• 한국세라믹학회지
• /
• 제35권4호
• /
• pp.347-354
• /
• 1998

Densification and grain growth behaviors of ITO ceramics were investigated as a function of TiO2 ad-ditions. TiO2 addition led to inhibition of the grain growth and promotion of the densification of ITO ceram-ics. From the microstructure observation it was found that the crack-like voids which were formed in pure ITO specimens decreased with increase of TiO2 additon. The grain growth exponent(n) was measur-ed to be 4 for pure ITO 3 for TiO2-doped ITO specimens respectively. It was supposed that the grain boun-dary migration of pure ITO ceramics was controlled by the pores which were moved by surface diffusion. On the contrary the grain boundary migration of TiO2-doped ITO specimens was depressed by solute drag effect. The activation energies for grain growth were measured to be 1013 kJ/mol for pure ITO ceramics and 460kJ/mol for TiO2-doped ITO specimens respectively.

• 한국표면공학회지
• /
• 제22권4호
• /
• pp.185-196
• /
• 1989

The surface modification of a mild and stainless steel by alumina sprayed coating were studied. The effects of surface roughness and bond coating layer on the adhesive strengthy and durability of sprayed specimens were also investiated. The adhesive strength of ceramic coating was affected by surface roughness and bond coating layer thinkness. That showed excellent undergrit blast time and bond coating layer; 60 sec and 0.15-0.33mm, respectively. The adhesive strength and densification of sprayed coating with air pressure were superior to those of without and fracture was mainly occured at alumina-bond coating interface. Under ambient atmosphere at $800^{\circ}C$, the oxides existed within bond coating layer promote diffusion of oxygen to lower durability of sprayed specimens. In this case, fracure was occured at sudstrate-bond coating interface.

• 한국표면공학회지
• /
• 제33권2호
• /
• pp.115-125
• /
• 2000

TiN films were deposited onto Stellite 6B alloy (Co base) by the reactive magnetron sputter ion plating. As the bias increases, TiN film changes from columnar structure to dense structure with great hardness and smooth surface due to densification and resputtering by ion bombardment. The content of oxygen and carbon impurities in the TiN film decreases greatly when the substrate bias is applied. The preferred orientation of the TiN films changes from (200) to (111) with decreasing $N_2$/Ar ratio, and from (200) to (111) and then (220) with increasing the substrate bias. The change of the preferred orientation is discussed in terms of surface energy and strain energy which are related to the impurity contents and the ion bombardment damage. The hardness of the TiN film increases with increasing compressive stress generated in the film by virtue of ion bombardment. It becomes as high as up to 3500kgf/mm$^2$ when an appropriate substrate bias is applied.

• 한국세라믹학회지
• /
• 제45권12호
• /
• pp.827-831
• /
• 2008

Spark plasma sintering (SPS) of AlN ceramics were carried out with ${Y_2}{O_3}$ as sintering additive at a sintering temperature $1,550{\sim}1,700^{\circ}C$. The effect of ${Y_2}{O_3}$ addition on sintering behavior and thermal conductivity of AlN ceramics was studied. ${Y_2}{O_3}$ added AlN showed higher densification rate than pure AlN noticeably, but the formation of yttrium aluminates phases by the solid-state reaction of ${Y_2}{O_3}$ and ${Al_2}{O_3}$ existed on AlN surface could delay the densification during the sintering process. The thermal conductivity of AlN specimens was promoted by the addition of ${Y_2}{O_3}$ up to 3 wt% in spite of the formation of YAG secondary phase in AlN grain boundaries because ${Y_2}{O_3}$ addition could reduced the oxygen contents in AlN lattice which is primary factor of thermal conductivity. However, the thermal conductivity rather decreased over 3 wt% addition because an immoderate formation of YAG phases in grain boundary could decrease thermal conductivity by a phonon scattering surpassing the contribution of ${Y_2}{O_3}$ addition.

• 한국분말재료학회지
• /
• 제22권4호
• /
• pp.283-288
• /
• 2015

Two sintering methods of a pressureless sintering and a spark-plasma sintering are tested to densify the Fe-TiC composite powders which are fabricated by high-energy ball-milling. A powder mixture of Fe and TiC is prepared in a planetary ball mill at a rotation speed of 500 rpm for 1h. Pressureless sintering is performed at 1100, 1200 and $1300^{\circ}C$ for 1-3 hours in a tube furnace under flowing argon gas atmosphere. Spark-plasma sintering is carried out under the following condition: sintering temperature of $1050^{\circ}C$, soaking time of 10 min, sintering pressure of 50 MPa, heating rate of $50^{\circ}C$, and in a vacuum of 0.1 Pa. The curves of shrinkage and its derivative (shrinkage rate) are obtained from the data stored automatically during sintering process. The densification behaviors are investigated from the observation of fracture surface and cross-section of the sintered compacts. The pressureless-sintered powder compacts show incomplete densification with a relative denstiy of 86.1% after sintering at $1300^{\circ}C$ for 3h. Spark-plasma sintering at $1050^{\circ}C$ for 10 min exhibits nearly complete densification of 98.6% relative density under the sintering pressure of 50 MPa.

• 한국분말재료학회지
• /
• 제25권5호
• /
• pp.426-434
• /
• 2018

In this study, $MgO-CaO-Al_2O_3-SiO_2$ (MCAS) nanocomposite glass powder having a mean particle size of 50 nm and a specific surface area of $40m^2/g$ is used as a sintering additive for AlN ceramics. Densification behaviors and thermal properties of AlN with 5 wt% MCAS nano-glass additive are investigated. Dilatometric analysis and isothermal sintering of AlN-5wt% MCAS compact demonstrates that the shrinkage of the AlN specimen increases significantly above $1,300^{\circ}C$ via liquid phase sintering of MCAS additive, and complete densification could be achieved after sintering at $1,600^{\circ}C$, which is a reduction in sintering temperature by $200^{\circ}C$ compared to conventional $AlN-Y_2O_3$ systems. The MCAS glass phase is satisfactorily distributed between AlN particles after sintering at $1,600^{\circ}C$, existing as an amorphous secondary phase. The AlN specimen attained a thermal conductivity of $82.6W/m{\cdot}K$ at $1,600^{\circ}C$.

• 자원리싸이클링
• /
• 제25권6호
• /
• pp.92-97
• /
• 2016

Spray dried $Cr_2O_3$ 분말은 겉보기밀도를 향상시키기 위해 plasma flame에 투입하여 실험을 진행 하였다. 첫번째 고밀도화 공정에서의 분말은 입자내부 공간까지 완전히 용해되어지지 않았으며, 두번째 공정 이후 완전히 용해가 되었다. 두번째 공정 결과 분말 입도는 작아졌으며, 용해 및 표면 연화에 의해 겉보기 밀도와 유동도는 향상이 되었다. 두번째 고밀도화 공정이 후 부분적으로 입자들이 $30{\mu}m$ 이상의 hollow structure을 보여주고 있다. 분말의 이러한 고밀도화는 plasma flame에 의해 응집되어진 응집체내의 열전도율 및 내부 가스압의 관점에서 정량적으로 논의 하였다.

• 한국펄프종이공학회:학술대회논문집
• /
• 한국펄프종이공학회 2006년도 PAN PACIFIC CONFERENCE vol.2
• /
• pp.485-488
• /
• 2006

Surface roughening which is occurred by interaction between base paper and water in coating color deteriorates surface properties of coated paper. In this study, the effect of calendering variables on surface roughening and the relationship between hot calendering and water penetration depth were investigated. BCTMP handsheets were calendered at the various conditions of temperature and linear load, and its PPS roughness was measured before and after moistening to evaluate surface roughening. To determine water penetration depth, thickness was measured from the cross sectional images of sheet which were obtained using CLSM technique. High pressure calendering was beneficial to reduce surface roughness before coating but its smoothening effect was mostly lost by contact with water. On the contrary, sheet calendered at the highest temperature showed the lowest roughening. High temperature calendering allowed the smallest penetration of water into fiber network because of sufficient deformation and densification in top side of z-direction of sheet. Consequently, hot calendering could be the effective way to reduce surface roughening and unevenness of paper surface.

• 한국분말재료학회지
• /
• 제10권6호
• /
• pp.374-382
• /
• 2003

During the sintering of powder materials, many these are microstructural phenomena are caused by atomic diffusion. (1) neck formation and compact densification, (2) grain growth, i.e., growth of matrix grains and dispersed grains, (3) alloying or generation of compound, (4) generations of peculiar and hard layers near sintered compact surface, etc. The studies of the present author and co-workers on these phenomena which were carried out during 40 years are briefly introduced.

• 한국표면공학회지
• /
• 제22권1호
• /
• pp.26-42
• /
• 1989

It has between investigated that the optimum spaying conditions, such as, spraying distance, fusing temperature and fusing time, ect, in a Ni-cr base self fluxing alloy sprayed on the mild steel substrate by oxygen-acetylenc flame spraying. Sprayed specimens on various conditions were fuused in a vacuum furnace and the results were as follows. The optimum spraying condition for excellent coating layer are obtained under spraying distances, fusing temperature and fusing and time ; 180~240mm,1050~110$0^{\circ}C$and 15~30min, respectively. The adhesive strength and surface hurface hardness of the as sprayed specimens were very low by mechanical bonding becaus of the diffusion layer during process. The carbides and borides and formed in the sprayed coating layer and densification of the layer was resulted from the elimination of pores and oxides. The hardness of sprayed coating layer, particularly in the high temperature, was superior to ordinary tool steels.