• Title/Summary/Keyword: surface charging

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Electrostatic Charging Measurement and PVC Separation of Triboeletrostatically Charged Plastic Particles using a Fluidized Bed Tribocharger

  • Shin, Jin-Hyouk;Lee, Jae-Keun
    • Journal of ILASS-Korea
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    • v.7 no.2
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    • pp.7-15
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    • 2002
  • A particle flow visualization, electrostatic charging measurement and separation of triboelectrically charged particles in the external electric field by a fluidized bed tribocharger are conducted for the removal of PVC particles from mixed waste plastics. The laboratory-scale triboelectrostatic separation system consists of the fluidized bed tribocharger, a separation chamber, a collection chamber and a controller. PVC and PET particles can be imparted negative and positive surface charges respectively due to the difference of triboelectric charging series between particles and particles in the fluidized bed tribocharger, and can be separated by passing them through an external electric field. To visualize these charged particles, He-Ne laser is used with cylindrical lenses to generate a sheet beam. In the charging measurement, the particle motion analysis system (PMAS), capable of determining particle velocity and diameter. is used to non-intrusively measure particle behavior in high strength electric field. The average charge-to-mass ratios of PVC and PET particles are $1.4\;and\;1.2{\mu}C/kg$, respectively. The highly concentrated PVC (91.9%) can be recovered with a yield of about 96.1% from the mixture of PVC and PET materials for a single-stage processing. The triboelectrostatic separation system using the fluidized tribocharger shows the potential to be an effective method for removing PVC from mixed plastics for waste plastic recycling.

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실리콘 기판위의 증착된 AAO Barrier Layer의 $Cl_2/BCl_3$ Neutral Beam Etching

  • Kim, Chan-Gyu;Min, Gyeong-Seok;O, Jong-Sik;Yeom, Geun-Yeong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2011.05a
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    • pp.135-136
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    • 2011
  • 본 연구에서는 실리콘 기판위의 형성된 AAO (Anodic Aluminum Oxide)의 barrier layer를 $Cl_2/BCl_3$ gas mixture에서 Neutral Beam Etching (NBE)과 Ion Beam Etching (IBE)로 각각 식각한 후 그 결과를 비교하였다. 이온빔의 경우 나노사이즈의 AAO pore의 charging에 의해 pore 아래쪽의 위치한 barrier layer를 어떤 식각조건에서도 제거하지 못하였다. 하지만, charging effect가 없고, 높은 중성화율을 나타내는 low angle forward reflected 방식의 neutral beam etching (NBE)에서는 $BCl_3$-rich $Cl_2/BCl_3$ gas mixture인 식각조건에서 AAO pore에 휘발성 $BO_xCl_y$를 형성하면서 barrier layer를 제거할 수 있었다.

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Improved Properties of Li4Ti5O2 (LTO) by Surface Modification with Carbon Nanotube (CNT) (CNT 첨가를 통해 표면 처리한 LTO의 특성향상에 관한 연구)

  • Park, Soo-Gil;Kim, Cheong;Habazaki, Hiroki
    • Journal of the Korean institute of surface engineering
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    • v.49 no.2
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    • pp.191-195
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    • 2016
  • Among the lithium metal oxides for hybrid-capacity, $Li_4Ti_5O_{12}(LTO)$ is an emerging electrode material as zero-stain material in volume change during the with the charging and discharging processes. However, LTO has a limitation of low ionic and electronic conductivity. To enhance the ionic and electronic properties of $Li_4Ti_5O_{12}(LTO)$, we synthesized the spherical LTO/CNT composite by sol-gel process for hybrid capacitors. CNT interconnection networks between CNT-LTO particles enhanced electronic conductivity and electrochemical charging/discharging properties. All of the LTO samples was observed to show the spinel structure and spherical morphology with the diameter of $5{\sim}10{\mu}m$. Especially, spherical LTO/CNT composite of the CNT-3 wt% showed the enhanced capacity from 110 mAh/g to 140 mAh/g at 10 C.

The Hydrogen Behavior of Surface Layers of High Strength DP Thin Sheet Steels for Automobile (자동차 박강판용 고강도 DP강 표면층의 수소거동)

  • Park, Jae-Woo;Kang, Kae-Myung
    • Journal of the Korean Institute of Gas
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    • v.14 no.6
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    • pp.38-43
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    • 2010
  • According to the lack of resources and the stringency of environmental regulations, a study of the high strength thin plate sheet steels for automobile have been become an important issue for automobile industry. However, the problem of hydrogen embrittlement of high strength sheet steels was concerned with the degradation of mechanical properties. Therefore, we studied the hydrogen behavior of surface layers of 590MPa DP sheet steels on development using by relationship the microstructure of subsurface and the distribution of micro hardnesses. Hydrogen was charged into the specimens using by the cathodic electrolytic method. The behavors of under surface layers were investigated by the observation of microstructures and the micro vickers hardness test with the amount of hydrogen charging with hydrogen charging conditions.

SURFACE POTENTIAL DISTRIBUTION ON POLYMER INSULATORS

  • Kitani, Isamu
    • Electrical & Electronic Materials
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    • v.11 no.11
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    • pp.17-21
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    • 1998
  • The surface potential distribution on insulating polymers was measured by scanning of the probe of an electrostatic voltmeter. The measurements were done for two measured by scanning of the probe of an electrostatis voltmeter. The measurements were done for two cases. In the first case, it was measured on the free surface of insulating films which had been inserted between plane electodes after the removal of the upper brass disk electrode. In the second case, we measured the charging region between a circular and its opposing concentric ring electrodes after the removal of dc ramp voltage in air and nitrogen gas.

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Numerical and Experimental Study on the Increase of Removal Efficiency of SO2 in a Laboratory Scale Electrostatic Spray Drying Absorber (실험실 규모 정전기 분무형 반건식 세정기의 SO2 제거효율 향상에 대한 계산 및 실험적 연구)

  • Byun, Young-Cheol;Hwang, Jung-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.22 no.8
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    • pp.1111-1120
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    • 1998
  • Spray Drying Absorber(SDA) system, where the combustion product gas is mixed with atomized limestone-slurry droplets and then the chemical reaction of $SO_2$ with alkaline components of the liquid droplets forms sulfates, has been widely used to eliminate $SO_2$ gas from coal fired power plants and waste incinerators. Liquid atomization is necessary because it can maximize the reaction efficiency by increasing the total surface area and dispersion angle of the alkaline components. First, numerical calculations using FLUENT are carried out to investigate $SO_2$ concentration distribution and thus to calculate $SO_2$ removal efficiency. So to attain the optimized spray conditions, then an electrostatic spraying system is set up and spray visualization is performed to show the effect of an electric field on overall droplet size. Next, the effect of an electric field on the concentrations of $SO_2$ is experimentally examined. Field strength is varied from -10 kV to 10 kV and configurations of conduction charging and induction charging are utilized. Consequently, the electrostatic removal efficiency of 501 increases about 30% with the applied voltage of ${\pm}10kV$ but is independent of polarity of the applied voltage. It Is also found that the conduction charging configuration results in higher efficiency of $SO_2$ removal that the induction charging configuration. Finally, the effect of slurry temperature on $SO_2$ removal is studied. The temperature influences on the electrostatic removal efficiency of $SO_2$.

Effects of Surface Charges on Hydrophobicity and Surface Potential Decay with Various Surface States of Silicone Rubber for Outdoor Insulator (옥외용 실리콘 절연재료의 발수성에 미치는 표면전하의 영향과 표면 상태에 따른 표면전위 감쇠)

  • 연복희;박충렬;허창수
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.8
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    • pp.678-686
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    • 2002
  • This paper presents the effects of accumulation of surface charges on hydrophobic level and the changes of surface potential decay with various artificial environment treatments on high temperature vulcanized (HTV) silicone rubber used for outdoor insulating material. For this study, the charging apparatus by corona discharge, in which grid electrode was installed between the main corona and ground electrode, was used. From this study, it was found that the accumulation of surface charges above a critical surface potential on silicone insulating materials could lead to the temporary loss of surface hydrophobicity. In addition, corona stress and water absorption stress increase the decay rate of surface charges of HTV silicone rubber, while ultraviolet (UV) stress causes longer decay time. We could conclude that the effects of surface charges on hydrophobicity level and the changes of surface state by various artificial treatments were found through a trend of surface potential decay.

Surface Characterization of Silicone Rubber for Outdoor Insulation by Measurement of Surface Voltage Decay

  • Youn, Bok-Hee;Huh, Chang-Su;Cho, Han-Gu
    • KIEE International Transactions on Electrophysics and Applications
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    • v.12C no.4
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    • pp.214-219
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    • 2002
  • The influence of ultraviolet (UV) irradiation and corona on the surface degradation of high temperature vulcanized (HTV) silicone rubber used for outdoor insulation through measuring surface voltage decay after corona charging, surface resistivity, contact angle and X-ray photoelectron spectroscopy (XPS) analysis was studied. The surface resistivity calculated by the surface voltage decay was compared with a value directly obtained from the three electrode method having the guard ring electrode. A good agreement between the two methods for surface resistivity was obtained. UV treated specimens showed the slower decrease of surface voltage decay, while the corona exposed specimens showed a dramatically faster decrease. Although both artificial treatments cause the same oxidative products, which was confirmed with XPS, we could distinguish the difference between the reactions of the two treatments by monitoring the surface voltage decay on corona-charged specimen. In addition, we could derive the specific surface states of the silicone rubber treated by accelerated artificial aging factors and the degradation process.

Surface Charcterization of plasma-treated silicone insulating materials (플라즈마 처리된 실리콘 절연재의 표면 특성화)

  • Song, J.Y.;Huh, C.S.;Youn, B.H.;Lee, T.H.;Yoo, H.C.;Seo, Y.J.;Lee, K.T.;Kim, N.R.;Lee, U.H.
    • Proceedings of the KIEE Conference
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    • 2002.11a
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    • pp.176-178
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    • 2002
  • Surface states of silicone polymer treated by plasma were investigated by the analysis by x-ray photoelectron spectroscopy(XPS) and surface voltage decay after corona charging. Plasma treatment causes the silica -like oxidative layer, which was confirmed with XPS, and lowers surface resistivity with increasing the plasma treatment time. Using the decay time constant of surface voltage, the calculated surface resistivity was compared with the value directly measured by voltage-current method using three electrodes system. A good agreement between two methods was obtained. In addition, we estimated the thermal activation energy for surface conduction, Based on our results, we could understand the relationship between surface chemical states and surface electrical properties.

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