• Title/Summary/Keyword: surface area expansion rate

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Effects of Salix subfragilis communities on water quality in Namgang Dam reservoir (남강댐 선버들 군락이 수질에 미치는 영향)

  • Kim, Ki Heung
    • Journal of Korea Water Resources Association
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    • v.55 no.12
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    • pp.1065-1076
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    • 2022
  • The purpose of this study was to investigate the effect of the expansion and withering of Salix subfragilis communities on the water quality in Namgang Dam reservoir. The distribution area of the Salix subfragilis communities was 0.12 km2 in 2003 for the first time, but it was 3.58 km2 in 2019, which has increased rapidly by about 30 times in 16 years. However, in 2013, the distribution area has decreased by 0.17 km2 due to long-term immersion in high turbidity, and self-thinning in Salix subfragilis communities. The lake characteristics of reservoir showed a combination of lake type and river type in terms of average water depth, watershed area/lake surface area ratio, water residence time, flushing rate, and stratification. From the result of analyzing long-term changes in lake water quality, COD, TP, and chlorophyll-a in Salix subfragilis communities were significantly larger than those in the three points located in the central part of reservoir. In particular, the fact that the value of chlorophyll-a showed the maximum value in winter rather than summer, unlike the trend of the three points in the Namgang Dam water quality monitoring network, is thought to have occurred internally rather than externally. It can be estimated that one cause of this deterioration of the water quality in Namgang Dam reservoir is the huge amount of nutrients generated in the decomposition process of by-products such as fallen leaves, branches and withered trees in Salix subfragilis communities.

Engineering Properties of Mylonite in the Youngju Area (영주지역 압쇄암의 공학적 특성 연구)

  • Kim, Sung-Wook;Choi, Eun-Kyeong;Yang, Tae-Sun;Lee, Kyu-Hwan
    • Journal of the Korean Geotechnical Society
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    • v.27 no.10
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    • pp.35-43
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    • 2011
  • The area to be studied is the place where the main line rail way will be constructed in accordance with the scheduled construction project of Yeongju dam, and is a fold and mylonite zone over several km that is formed by ductile-shearing effect. The ductile shear zone, which has been transformed by faulting for long geological time, shows a complicated geological structure. Due to the recrystallization of mineral caused by transformation in deep underground (>8km), a mylonite zone with lamellar structure has properties distinguished from other fault zones formed by transformation near earth surface <2km). To see the properties of mylonite, this study analyzed the transformation rate of sample rocks and the shape of constriction structure accompanied with transformation. While the transformation of fault zone shows a round oblate, the mylonite zone shows a prolate form. Transformation rate in fault zone was measured to be less than 1.2 compared to the state before transformation while the measured rate in mylonite zone was 2.5 at most. Setting the surface of discontinuity as the base, the unconfined compressive strength of slickenside can be categorized in sedimentary rocks, and a change of strength was observed after water soaking over certain time. Taking into account that the weathering resistance of the rock based on mineral and chemical organization is relatively higher, its engineering properties seems to result from the shattered crack structure by crushing effect. When undertaking tunnel construction in mylonite zone, there should be a special care for the expansion of shattered cracks or the fall of strength by influx of ground water.

Eruptive mechanisms and processes at Udo tuff cone, Udo Island, Korea (우도응회과의 분출기기구와 분출과정)

  • Hwang, Sang-Koo
    • The Journal of the Petrological Society of Korea
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    • v.1 no.2
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    • pp.91-103
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    • 1992
  • Eruptive mechanisms and processes at Udo tuff cone can be inferred from indicative characters of products, bedforms and lithofacies, and ring faults. In terms of bedforms and lithofa-cies in particular, massive lapilli tuff beds and chaotic lapilli tuff beds are derived from subaerial falls of aggregated tephra of wet tephra finger jets, occurring dominantly at the lower sequences of proximal part at the tuff cone. Crudely stratified lapilli tuff are derived from subaerial falls of slightly aggregated tephra of less wet tephra finger jets, whereas reversely graded lapilli tuff beds are from slightly disaggregated subaerial falls of continuous uprush. Both beds frequently occur in the middle sequences at proximal and near medial part of the tuff cone. Block and lapilli tephra lenses, ash-coated lapilli tephra beds(lenses) and thin-bedded tuff beds are derived from extremely disaggregated subaerial falls of dry tephra in the continuous uprush, frequently occurring at the upper sequences of medial part at the tuff cone. Udo tuff cone is a basaltic volcano emergent through the sea water surface while water could flood across or into the vent area. Emergence of the tuff cone was from the type-Surtseyan eruption characterized by earlier tephra finger jets and later continuous uprush columns of tephra with copious volumes of steam. Explosions began when boiling of wter produced a bubble column reducing the hydrostatic pres-sure, allowing exsolution of gases from the magma. This expansion of magma into a vesiculating froth fragmented the magma and permitted mixing of magma and water so that a more vigorous generation of steam could proceed. Tephra finger jetting explosions continued to build the crater rims, then remove water from the vent that their deposits flowed like slsurries until the continuous uprush explosion ensued. Continuous uprush explosions were associated with most rapid accumula-tion of tephra. The increasing volume rate led to partial removal of water from the vent area by the newly tephra ring so that more vigorous activity could be attended by a reducing water supply. This might restrain surplus of cold water entering the vent and thus enhance the vigour of the eruption by allowing optimal heat exchange. Eventually the crater became so deep and unsuported that piecemeal sliding, or massive subsidence on indipping ring faults, filled and closed the vent, and the cycle of explosions and collapse began anew.

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A Study on the Cobalt Electrodeposition of High Aspect Ratio Through-Silicon-Via (TSV) with Single Additive (단일 첨가제를 이용한 고종횡비 TSV의 코발트 전해증착에 관한 연구)

  • Kim, Yu-Jeong;Lee, Jin-Hyeon;Park, Gi-Mun;Yu, Bong-Yeong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.140-140
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    • 2018
  • The 3D interconnect technologies have been appeared, as the density of Integrated Circuit (IC) devices increases. Through Silicon Via (TSV) process is an important technology in the 3D interconnect technologies. And the process is used to form a vertically electrical connection through silicon dies. This TSV process has some advantages that short length of interconnection, high interconnection density, low electrical resistance, and low power consumption. Because of these advantages, TSVs could improve the device performance higher. The fabrication process of TSV has several steps such as TSV etching, insulator deposition, seed layer deposition, metallization, planarization, and assembly. Among them, TSV metallization (i.e. TSV filling) was core process in the fabrication process of TSV because TSV metallization determines the performance and reliability of the TSV interconnect. TSVs were commonly filled with metals by using the simple electrochemical deposition method. However, since the aspect ratio of TSVs was become a higher, it was easy to occur voids and copper filling of TSVs became more difficult. Using some additives like an accelerator, suppressor and leveler for the void-free filling of TSVs, deposition rate of bottom could be fast whereas deposition of side walls could be inhibited. The suppressor was adsorbed surface of via easily because of its higher molecular weight than the accelerator. However, for high aspect ratio TSV fillers, the growth of the top of via can be accelerated because the suppressor is replaced by an accelerator. The substitution of the accelerator and the suppressor caused the side wall growth and defect generation. The suppressor was used as Single additive electrodeposition of TSV to overcome the constraints. At the electrochemical deposition of high aspect ratio of TSVs, the suppressor as single additive could effectively suppress the growth of the top surface and the void-free bottom-up filling became possible. Generally, copper was used to fill TSVs since its low resistivity could reduce the RC delay of the interconnection. However, because of the large Coefficients of Thermal Expansion (CTE) mismatch between silicon and copper, stress was induced to the silicon around the TSVs at the annealing process. The Keep Out Zone (KOZ), the stressed area in the silicon, could affect carrier mobility and could cause degradation of the device performance. Cobalt can be used as an alternative material because the CTE of cobalt was lower than that of copper. Therefore, using cobalt could reduce KOZ and improve device performance. In this study, high-aspect ratio TSVs were filled with cobalt using the electrochemical deposition. And the filling performance was enhanced by using the suppressor as single additive. Electrochemical analysis explains the effect of suppressor in the cobalt filling bath and the effect of filling behavior at condition such as current type was investigated.

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Application of the Surface Cover Materials for Reduction of NPS Pollution from Actual Cultivation (실경작지 밭의 비점오염물질 저감을 위한 지표피복재 적용)

  • Shin, Min Hwan;Jang, Jeong Ryeol;Jung, Young Hun;Kum, Dong Hyuk;Won, Chul Hee;Lee, Su In;Lim, Kyoung Jae;Choi, Joong Dae
    • Journal of The Korean Society of Agricultural Engineers
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    • v.56 no.3
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    • pp.31-38
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    • 2014
  • Four actual cultivations were prepared and a variety of soybean was cultivated. A H-flume, an automatic water level gauge and an automatic water sampler were installed at the outlet of each plot equipped for the measurement of flow rate and its water quality. The amount of rainfall of the study area in 2013 was measured as 975.6 mm which was much lower than the annual average rainfall of 1,271.8 mm, resulting in less occurrences in rainfall-runoff events. Rainfall-runoff events were occurred three times during the rainfall event of 4~5 July, 23 and 24 August. The characteristics of NPS pollution discharge of the plots and the reduction effect of the selected BMPs were analyzed during these events. The reduction effect of straw mat and soil amendments (Polyacrylamide (PAM) and Gypsum) on runoff ratio ranged between 38.2 and 92.9% (average 71.6%). The NPS pollution load reduced between 27.7 and 95.1% (average 70.0%) by the application of rice straw mat and soil conditioner when compared with that of control plot. Soybean yield (2,133.3 kg/ha) of the straw mat covered plots increased by 14.3% when compared with control (1,866.7 kg/ha). The effect of straw mat on the yield was not economically viable if the material and accompanying labor costs were considered. The data collected and analyzed on different soil textures and crops in this study are expected to be a fundamental reference for the expansion of the results to the application nationwide and the development of NPS pollution management policies.

Performance of Heat Pump Water Heater with Dual Condenser (2단 응축 히트펌프 온수시스템의 사이클 해석 및 성능분석)

  • Ryou, Y.S.;Kim, Y.J.;Kang, G.C.;Paek, Y.;Yun, J.H.;Kang, Y.G.;Lee, H.M.
    • Journal of Biosystems Engineering
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    • v.31 no.5 s.118
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    • pp.423-429
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    • 2006
  • The heat pump water heater developed in this research consisted of one evaporator, one compressor, 1st condenser, 2nd condenser, one expansion valve, one water tank, one recirculation circuit and etc. The performance of heat pump water heater was tested and analyzed. The quantities of output water changed linearly from 2380 to $660{\ell}/h$, and the output water temperature changed curvedly from 29.9 to $44.5^{\circ}C$ when the opening rate of recirculation valve changed from 0 to 100%. The COP of heat pump water heater increased from 3.0 to 3.8 when the quantities of output water changed from 660 to $2380{\ell}/h$. When the temperature distributions of water tank were measured during 50 minutes after turning on the heat pump, the temperature stratification by the level appeared apparently. When the inlet water temperature changed from 30 to$50^{\circ}C$, the output energy of heat pump hardly changed. The surface area of double pipe heat exchanger changed from 0.429 to $6.254m^2$ when the compressor capacity increased from 1.0 to 50.0 PS.

Comparison of study affecting the use of dental sealant in consequence of its inclusion in the National Health Insurance coverage: Using data from the 5th-7th National Health and Nutrition Examination Survey(KNHANES) (치면열구전색 급여화에 따른 치면열구전색 수혜 비교 연구: 국민건강영양조사 제5기~7기 자료를 활용하여)

  • Kim, Mi-Jeong;Lim, Cha-Young;Son, Ju-Lee
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.12
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    • pp.798-806
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    • 2020
  • Dental sealant is a procedure to prevent dental caries on the occlusal surface of healthy teeth. Raw data from the 6th-7th Korean National Health and Nutritional Examination Survey (KNHANES) were analyzed. This study was conducted to provide basic data which is necessary for the national health care project and for expanding the standards of coverage for the Dental sealant procedure. In this study, subjects were a total of 4,366 children from the age of 6 to 18 and surveyed for the Amount of Received Dental sealant and rate of Received Dental sealant. In 2012, the coverage rate for pit and fissure sealing procedures differed significantly in terms of age, residential area and average monthly income. This coverage varied as per average monthly income in 2014 and as per age and average monthly income in 2017 (P < 0.05). In 2014, average monthly income had a significant influence on the coverage rate, while age and average monthly income had a significant influence on it in 2017 (P < 0.05). These findings suggest that in order to increase the sealing procedure coverage, continuous promotion of dental sealant projects, reduction of copayments, inclusion of varied tooth types and age groups, expansion of coverage to isolated areas and inclusion of socially disadvantaged groups are necessary.

Long-term Changes of Bathymetry and Surface Sediments in the dammed Yeongsan River Estuary, Korea, and Their Depositional Implication (영산강 하구의 수심 및 표층 퇴적물 특성의 변화와 퇴적환경)

  • KIM, YOUNG-GIL;CHANG, JIN HO
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.22 no.3
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    • pp.88-102
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    • 2017
  • Long-term changes in bathymetry and grain size of surface sediments were investigated for understanding depositional sedimentary environments in the channelized Yeongsan River Estuary, Korea. The results revealed that an average depth of the estuary had decreased up to 2.1 m from 1982 to 2006, while it had increased to 0.3 m from 2006 to 2012. The rapid decrease of the water depth from 1982 to 2006 was due to the vast deposition of mud caused by the change of water course and flow velocity after the estuary was dammed. Meanwhile the increase of the water depth from 2006 to 2012 may be associated with multiple erosional processes, including a dredging at the southern part of the estuary and other erosions from the dike sluice expansion work. Considering the water-depth change and tidal-level variation in the study area, an depositional rate in the estuary is estimated to be 8~9 cm/yr for the last 2 decades (1982~2006). The sediments of Yeongsan River Estuary are largely composed of silt-clay mixtures: overall, silt is distributed mainly in the shallow area of the estuary edge, while clay is confined to the deep area of the estuary center. Mean grain size of the sediments is 6.0 Ø on average in 1997, 7.8 Ø on average in 2005 and 7.7 Ø on average in 2012, respectively, suggesting that the sediments became finer due to the increase of silt and clay contents in 1997~2005. Furthermore, several lines of evidences, including the comparison between the amounts of the sediment influx discharged from the Yeongsan River and the sediments in the estuary, and the changes in distribution pattern of silt and clay contents implying that they moved from offshore to estuary dike, indicate that the mud sediments are originated mainly from the offshore, not from the river.

Synthesis and Electrochemical Properties of Porous Li4Ti5O12 Anode Materials (기공구조로 제조된 Li4Ti5O12 음극활물질의 전기화학적 특성)

  • Seo, Jin-Seong;Na, Byung-Ki
    • Korean Chemical Engineering Research
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    • v.57 no.6
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    • pp.861-867
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    • 2019
  • $Li_4Ti_5O_{12}$ is a promising next-generation anode material for lithium-ion batteries due to excellent cycle life, low irreversible capacity, and little volume expansion during charge-discharge process. However, it has poor charge capacity at high current density due to its low electrical conductivity. To improve this weakness, porous $Li_4Ti_5O_{12}$ was synthesized by sol-gel method with P123 as chelating agent. The physical characteristics of as-prepared sample was investigated by XRD, SEM, and BET analysis, and electrochemical properties were characterized by cycle performance test, cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS). $Li_4Ti_5O_{12}$ synthesized by 0.01mol ratio of P123/Ti showed most unified particle size, high specific surface area, and relatively high porosity. EIS analysis showed that depressed semicircle size was remarkably reduced, which suggested resistance value in electrode was decreased. Capacity in rate performance showed 178 mAh/g at 0.2C, 170 mAh/g at 0.5C, 110 mA/h at 5C, and 90 mAh/g at 10C. Capacity retention also showed 99% after rate performance.

Characterization of SEI layer for Surface Modified Cathode of Lithium Secondary Battery Depending on Electrolyte Additives (전해질 첨가제에 따른 graphite 음극의 SEI분석 및 전기 화학적 특성 고찰)

  • Lee, Sung Jin;Cha, Eun Hee;Lim, Soo A
    • Journal of the Korean Electrochemical Society
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    • v.19 no.3
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    • pp.69-79
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    • 2016
  • Lithium ion battery with high energy density is expanding its application area to electric automobile and electricity storage field beyond existing portable electric devices. Such expansion of an application field is demanding higher characteristic and stable long life characteristic of an anode material, the natural graphite that became commercialized in lithium ion battery. This thesis produced cathode by using natural graphite anode material, analyzed creation of the cathode SEI film created due to initial reaction by using electrolyte additives, VC (vinylene carbonate), VEC (vinyl ethylene carbonate), and FEC (fluoroethylene carbonate), and considered correlation with the accompanying electrochemical transformation. This study compared and analyzed the SEI film variation of natural graphite cathode according to the electrolyte additive with SEI that is formed at the time of initial filling and cathode of $60^{\circ}C$ life characteristic. At the time of initial filling, the profile showed changes due to the SEI formation, and SEI was formed in No-Additive in approximately 0.9 V through EVS, but for VC, VEC, and FEC, the formation reaction was created above 1 V. In $60^{\circ}C$ lifespan characteristic evaluation, the initial efficiency was highest in No-Additive and showed high contents percentage, but when cycle was progressed, the capacity maintenance rate decreased more than VC and FEC as the capacity and efficiency at the time of filling decreased, and VEC showed lowest performance in efficiency and capacity maintenance rate. Changes of SEI could not be verified through SEM, but it was identified that as the cycle of SEI ingredients was progressed through FT-IR, ingredients of Alkyl carbonate ($RCO_2Li$) affiliation of the $2850-2900cm^{-1}$ was maintained more solidly and the resistance increased as cycle was progressed through EIS, and specially, it was identified that the resistance due to No-Additive and SEI of VEC became very significant. Continuous loss of additives was verified through GC-MS, and the loss of additives from partial decomposition and remodeling of SEI formed the non-uniform surface of SEI and is judged to be the increase of resistance.