• 대한전기학회:학술대회논문집
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• 대한전기학회 2000년도 학술대회 논문집 전문대학교육위원
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• pp.29-32
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• 2000

Ozone has been widely applied to many industrial fields because of its strong oxidation effects. Therefore, the studies have been progressed for the effective and high concentration of one generation. The silent or surface discharge have been mainly used for high concentration ozone generation until now. But these two types of ozone generators have shortcomings to be improved. In this study, the ozone generator which improved the shortcomings of above two type of ozone generators was proposed and manufactured for high concentration ozone generation. And the proposed ozone generator could generate the surface and barrier discharge simultaneously. For this purpose, a mesh type discharge electrodes were proposed and the experiments were fulfilled as a function of the widths and spacings of mesh electrodes and gap spacings between the dielectric barrier and mesh electrode. When the width of mesh electrode[WM] and spacing of mesh electrode[SM] are 0.3[mm] and 0.8[mm] respectively, the maximum ozone concentration of 2.96[vol%] was obtained at 5.6[kV], 830[mA], gap spacing (S)=0.65[mm].

• 한국대기환경학회지
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• 제25권1호
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• pp.57-74
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• 2009

In order to clarify the vertical ozone distribution in planetary boundary layer of coastal area with complex terrain, an observation campaign was carried out around Gwangyang Bay with dense pollutant emission sources during two days from June, 4 2007. For this observation are Radiosonde, SODAR(SOnic Detection And Ranging) and Tethered ozone sonde were employed. The surface meteorological and photochemical observation data provided by AWS (Automatic Weather System) and AQMS (Air Quality Monitoring System) were also applied for analysis. Synoptic condition is strongly associated with lower level ozone distribution in complex terrain coastal area. Since mesoscale circulation induced by difference of characteristics of land and sea and orographic forcing is predominant under calm synoptic condition, vertical distribution of ozone is complicate and vertical ozone concentration greatly fluctuated. However in second day when synoptic influence become strong, ozone concentration in lower levels is vertically uniform regardless of observation level. This results in vertical observation indicates that vertical ozone distribution is often determined by synoptic condition and also affects surface ozone concentration.

• Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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• 제4권3호
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• pp.127-137
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• 2000

This study presents an analysis of the characteristics of vertical ozone distribution near the surface using ozonesonde data(l995 to 1998), plus surface ozone and meteorological data from the Pohang region. These features were examined in detail using three case studies. The first related to episodes of high surface ozone concentrations during the Spring season when the frontogenesis between the high and low pressure associated with the upper-level jet stream was found to be located near the surface. The second was a 5-day winter period(l3 -17 December, 1997) in the Pohang province when the hourly concentrations exceeded 90 ppb on several occasions owing to low-level jets(LLJs) induced by a nocturnal stable layer. Accordingly, this explains why the high surface ozone concentrations occurred at night as the ozone was transported across the zone by a strong wind speed( over 12.5 ms .1). The third case study was ozone enhancement due to photochemical reactions. In this case, the maximum concentration of ozone exceeded 60 ppb in the summer(23 -28 August, 1997). When an ozone peak appeared within the boundary layer, the occurrence frequency of a low-level jet due to the nocturnal stable layer was about 77%, similarly the occurrence frequency of a near-surface ozone peak relative to the appearance of an LLJ was about 76%. Accordingly, there is clearly a close correlation between the occurrence of LLJs and near-surface ozone peaks.

• 한국환경과학회지
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• 제13권4호
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• pp.377-387
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• 2004

This study has been performed to clarify the characteristics of temporal and spatial distribution of surface ozone concentration over Jeju Island, one of the cleanest areas in Korea with low emissions of air pollutants. Ozone data are monitored at four sites in Jeju Island. These monitoring sites are located at two urban area(referred to Ido and Donghong), coastal area(Gosan site) and forest site(Chuna site). Ozone data has been routinely collected at these sites for the late four years. The patterns of seasonal cycle of ozone concentrations at all stations show the bimodal with the peaks on spring and autumn and a significant summer minimum. However, the patterns of diurnal variations at rural station, i.e., Gosan and Chuna sites are considerably different to those at urban stations such as Ido and Donghong sites. The patterns of $\DeltaO_3$ variations are very similar with those of monthly mean ozone concentrations and $\DeltaO_3$ values are exceeded 30 ppb, at urban stations. This may be that urban stations are more influenced by local photochemical reactions rather than rural stations. In order to assess the potential roles of meteorological parameters on ozone formation, the meteorological parameters, such as radiation, temperature, and wind are monitored together with ozone concentrations at all stations. The relationships of meteorological parameters to the corresponding ozone concentration are found to be insignificant in Jeju Island. However, at Gosan and Donghong stations, when the sea breeze blew toward the station, the ozone concentration is considerably increased.

• 한국환경과학회지
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• 제20권8호
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• pp.1049-1059
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• 2011

This paper examines the effects of the partial solar eclipse of 22 July 2009 across the Korean peninsular on surface temperature and ozone concentrations in over the Busan metropolitan region (BMR). The observed data in the BMR demonstrated that the solar eclipse phenomenon clearly affects the surface ozone concentration as well as the air temperature. The decrease in temperature ranging from 1.2 to $5.4^{\circ}C$ was observed at 11 meteorological sites during the eclipse as a consequence of the solar radiation decrease. A large temperature drop exceeding $4^{\circ}C$ was observed at most area (8 sites) of the BMR. Significant ozone drop (18~29 ppb) was also observed during the eclipse mainly due to the decreased efficiency of the photochemical ozone formation. The ozone concentration started to decrease at approximately 1 to 2 hours after the event and reached its minimum value for a half hour to 2 hours after maximum eclipse. The rate of ozone fall ranged between 0.18 and 0.49 ppb/min. The comparison between ozone measurements and the expected values derived from the fitted curve analysis showed that the maximum drop in ozone concentrations occurred at noon or 1 PM and was pronounced at industrial areas.

• 한국대기환경학회지
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• 제15권6호
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• pp.747-755
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• 1999

Effects of precipitation and cloud cover on high ozone days are examined by investigating the precipitation and average cloud cover before the ozone peak time within a day. High ozone days above 100 ppb in the Greater Seoul Area(GSA) for the ozone season from May to September are chosen for the analyses in terms of the surface meteorological data during 1990~1997. The result shows that the effect of precipitation on the rise of ozone concentration is definitely negative so that ozone concentration could not rise above 100ppb immediately after precipitation. But, the effect of cloud cover is associated with the variations of other meteorological parameters. The number of high ozone days with "zero" cloud cover is rather less than that with cloud cover of 1 to 4 since temperature is usually lower in "zero" cloud cover days. Furthermore, ozone concentration can rise above 100ppb even with full cloud cover when the wind is weak and the temperature is high.temperature is high.

• 상하수도학회지
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• 제18권5호
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• pp.656-665
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• 2004

An Ozone reaction model combined with CFD(Computational Fluid Dynamics) technique was developed in this research, in the simulation of ozonation, hydrodynamic behavior as well as reaction model is important because ozone is supplied to treated water as gas ozone. In order to evaluate hydrodynamic behavior in an ozone contactor, CFD technique was applied. CFD technique elucidated hydrodynamic behavior in the selected ozone contactor, which consisted of three main chambers. Three back-mixing zones were found in the contactor. The higher velocities of water were observed in the second and third compartments than that in the first compartment. The flow of the opposite direction to the main flow was observed near the water surface. Based on the results of CFD simulation, the ozone contactor was divided into small compartments. Mass balance equations were established were established in each compartment with reaction terms. This reaction model was intended to predict dissolved ozone concentration, especially. We concluded that the model could predict favorably the mass balance of ozone, namely absorption efficiency of gaseous ozone, dissolved ozone concentration and ozone consumption. After establishing the model, we discussed the effect of concentration of gaseous ozone at inlet, temperature and organic compounds on dissolved ozone concentration.

• 한국대기환경학회지
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• 제20권3호
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• pp.345-360
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• 2004

The late sea-breeze and its impacts on ozone distributions were investigated during April to September from 1998 to 2002, in the Busan metropolitan area (including surrounding areas) using the surface ozone concentrations (obtained at 9 monitoring sites), local meteorological variables (obtained near the shore), together with synoptic data. The urban scale ozone concentration was also simulated using the MM5/UAM-V to better understand the role of late sea-breeze in Busan. The results from observation study showed that most of the late sea-breeze occurred when weak offshore synoptic flow (northwesterly) suppressed development of sea - breeze, and the ozone concentration level and frequencies exceeding ozone standard increased with the onset time of sea breeze. We also found that the late sea-breeze clearly induces relatively weak wind speed and high temperature during the daytime As a result it enhances the photochemical ozone accumulation and delays the occurrence time of the averaged maximum ozone concentrations. The results of simulation for high ozone episode (24 August, 2001) by MM5/UAM -V revealed that the late sea-breeze interacted with weak offshore synoptic wind can contribute significantly to high ozone concentration in the coastal urban area. The simulated horizontal and vertical distribution of ozone concentration indicated that ozone can be accumulated over the sea under stagnant condition and return to the land in the late afternoon with the sea breeze, suggesting both the relationship between late sea-breeze and recirculation and the importance of late sea -breeze effects influencing severe ozone pollution in Busan.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제48권12호
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• pp.791-797
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• 1999

Recently the ozone generation system is well used for cleaning the contaminated water by using the strong oxidization effects of ozone. In this paper the concentration, yield and generation quantity of the ozone by the Surface-Silent Discharge According to the Length of Coaxial Electrode is described. The electrodes composed of 3 electrodes-2 gaps are coaxial type and the ozone generation tube were designed and fabricated from the point of view of the energy efficiency, stability and easy control. To investigate the ozone generation dependency on electrode length, a few discharge tubes with different lengths were fabricated. The experimental equipments were provided with cooling system and dehumidifier for the many testing conditions. The main results show that the concentration, yield and generation quantity of ozone are improved by decreasing gas temperatures and increasing electrode lengths.

• 한국대기환경학회지
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• 제11권3호
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• pp.253-262
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• 1995

A study has been performed on the characteristics of rural and urban surface ozone concentration for the period of March 1992 to February 1993. The monitoring station of rural ozone is located at Kosan, Cheju and other urban monitoring stations are located at Seoul, Pusan and Kwangju. Rural's and urban's ozone data exhibit a distinct features in many ways. First, annual mean of rural ozone concentration os very high(42 ppbv) but urban's are very low(10 .sim.15 ppbv). Second, rural ozone data shows a seasonal variation with it's maximum in spring, and minimum in summer, but urban's show a seasonal variation with it's maximum in spring, and minimum in winter. Third, diurnal variation of rural data is very small but that of urban's are very large. Fourth, urban's data are extremely low(< 3 ppbv) and have no seasonal variations.