• Journal of Environmental Health Sciences
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• v.38 no.6
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• pp.568-574
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• 2012

Objectives: The purpose of this experiment is to understand the phosphorus removal ratio effects of iron plates per unit of surface area through the iron electrolysis system, which consists of an anoxic basin, aerobic basin, and iron precipitation apparatus. Methods: Iron electrolysis, which uses an iron precipitation reactor in anoxic and oxic basins, consisted of iron plates with total areas of 400 $cm^2$, 300 $cm^2$ and 200 $cm^2$ respectively. The FNR process was operated with a hydraulic retention time and a sludge retention time of 12 hours and three days, respectively. Wastewater used in the experiments was prepared by dissolving $KH_2PO_4$ in influent water. Results: The iron plates 400 $cm^2$ (16.6 $mA/cm^2$), 300 $cm^2$ (13.3 $mA/cm^2$) and 200 $cm^2$ (7.3 $mA/cm^2$) in surface area in the phosphorus reactor had respective phosphorus of 2.4 mg/l, 2.7 mg/l and 3.2 mg/l in the effluent and phosphorus removal respective efficiencies of 90.3%, 89.1% and 87.1%. The effluent in the reactor, where the iron plate was not used, had relatively very low phosphorus removal efficiency showing phosphorus concentration of 15.3 mg/l and a phosphorus removal efficiency about 38.3%. Phosphorus removal per ferrous was 0.472 mgP/mgFe in the iron electrolysis system where the surface area of iron was low. Phosphorus pollution load per active surface area and the phosphorus removal efficiency had an interrelation of RE = -0.27LS + 89.0 (r = 0.85). Conclusion: With larger iron plate surface area, the elution of iron concentration and phosphorus removal efficiency was higher. The removal efficiency of phosphorus has decreased by increasing the initial phosphate concentration in the iron electrodes. This shows a tendency of decreasing phosphorus removal efficiency because of decreasing of iron deposition as the phosphorus pollution load per active surface area increases.

• Clean Technology
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• v.27 no.3
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• pp.240-246
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• 2021

The waste etching solution for chip on film (COF) contained about 3.5% copper, and it was recovered through cementation using iron samples. The effect of cementation with plate, chip, and powder iron samples was investigated. The molar ratio (m/r) of iron to copper was used as a variable in order to increase the recovery rate of copper. As the molar ratio increased, the copper content in the solution rapidly decreased at the beginning of the cementation reaction. Before and after the reaction, the copper content of the solution was determined by Inductively Coupled Plasma (ICP) using copper concentration according to time. After cementation at room temperature for 1 hour, the recovery rate of copper had increased the most in the iron powder sample, having the largest specific surface area of the samples, followed by the chip and plate samples. The recovered copper powder was characterized for its crystalline phase, morphology, and elemental composition by X-ray diffraction (XRD), scanning electron microscopy (SEM), and Energy-dispersive X-ray spectroscopy (EDS), respectively. Copper and unreacted iron were present together in the iron powder samples. The optimum condition for recovering copper was obtained using iron chips with a molar ratio of iron to copper of 4 giving a recovery rate of about 98.4%.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.6
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• pp.581-586
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• 2018

Cast iron manhole lids cause environmental pollution during the manufacturing process, and the work environment is very poor. In addition, if the height of the manhole cover does not match the height of the road surface, it causes considerable inconvenience and safety problems. This study proposes a height - adjustable steel manhole cover that can replace cast iron manhole covers and easily match the road surface with the upper surface of the manhole cover. Structural analysis was performed to grasp the design variable of the structure of the manhole cover, satisfying the required quality performance. To fabricate a manhole cover that satisfies the required load capacity, the optimal design for the U-shaped reinforcement structure was made. The cylindrical shape of the height adjustment part and the low frame were formed by bending the steel sheet into a circular shape and then welding. Reinforcing bars were also made by bending a steel plate. The height adjustment groove was machined by a CNC milling machine. Four prototypes were fabricated and a load bearing test was carried out, and new manhole cover was made reflecting results of the test. In the load bearing test, there was no breakage of the welded part, and deformation occurred mainly at the contact area between the groove and gusset plate. Deformation of 1 to 2.7mm occurred due to a load of 450kN. On the other hand, after removing the load, there was almost no residual deformation, and the load bearing evaluation was judged to be satisfactory because the manhole cover could be disassembled and reassembled.