• 한국농림기상학회지
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• 제23권4호
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• pp.198-221
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• 2021

1960-70년대 대규모 산림녹화 이후에 한국의 산림은 점차 노령화되고 있다. 노령림의 순 CO₂ 교환은 이론적으로 중립에 가깝지만, 교란이나 관리에 의해 CO₂ 흡원 또는 발원이 될 수 있다. 본 연구는 한국의 광릉 낙엽활엽수 노령림(GDK)의 CO₂ 수지 역학을 이해함으로써, 다음 두 가지 질문에 답하고자 하였다: (1) 보전되고 있는 GDK는 과연 이론적으로 알려져 있는 CO₂ 중립인가? (2) 관측된 CO₂ 수지의 경년 변동이 문헌에 보고된 조절 인자들과의 선형적인 인과관계로 설명이 가능한가? 이에 답하기 위해, 본 연구는 KoFlux GDK 관측지에서 에디 공분산 기술로 2006년부터 2020년까지 15년 동안 관측된 CO₂ 플럭스 자료와 생기상학적 자료를 분석하였다. 연구 결과, (1) GDK는 15년 자료를 평균해서 보면 약한 CO₂ 발원이며, 관측기간 동안 흡원과 발원 사이를 오갔으나 최근 5년 동안 CO₂ 발원으로서의 강도가 증가하고 있다. (2) 전천일사, 생장기간, 엽면적지수의 경년 변동은 총 일차생산량(Gross Primary Production, GPP)의 경년변동과 양의 상관관계(R²=0.32~0.45)가 있는 반면, 기온과 지표면 온도의 경년 변동은 생태계 호흡(Ecosystem Respiration, RE)의 경년 변동과 유의한 상관관계가 없었다. 또한, 관측기간 초반(첫 10년)의 CO₂ 플럭스와 기상요인 및 생물학적 요인으로 학습시킨 기계학습은 관측기간 후반(최근 5년)의 GPP와 RE의 경년 변동을 제대로 모사해내지 못했다. 단, 고사목에서 배출된 탄소 추정량이 CO₂ 발원으로의 전환에 일부 기여했을 것으로 추정된다. GDK의 장기 CO₂ 수지 역학에 대해 올바로 이해하고 해석하기 위해서는, 분석과 모델링을 위한 복잡계과학 기반의 새로운 프레임워크가 필요하다. 더불어, 플럭스 모니터링 및 자료 품질 유지와 함께 고사목과 교란을 지속적으로 모니터링하는 것이 중요함을 다시 한 번 확인하였다.

• 신재생에너지
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• 제16권3호
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• pp.27-34
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• 2020

This study involved a total budget analysis on the greenhouse gas (GHGs) emissions of landfills, focusing on surface emissions and the effect on emissions reductions of generating landfill gas (LFG) electricity from March 7, 2007 to December 31, 2018. The GHGs reduction effect from the electricity generation using 536.6 × 10³ tCO₂ of CH₄ was only 5.8% of the GHGs from surface emissions of 9,191 × 10³ tCO₂. In the total budget, the collection ratio should be over 95% if the reduction effect is greater than the surface emissions. The correlation coefficient for the relationship between the LFG collection ratio and GHGs reduction was -0.89. An additional effect of lowering CH₄ content may occur if the surface emitting flux of LFG decreased with an increase in the collection ratio. The unit reduction effect of GHGs by suppressing surface emissions was 4174 tCO₂/TJ. This was far greater than that of LFG power generated (54.3 tCO₂/TJ), demonstrating that surface emission control is the most important measure by which to mitigate GHGs emission.

• 한국기후변화학회지
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• 제7권3호
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• pp.249-256
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• 2016

Porous $Al_2O_3$ hollow fiber membranes were successfully prepared by dry-wet spinning/sintering method. The SEM image shows that the $Al_2O_3$ hollow fiber membrane consists mostly of sponge pore structure. The contact angle and the breakthrough pressure were $126^{\circ}$ and 1.91 bar, respectively. This results indicate that the $Al_2O_3$ hollow fiber membranes were successfully modified to hydrophobic surface. The hydrophobic modified $Al_2O_3$ hollow fiber membranes were assembled into a membrane contactor system to separate $CO_2$ from a model gas mixture of the flue gas at elevated gas velocity. The $CO_2$ absorption flux was enhanced when the gas velocity increased from $1{\times}10^{-3}$ to $6{\times}10^{-3}$ m/s. Whereas the $CO_2$ absorption flux was decreased with the number of hollow fiber membrane of a module because of the concentration polarization. Furthermore, we developed an lab-scale $Al_2O_3$ hollow fiber membrane contactor modules and their system (i.e., $CO_2$ absorption using the $Al_2O_3$ membrane and monoethanolamine (MEA)) that could dispose of over $0.02Nm^3/h$ mixture gas (15% $CO_2$) with the removal efficiency higher than 95%. The results can be useful in a field of the membrane contactor for $CO_2$ separation, helping to design and extend a equipment.

• 한국농림기상학회지
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• 제10권3호
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• pp.82-93
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• 2008

보다 자동화된 방법으로 신뢰성 있는 난류 플럭스의 자료를 생산하기 위해서 Hong and Kim(2002)의 난류 품질 관리 프로그램을 개선하고 개선된 프로그램을 광릉산림에 적용하여 복잡한 산림지역에서 난류 플럭스의 특성을 조사하였다. 개선된 프로그램을 이용하여 2005년 1월부터 5월까지 광릉 수목원에 위치한 주 타워의 두 고도(20m와 40m)에서 관측된 난류 자료에 대하여 품질 검사를 실시하였다. 개선전과 비교해 개선된 프로그램은 이상점(outlier)에 해당되는 자료들을 많이 제거하였다. 자료의 품질체계는 4등급(Good, Dubious, Missing, Bad)으로 분류하였으며 본 분석에서 사용된 기간의 자료 중 25%는 결측이었고(Missing 등급), 60%는 Good 등급으로 분류되었다. 고도 별로는 40m에서 관측된 자료가 20m에서 관측된 자료보다 Bad 등급의 자료수가 적었는데 이는 20m가 식생 꼭대기에 인접한 거칠기 아층에 해당하고 또한 풍속도 더 낮은데 기인한다. Bad 등급으로 분류된 자료의 주원인은 낮은 풍속으로 나타났다. 분석 기간 동안의 에너지 수지의 닫힘은 약 40%로 나타났고 이러한 에너지 불균형의 부분적인 이유로는 열 저장항들이 고려되지 않은 점, 토양열 플럭스 측정의 불확실성, 복잡한 지형 등에 의한 국지풍에 의한 이류 등이 복합적으로 작용했을 것으로 생각된다. 광릉에서 발생하는 상향 운동량 플럭스는 국지풍의 발달 시 높은 발생률을 보여 이 둘이 밀접히 관련되어 있음을 나타낸다. 야간에 낮은 음의 $CO_2$ 플럭스가 발생하는 경우에 대하여 평균 시간을 증가시킴에 따른 $CO_2$ flux의 변화를 조사한 결과 평균시간이 10분 이상 증가함에 따라 $CO_2$ flux의 절대값이 빠르게 증가하는 경향을 보였다. 이는 야간에 $CO_2$ 플럭스는 중규모 운동이나 비정상성(nonstationarity) 등의 영향을 많이 받고 있음을 시사한다. 그러므로 야간에 보다 정확한 난류 플럭스 값을 산출하기 위해서는 평균시간의 적절한 조절이 필요할 것으로 보인다.

• 한국수소및신에너지학회논문집
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• 제14권1호
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• pp.17-23
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• 2003

$H_2$ permeation flux though a $100{\mu}m-thick$ Pd-Ru (6wt%) membrane was measured at various temperatures and pressures. The permeation flux followed the Sievert's law and thus the rate-limiting step of the hydrogen permeation was the bulk atomic diffusion step. The activation energy of the permeation flux was obtained at 17.9 kJ/mol and this value is consistent with those published previously. While no degradation of the permeation flux wasfound in the membrane exposed to the $O_2$ and $CO_2$ environments for 100 hours, the membrane exposed to $N_2$ environment for 100 hours showed the degradation in the $H_2$ permeation flux. The $H_2$ permeation was decreased as the exposure temperature to $N_2$, environment was increased. The $H_2$ permeation flux was fully recovered after the membrane was kept in the $H_2$ environment for certain time. The permeation flux degradation might be caused by the formation of metal nitride on the membrane surface.

• 한국대기환경학회지
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• 제27권3호
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• pp.313-325
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• 2011

From October 2009 to June 2010, major greenhouse gases (GHG: $N_2O$, $CH_4$, $CO_2$) soil emission were measured from upland cabbage field at Kunsan ($35^{\circ}$56'23"N, $126^{\circ}$43'14"E), Korea by using closed static chamber method. The measurements were conducted mostly from 10:00 to 18:00LST during field experiment days (total 28 days). After analyzing GHG concentrations inside of flux chamber by using a GC equipped with a methanizer (Varian CP3800), the GHG fluxes were calculated from a linear regression of the changes in the concentrations with time. Soil parameters (e.g. soil moisture, temperature, pH, organic C, soil N) were also measured at the sampling site. The average soil pH and soil moisture were ~pH $5.42{\pm}0.03$ and $70.0{\pm}1.8$ %WFPS (water filled pore space), respectively. The ranges of GHG flux during the experimental period were $0.08\sim8.40\;mg/m^2{\cdot}hr$ for $N_2O$, $-92.96\sim139.38mg/m^2{\cdot}hr$ for $CO_2$, and $-0.09\sim0.05mg/m^2{\cdot}hr$ for $CH_4$, respectively. It revealed that monthly means of $CO_2$ and $CH_4$ flux during October (fall) were positive and significantly higher than those (negative value) during January (winter) when subsoil have low temperature and relatively high moisture due to snow during the winter measurement period. Soil mean temperature and moisture during these months were $17.5{\pm}1.2^{\circ}C$, $45.7{\pm}8.2$%WFPS for October; and $1.4{\pm}1.3^{\circ}C$, $89.9{\pm}8.8$ %WFPS for January. It may indicate that soil temperature and moisture have significant role in determining whether the $CO_2$ and $CH_4$ emission or uptake take place. Low temperature and high moisture above a certain optimum level during winter could weaken microbial activity and the gas diffusion in soil matrix, and then make soil GHG emission to the atmosphere decrease. Other soil parameters were also discussed with respect to GHG emissions. Both positive and negative gas fluxes in $CH_4$ and $CO_2$ were observed during these measurements, but not for $N_2O$. It is likely that $CH_4$ and $CO_2$ gases emanated from soil surface or up taken by the soil depending on other factors such as background concentrations and physicochemical soil conditions.

• 방사성폐기물학회지
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• 제19권1호
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• pp.133-140
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• 2021

This study evaluates the radioactivity of concrete waste that occurs due to large amounts of decommissioned nuclear wastes and then determines the surface dose rate when the waste is packaged in a disposal container. The radiation assessment was conducted under the presumption that impurities included in the bio-shielded concrete contain the highest amount of radioactivity among all the concrete wastes. Neutron flux was applied using the simplified model approach in a sample containing the most Co and Eu impurities, and a maximum of 9.8×104 Bq·g-1 60Co and 2.63×105 Bq·g-1 152Eu was determined. Subsequently, the surface dose rate of the container was measured assuming that the bio-shield concrete waste would be packaged in a newly developed disposal container. Results showed that most of the concrete wastes with a depth of 20 cm or higher from the concrete surface was found to have less than 1.8 mSv·hr-1 in the surface dose of the new-type disposal container. Hence, when bio-shielded concrete wastes, having the highest radioactivity, is disposed in the new disposal container, it satisfies the limit of the surface dose rate (i.e., 2 mSv·hr-1) as per global standards.

• 한국세라믹학회지
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• 제44권8호
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• pp.424-429
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• 2007

Novel conductive $CO_2$ membranes composed of dual phases, molten carbonates and electronic conducting ceramics, were investigated. As the microstructure control of electronic conducting ceramic supports is extremely important to keep the molten carbonates stable in the membranes by a capillary force applied by the pore structure of the supports, we have scrutinized the microstructure of the electronic conducting supports utilizing microscopic images and gas permeability measurement. From the evaluation of the electrical conductivities of the molten carbonates and the electronic conducting ceramic supports, we found that the ionic conductivity of the molten carbonates could determine $CO_2$ flux through the dual phase membranes if the surface exchange rate were relatively high enough.

• 한국세라믹학회지
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• 제50권6호
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• pp.485-488
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• 2013

A SiC-$CeO_2$ composite membrane was successfully fabricated using an ally-hydridopolycarbosilane (AHPCS) binder and treated by dip-coating at 60 times with a $CeO_2$ sol solution. The dip-coated SiC membrane was calcined at 773 K and then sintered at 1173 K under an air atmosphere. The coated membrane was characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM) and a BET surface analysis. The difference in permeation performance between $H_2$ and CO gases was measured by varying the temperature. The permeation flux of $H_2$ on the SiC membrane with layered $CeO_2$ was obtained as $8.45{\times}10^{-6}\;mol/m^2sPa$ at room temperature. The CO permeation flux was $2.64{\times}10^{-6}\;mol/m^2sPa$ at room temperature. The reaction enthalpy (${\Delta}H^{\circ}$) for the hydrogen permeation process was calculated as -7.82 J/mol by Arrhenius plots.

• 대한용접접합학회:학술대회논문집
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• 대한용접접합학회 2010년도 춘계학술발표대회 초록집
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• pp.51-51
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• 2010

Recently just as in the automobile industry, shipbuilders also try to reduce material consumption and weight in order to keep operating costs as low as possible and improve the speed of production. Naturally industry is ever searching for welding techniques offering higher power, higher productivity and a better quality. Therefore it is important to have a details research based on the various welding process applied to steel and other materials, and to have the ability both to counsel interested companies and to evaluate the feasibility of implementation of this process. Submerged-arc welding (SAW) process is usually used about 20% of shipbuilding. Similar to gas metal arc welding(GMAW), SAW involves formation of an arc between a continuously-fed bare wire electrode and the work-piece. The process uses a flux to generate protective gases and slag, and to add alloying elements to the weld pool and a shielding gas is not required. Prior to welding, a thin layer of flux powder is placed on the work-piece surface. The arc moves along the joint line and as it does so, excess flux is recycled via a hopper. Remaining fused slag layers can be easily removed after welding. As the arc is completely covered by the flux layer, heat loss is extremely low. This produces a thermal efficiency as high as 60% (compared with 25% for manual metal arc). SAW process offers many advantages compared to conventional CO2 welding process. The main advantages of SAW are higher welding speed, facility of workers, less deformation and better than bead shape & strength of welded joint because there is no visible arc light, welding is spatter-free, fully-mechanized or automatic process, high travel speed, and depth of penetration and chemical composition of the deposited weld metal. However it is difficult to application of thin plate according to high heat input. So this paper has been focused on application of the field according to SAW process for thin plate in ship-structures. For this purpose, It has been decided to optimized welding condition by experiments, relationship between welding parameters and bead shapes, mechanical test such as tensile and bending. Also finite element(FE) based numerical comparison of thermal history and welding residual stress in A-grade 3.2 thickness steel of SAW been made in this study. From the result of this study, It makes substantial saving of time and manufacturing cost and raises the quality of product.