• Bulletin of the Korean Chemical Society
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• 제16권3호
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• pp.238-243
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• 1995

A pulsed molecular beam source having short pulse duration (typically 70 ${\mu}s)$ and narrow velocity distribution (${\Delta}$v/v=8% for helium) has been costructed utilizing a commercial fuel injector. Beam characteristics of helium and ammonia seeded in helium expansions are accomplished by the use of an electron impact time-or-flight mass spectrometer. The comparisons between experimental data and theoretical calculations show that the proper beam speed is important to predict the evolution of stream temperature and valve shutter function. The decreasing tendency of pulse duration with increasing cluster size leads to the conclusion that the cluster beam property is described as a function of cluster mass and disinct cluster temperature.

• Bulletin of the Korean Chemical Society
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• 제33권3호
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• pp.993-996
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• 2012

We investigated fluorescence and fluorescence excitation of diphenylsilane (DPS) in a solution and molecular beams in combination with the aid of the DFT method. When the molecule was photoexcited at 250 nm in a cyclohexane solution, normal and excimer fluorescences were observed in the ranges of 260-320 and 330-450 nm, respectively. The fluorescence excitation spectrum indicates that the channel leading to the intramolecular excimer formation is not efficient in comparison with the normal fluorescence. Vibrationally resolved fluorescence excitation spectra were measured for the DPS molecules cooled in pulsed supersonic expansion of He in the range 262.2-271.7 nm, in which we can see several electronic excitation spectra exhibiting the electronic band origins. We found that the simulated absorption spectrum based on the time-dependent densityfunctional theory calculations accords well with the absorption spectrum.

• 천문학회보
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• 제43권1호
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• pp.45.1-45.1
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• 2018

Formation of filaments and subsequent dense cores in ISM is one of the essential questions to address in star formation. To investigate this scenario in detail, we recently started a molecular line survey namely 'Filaments, the Universal Nursery of Stars (FUNS)' toward nearby filamentary clouds in Gould Belt using TRAO 14m single dish telescope equipped with a 16 multi-beam array. In the present work, we report the first look results of kinematics of a low mass star forming region L1478 of California molecular cloud. This region is found to be consisting of long filaments with a hub-filament structure. We performed On-The-Fly mapping observations covering ~1.1 square degree area of this region using C18O(1-0) as a low density tracer and 0.13 square degree area using N2H+(1-0) as a high density tracer, respectively. CS (2-1) and SO (32-21) were also used simultaneously to map ~290 square arcminute area of this region. We identified 10 filaments applying Dendrogram technique to C18O data-cube and 13 dense cores using FellWalker and N2H+ data set. Basic physical properties of filaments such as mass, length, width, velocity field, and velocity dispersion are derived. It is found that filaments in L~1478 are velocity coherent and supercritical. Especially the filaments which are highly supercritical are found to have dense cores detected in N2H+. Non-thermal velocity dispersions derived from C18O and N2H+ suggest that most of the dense cores are subsonic or transonic while the surrounding filaments are transonic or supersonic. We concluded that filaments in L~1478 are gravitationally unstable which might collapse to form dense cores and stars. We also suggest that formation mechanism can be different in individual filament depending on its morphology and environment.