• 한국전기전자재료학회논문지
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• 제15권8호
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• pp.678-686
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• 2002

This paper presents the effects of accumulation of surface charges on hydrophobic level and the changes of surface potential decay with various artificial environment treatments on high temperature vulcanized (HTV) silicone rubber used for outdoor insulating material. For this study, the charging apparatus by corona discharge, in which grid electrode was installed between the main corona and ground electrode, was used. From this study, it was found that the accumulation of surface charges above a critical surface potential on silicone insulating materials could lead to the temporary loss of surface hydrophobicity. In addition, corona stress and water absorption stress increase the decay rate of surface charges of HTV silicone rubber, while ultraviolet (UV) stress causes longer decay time. We could conclude that the effects of surface charges on hydrophobicity level and the changes of surface state by various artificial treatments were found through a trend of surface potential decay.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2003년도 춘계학술대회 논문집 유기절연재료 방전 플라즈마연구회
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• pp.1-5
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• 2003

This paper presented the effects of accumulation of surface charges on hydrophobicity level and the surface states of silicone polymer used for outdoor insulator treated by ultraviolet irradiation and corona discharge through measuring surface voltage decay of a corona-charged specimen were investigated. The surface resistivity by the method of the surface potential decay was compared with the value by the three electrodes methods. From this study, it was found that the accumulation of surface charges above a critical surface voltage on silicone insulating materials could lead to the temporary loss of surface hydrophobicity. In addtion, uv stress lead to a longer decay time of surface charges. We could conclude that the effects of surface charges on hydrophocity level and the changes of surface state by various artificial treatments were understood through a trend of surface potential decay.

• 전기학회논문지
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• 제59권12호
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• pp.2230-2234
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• 2010

This paper deals with the change of surface potential decay, surface resistivity, contact angle and XPS of ultraviolet-treated PET films. From the experimental results on the surface potential decay of UV degraded-samples, it was found that the accumulation of charge is decreased and the surface potential decay time is shortened. Also, from the result of XPS, it was found that the changes affected by the surface degradation of PET film were caused by the generation of carboxyl groups through the chain decomposition and recombination with oxygen molecules in the air.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제49권10호
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• pp.553-558
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• 2000

This paper deals with change of contact angle, surface potential decay, surface resistivity and XPS of water-treated epoxy insulator. From the experimental results on the contact angle was reduced from $74^{\circ}$to $24^{\circ}$ due to the formation of polar hydroxyl groups on surface which was associated with intermolecular reaction between epoxy chains of three-dimensional network structure and water molecules. From the experimental results in the surface potential decay of water treated-samples, it was found that the accumulation of charge is decreased and the surface potential decay time is shortened by the interaction of polar hydroxyl groups induced on the treated surface as the increment of treatment time. The positive charging on the treated surface compared with negative charging is relatively lowered by the induction of polar hydroxyl groups. The surface resistivity was changed from $10^{15}[{\Omega}/cm^2$] to $10^{12}[{\Omega}/cm^2$] caused by water treatment. From XPS, it was found that the changes affected by the surface degradation of epoxy were caused by the generation of carboxyl groups through the chain decomposition and recombination with oxygen molecules in the air.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2001년도 하계학술대회 논문집 C
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• pp.1457-1459
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• 2001

This paper deals with the change of surface Potential decay, surface resistivity, contact an91e and XPS of ultraviolet-treated PET films. From the experimental results on the surface Potential decay of UV degraded-samples, it was found that the accumulation of charge is decreased and the surface potential decay time is shortened. Also, from the result of XPS, it was found that the changes affected by the surface degradation of PET film were caused by the generation of carboxyl groups through the chain decomposition and recombination with oxygen molecules in the air.

• 전자공학회논문지 IE
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• 제44권3호
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• pp.6-11
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• 2007

본 연구는 플라즈마 처리한 고분자 복합재료 표면의 접촉각, X-선광전자분광법(XPS) 및 코로나 대전에 의한 표면 정전특성을 분석하여 발생된 화학적 변화와 정전적 특성 변화를 고찰하여 열화 메커니즘을 도출하였다. 플라즈마 처리된 시료의 접촉각 및 표면전위는 표면에 카르복실기 라디칼을 포함하는 다량의 측쇄화가 집중적으로 발생되어 처리시간에 따라 급격한 친수화가 진행되었다. 플라즈마 처리로 인한 화학적 변화에서 표면에 carboxyl 라디칼이 주로 형성되면서 급격히 표면 친수화로 변화하였다. 정전변화를 분석한 전위감쇠 결과에서 미처리 시료는 부극성 표면을 나타내었으나, 친수화 표면은 carboxyl 라디칼(-COO*)을 포함하는 정극성 라디칼로 인해 정극성 표면으로 변화하여 부극성 전하가 빠르게 감소하였다.

• 한국안전학회지
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• 제12권2호
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• pp.65-69
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• 1997

Especially, Fiber glass Reinforced Plastics(FRP) is the best composite insulating material which has been so far. Therefore, it's worthy of notice to investigate on the corona electrified composite insulating material by surface condition. And then some other materials will be focussed on. In this study, charge decay were measured with charging-time and grid voltage on FRP composite material surface in order to analyze the mechanism. As a result we have studied that the way of the composite glass fiber(GF) and Polymer and the condition of the contaminated surface was different. In case of the GF is mixed with vertical, charge decay speed is fast because the charge is easily leaked. On the other hand, the surface charge decay speed is depend on conductive or insulated of the contaminant.

• 한국전기전자재료학회논문지
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• 제14권10호
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• pp.821-827
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• 2001

In this study performed to identify a degradation mechanism in macromolecular insulating material, the contact angel, surface potential decay, surface resistivity, and XPS analysis were compared after exposure of FRP laminate to plasma discharge. In the case of contact angle, the surface of specimen untreated showed weak hydrophobic property of 73。. However, the contact angle was decreased to 20。in the plasma-treated specimen. In the case of chemical changes arising form plasma treatment, carboxl radicals were generated mainly in the surface treated, which was rapidly changed to the hydrophilic one. In the corona potential decay study to determine the electrical changes of the surface, positive charges were rapidly decreased when compared with negative charges, leading to negative property in the surface of specimen not treated. However, in the case of the hydrophilic surface, lots of carboxl radicals acting as positive polarity were generated, resulting in positive surface. Owing to such positive surface, charges of negative polarity applied were rapidly decreased.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제53권12호
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• pp.596-600
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• 2004

In this study, the surface properties of PET film were analyzed after plasma surface treatment. After plasma treatment of surface roughness and XPS were evaluated to analyze the chemical property, while the surface potential decay and surface resistance rate was measured to analyze the electric관 characteristic. When plasma discharge treatment was conducted for less than 10 minutes, the electrical insulating property was improved by evaporation of low molecular weight materials and cleaning of surface. However, when the treatment was conducted for more than 10 minutes, the insulating property was decreased due to excessive discharge energy. Analyses of chemical characteristics showed that 10-minute treatment resulted in increase of C-O and O=C-O bonds. However, when treated for more than 10 minutes. they were relatively decreased.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제48권2호
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• pp.86-91
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• 1999

In order to analyse the degradation process of epoxy/glass fiber for outdoor condition, FRP laminate was exposed to the wavelength of ultraviolet rays and evaluated by comparing contact angle, surface resistivity, surface potential decay, and ESCA spectrum respectively. As irradiation energy are increased, the surface properties were steeply decreased in the range of 300[nm]. But the measured values within the scope of400[nm]∼440[nm] showed a increase as compared with the untreated ones. Also, fromthe result of ESCA spectrum, it was confirmed plenty of oxygen groups on the spot showing the maximum decrease of surface properties and the existence of ether groups on the surface of coloring phase. We can conclude that the degradation phenomena on the surface of epoxy composites are dominated by the induction of ester and carboxyl groups.