• Title/Summary/Keyword: superplasticizer

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Application of Cold Weather Concreting with Accelerator for Freeze Protection to Full Scale Structures (내한촉진제를 사용한 한중콘크리트의 실구조물 적용에 관한 연구)

  • Kim, Young-Jin;Baek, Tae-Ryong;Lee, Sang-Soo;Won, Chul;Kim, Dong-Seok
    • Journal of the Korea Concrete Institute
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    • v.15 no.2
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    • pp.254-262
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    • 2003
  • In this study, the results of applying cold weather concreting mixed with Accelerator for Freeze Protection(AFP) to full scale structures are presented. Since the determination of W/C and amount of AFP significantly have an effect on strength gain and protection of frost damage in early, a full investigation is needed to determine these values at stage of nux design. The flowability of fresh cold weather concreting with AFP was similar to the same W/C. Lower loss of workability and initial slump flow of concrete using superplasticizer of polycarboxylic ester than that of melamine sulphonate showed that polycarboxylic ester was more effective on elapsed time. Temperature histories of specimens located in insulation boxes at the site was similar to that of structures. Thus, it is cleared that simple adiabatic curing method is effective for evaluating in-place concrete strength than specimens cured by sealing method. The investigation results of development of compressive strength of cold weather concreting included AFP with curing methods by logistic curves indicated that AFP can be effective to gain strength at lower temperature than normal curing temperature. In field testing, vinyl sheets were placed over the concrete sections and AFP enabled concrete to gain $5N/{mm}^2$ to protect frost damage in early ages and specified compressive strength of concrete at 28 days under average temperature of $-2^{\circ}C$ (lowest temperature was $-12^{\circ}C$) during site application.

A Study on Durability of High Strength Concrete (고강도(高强度)콘크리트의 내구성(耐久性)에 관한 연구(研究))

  • Kim, Saeng Bin
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.1 no.1
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    • pp.9-19
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    • 1981
  • Using superplasticizer or the methods of autoclave curing is the most typical and practical of the ways to make high strength concrete. In this study the high strength concrete piles by way of centrifugal forming and hand compacting, are put to the freezing and thawing test after the process of autoclave curing, water curing after steam curing, or stand water curing. And the relation of such piles to durability, the rate of strength decrease, and the rate of weight variation is shown. The durability of those test piles throughout freezing and thawing test proves to be comparatively sufficient in the above-mentioned curings when the piles contain a proper quantity of air. But it is also acknowledged that without A.E agent, the high strength concrete piles of autoclave curing is higher than those of the other curing in strength, but lower in modulus of dynamic elasticity and their durability factor after the test is much lower.

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Engineering Characteristics of Ultra High Strength Concrete with 100 MPa depending on Fine Aggregate Kinds and Mixing Methods (잔골재 종류 및 혼합방법 변화에 따른 100 MPa 급 초고강도 콘크리트의 공학적 특성)

  • Han, Min-Cheol;Lee, Hong-Kyu
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.2
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    • pp.536-544
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    • 2016
  • Recently, with the increase in the number of high rise and huge scaled buildings, ultra-high strength concrete with 80~100 MPa has been used increasingly to withstand excessive loads. Among the components of concrete, the effects of the kinds and properties of fine aggregates on the performance and economic advantages of ultra-high strength concrete need to be evaluated carefully. Therefore, this study examined the effects of the type of fine aggregates and mixing methods on the engineering properties of ultra-high strength concrete by varying the fine aggregates including limestone fine aggregate (LFA), electrical arc slag fine aggregate (EFA), washed sea sand (SFA), and granite fine aggregate (GFA) and their mixtures. Ultra-high strength concrete was fabricated with a 20 % water to binder ratio (W/B) and incorporated with 70 % of Ordinary Portland cement: 20 % of fly ash:10 % silica fume. The test results indicate that for a given superplasticizer dose, the use of LFA resulted in increases in slump flow and L-flow compared to the mixtures using other aggregates due to the improved particle shape and grading of LFA. In addition, the use of LFA and EFA led to enhanced compressive strength and a decrease in autogenous shrinkage due to the improved elastic properties of LFA and the presence of free-CaO in EFA, which resulted in the formation of C-S-H.

A Study on Early Age Properties of Alkali Activated Slag Mortar According to Water/Binder Ratio (물-결합재비에 따른 알칼리 활성 슬래그 모르타르의 초기 재령 특성에 관한 연구)

  • Oh, Sang-Hyuk;Kim, Dae-Wang;Lee, Kwang-Myong
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.2
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    • pp.63-69
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    • 2012
  • Recently, the cement industries brought very severe environment problems such as resource depletion and global warming with massive carbon dioxide during its production. The number of cases using industrial by-products such as the ground granulated blast furnace slag (GGBFS) in concrete mixtures is increasing to resolve the environmental issue. GGBFS is mainly used in the range between 20 to 50% to replace cement, but nowadays lots of researches are carried out to develop the alkali-activated slag (AAS) concrete with no cement. In this study, the early age properties of alkali activated slag (AAS) mortar are investigated to obtain the fundamental data for AAS concrete application to structural members. The experimental variables were the water-binder ratios of 0.3, 0.4, and 0.5 and NaOH as the alkali activator of 4%, 8%, and 12% by the mass of GGBFS, and compressive strength, flow, setting time, and ultrasonic pulse velocity of AAS mortars were measured and analyzed. It is found from the test results that as the normal concrete the lower W/B, the higher compressive strength. However, superplasticizer has to be used for producing high strength AAS concrete because the workability of AAS mortar are significantly lowered.

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The Dispersibility and Adsorption Behaviour of Cement Paste with Molecular Structures of Polycarboxylates (폴리카복실레이트 분자 구조에 따른 시멘트페이스트의 분산 및 흡착 특성 연구)

  • Shin, Jin-Yong;Hong, Ji-Sook;Suh, Jeong-Kwon;Lee, Young-Seok;Hwang, Eui-Hwan
    • Journal of the Korea Concrete Institute
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    • v.18 no.4 s.94
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    • pp.489-496
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    • 2006
  • Graft copolymerized polycarboxylate(PC)-type superplasticizers which have carboxylic acid with $\pi$ bond among the molecular structure and polyethyleneglycol methyl ether methacrylate(PMEM) were synthesized by free radical reaction. To investigate their chemical structures and molecular weights, PCs were analyzed by FT-IR(fourier transform spectrometer), C-NMR(nuclear magnetic resonance spectrometer) and GPC(gel permeation chromatograpy). When types of carboxylic acids(methacrylic acid, acrylic acid, maleic anhydride, and itaconic acid) and molar ratios of carboxylic acid/PMEM) were varied, adsorptive and fluid characteristics in cement paste were discussed. As the molar ratio of carboxylic acid/PMEM) was higher, amount adsorbed on the cement particles and the fluidity of cement paste by mini-slump spread testing method were increased. When main chain of PC was methacrylic acid, a larger amount was adsorbed on the cement particles. PCs with acrylic acid as main chain showed higher dispersing power. However, it was confirmed that PCs with dicarboxylic acids(maleic anhydride, itaconic acid) didn't have good adsorption and dispersibility.

Adhesive Properties of High Flowable SBR-modified Mortar for Concrete Patching Material Dependent on Surface Water Ratio of Concrete Substrate (콘크리트 피착체의 표면수율에 따른 단면복구용 고유동성 SBR 개질 모르타르의 부착특성)

  • Do, Jeong Yun;Kim, Doo Kie
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.17 no.2
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    • pp.124-134
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    • 2013
  • This study investigated the effect of surface water on concrete substrate on adhesive strength in tension of very high flowable SBR-modified cement mortar. The specimens were prepared with proportionally mixing SBR latex, ordinary portland cement, silica sand, superplasticizer and viscosity enhancing agent. Polymer cement ratio (P/C) were 10, 20, 30, 50 and 75% and the weight ratio of fine aggregate to cement were 1:1 and 1:3. The specimens obtained with different P/C and C:F were characterized by unit weight, flow test, crack resistance and adhesion test. After basic tests, two mixtures of P/C=20% and 30% in case of C:F=1:1, and one mixture of P/C=50% in case of C:F=1:3 were selected, respectively. These three selected specimens were studied about the effect of surface water evenly sprayed on concrete substrate by a amount of 0, 0.006, 0.012, 0.017, 0.024g per unit area ($cm^2$) of concrete substrate surface The results show that surface water on concrete substrate increases the adhesive strength in tension of high flowable SBR-modified cement mortar and improve the flowability compared to the non-sprayed case.

Effect of Substrate Surface Water on Adhesive Properties of High Flowable VA/VeoVa-modified Cement Mortar for Concrete Patching Material (단면수복용 고유동성 VA/VeoVa 개질 시멘트 모르타르의 부착특성에 대한 피착면 표면수의 영향)

  • Do, Jeong-Yun;Kim, Doo-Kie
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.17 no.5
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    • pp.94-104
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    • 2013
  • Experiments were divided into two parts; one part is to understand the basic properties of high flowable VA/VeoVa-modified cement mortar with different polymer cement ratio (P/C) and the weight ratio of fine aggregate to cement (C:F) and the other part is to investigate the effect of surface water spread on the concrete substrate on adhesion in tension. To understand the basic performance, the specimens were prepared with proportionally mixing VA/VeoVa redispersible powder, ordinary portland cement, silica sand, superplasticizer and viscosity enhancing agent. Here, P/C were 10, 20, 30, 50 and 75% and C:F were 1:1 and 1:3. As the change of P/C and C:F unit weight, flow test, crack resistance and adhesion in tension were measured. Three specimens with good adhesion properties were selected among specimens with different P/C and C:F. The effect of surface water evenly sprayed on concrete substrate on adhesive strength is investigated. The results show that surface water on concrete substrate increases the adhesion in tension of high flowable VA/VeoVa-modified cement mortar and additionally improves the flowability compared to the non-sprayed case.

Mechanical Properties and Field Implementation of Floor Mortar Incorporated with VAE Polymer (VAE 폴리머를 이용한 모르타르 바닥재의 역학적 특성과 현작 적용성)

  • Bang, Jin-Wook;Lee, Sun-Mok;Kim, Yun-Yong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.3
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    • pp.27-34
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    • 2017
  • Recently, the importance of the industrial warehouse floor has been increasing due to the development of the distribution and logistics industry. In this present study, an early-hardening polymer floor mortar which can compensate for the limitation of conventional cement based floor mortar regarding fluidity and long curing time was developed. In order to achieve the early-hardening of mortar characteristic ultra rapid hardening cement was used as binder. Four types of mixture proportions in accordance with the vinyl acetate ethylene(VAE) polymer contents with range from 10% to 20% and the other proto proportion without VAE polymer were designed. Mechanical experiments including the fluidity test, compressive strength test, bending test, bond test, and abrasion test were conducted for all mixture proportions. From the flow test result, it was possible to achieve the high flow with 250 mm by controlling the amount of superplasticizer. The incorporation of VAE polymer was found to affect the compressive strength reduction, however, the flexural strength was higher than that of the proto mixture, and it was evaluated to increase the compressive strength / flexural strength ratio. Moreover, at least 2.6 times higher bond strength and more than 4 times higher abrasion resistance were secured. From the mechanical experiments results, the optimum mixing ratio of the VAE polymer was determined to be 10%. As a result of application and monitoring, it shows that it has excellent resistance to cracking, discoloration, impact, and scratch as well as bond performance compared to the cement based floor mortar.

Box-Wilson Experimental Design-based Optimal Design Method of High Strength Self Compacting Concrete (Box-willson 실험계획법 기반 고강도 자기충전형 콘크리트의 최적설계방법)

  • Do, Jeong-Yun;Kim, Doo-Kie
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.19 no.5
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    • pp.92-103
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    • 2015
  • Box-Wilson experimental design method, known as central composite design, is the design of any information-gathering exercises where variation is present. This method was devised to gather as much data as possible in spite of the low design cost. This method was employed to model the effect of mixing factors on several performances of 60 MPa high strength self compacting concrete and to numerically calculate the optimal mix proportion. The nonlinear relations between factors and responses of HSSCC were approximated in the form of second order polynomial equation. In order to characterize five performances like compressive strength, passing ability, segregation resistance, manufacturing cost and density depending on five factors like water-binder ratio, cement content, fine aggregate percentage, fly ash content and superplasticizer content, the experiments were made at the total 52 experimental points composed of 32 factorial points, 10 axial points and 10 center points. The study results showed that Box-Wilson experimental design was really effective in designing the experiments and analyzing the relation between factor and response.