and paper gloss as well as sizing level were accomplished through internal and surface sizing and calendering, which made the paper better suited for printing and decreased problems during printing.