• Clean Technology
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• v.14 no.2
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• pp.110-116
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• 2008

The radioactive wastes generated from the nuclear industry can be divided into the forms of solid, liquid, or gas. Radioactive methyl iodide, a gaseous radioactive waste, is absorbed by activated carbon with 5 wt% of Trietylenediamine (1,4-diazania-bicycle[2.2.2]octane, TEDA) impregnated on the surface. Methyl Iodide ($CH_3I$) is combined chemically with TEDA (the final product : I-TEDA). To recycle radioactive activated carbon, removal of I-TEDA from activated carbon is needed. A wet method for recycling impregnated active carbon was developed to remove radioactive I-TEDA using an acetonitrile solution, which produces lots of secondary wastes. We suggest the removal of I-TEDA by supercritical carbon dioxide with co-solvents. In this experiment, we used a quartz crystal microbalance (QCM) for measuring the removal rate of the I-TEDA. From the experimental results, methanol was found to be the optimum co-solvent, and the optimum conditions such as temperature, pressure, and co-solvent flow rate were obtained. Possibility of using supercritical fluid in the removal of I-TEDA from radioactive activated carbon was also discussed.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.34 no.3
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• pp.213-217
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• 2001

In order to develop a new separation technology, supercritical fluid extraction process was used to produce high purity pigments and fatty acids from seaweed (Undaria pinnatifida). Supercritical carbon dioxide was used as a solvent and ethanol as an entrainer. The sample was treated by a frozen drier and experiments were conducted with a semi-batch flow system at various operating conditions (pressure range, $10.3\~17.2$ MPa; temperature range, $30\~45^{\circ}C$: particle size, $500\~1,000{\mu}m$ extraction time, 60 min). Characteristics of the recovered pigment (chlorophyll a) and fatty acids were determined by UV-spectrophotometry and gas chromatography, respectively. The highest extraction efficiency for fatty acids and pigments was achieved at 12.4 MPa, $35^{\circ}C$, $500{\mu}m$of seaweed size.

• Korean Chemical Engineering Research
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• v.43 no.2
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• pp.318-323
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• 2005

Supercritical water oxidation (SCWO, P>221 bar, T>$374^{\circ}C$) is a promising method for the decomposition of refractory organic compounds. In this study, the SCWO of Ethylenediaminetetraacetic acid (EDTA) was carried out in a tubular-type continusous reactor system with an $H_2O_2$ oxidant at $387-500^{\circ}C$, 250 bar and residence time (RT) of 15.9-88.9 s. The decomposition efficiencies increased with increasing temperature and oxidant amount, while it was inversely proportional to feed flow rate. The decomposition efficiency of 99.6% was obtained at $500^{\circ}C$, 250 bar, oxidant amount of 400% and residence time of 40.1 s. The effect of temperature on the decomposition efficiency was more significant than that of oxidant amount. In the case of the decomposition efficiency of 5,000 mg/L of EDTA (3,063 mg/L as $COD_{Cr}$), the decompostion of 99% or higher was obtained at the condition of over 40.1 s (RT) and 200 stoichiometric % of $H_2O_2$ in the supercritical water of $500^{\circ}C$ and 250 bar.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.43 no.5
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• pp.387-395
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• 2015

A technique for calculating the additive drag of the inlet in supersonic flow was studied using commercial CFD software, STAR-CCM+, which provides a efficient way of 3 dimensional flow analysis with polyhedron-shaped grid system. Three configurations were chosen and applied to the calculation with various flow conditions of two different free stream Mach No. and some mass flow ratios. Comparisons with results from wind tunnel test gave good agreements. Though computation were carried out with the inviscid and compressible flow around the supersonic inlet for the supercritical condition, ignoring the viscous effects is concluded to give little effects on the accuracy of the additive drag calculation and to make the calculation more efficient owing to less effort and time consumed for grid system build-up and for iteration because of less grid number and simpler boundary condition.

• Journal of Korea Water Resources Association
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• v.47 no.11
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• pp.1061-1066
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• 2014

A stable second-order finite volume method was proposed to predict sediment transport under rapidly varied flow conditions such as transcritical flow. For the use under unsteady flow conditions, a sediment transport model was coupled with shallow water equations. HLLC approximate Riemann solver based on a monotone upstream-centered schemes for conservation laws (MUSCL) reconstruction was used for the computation of the flux terms. From the comparisons of dam break flow experiments on erodible beds in one- and two-dimensional channels, good agreements were obtained when proper parameters were provided. Lastly, dam surface erosion problem by overtopped water was simulated. Overall, the numerical solutions showed reasonable results, which demonstrated that the proposed numerical scheme could provide stable and physical results in the cases of subcritical and supercritical flow conditions.

• Journal of Life Science
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• v.19 no.4
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• pp.508-513
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• 2009

Pine needles have long been used as a traditional health-promoting medicinal food in Korea. To investigate the effects of pine (pinus densiflora) needle extracts on blood flow and serum lipid improvement were assessed in vivo. 8 week-old Sprague Dawley strain rats were divided into four groups of seven rats each; CON, 0.5% CHOL, HOT water and Sub-supercritical group. Serum total cholesterol and triglyceride contents were lower in the CON group than the 0.5% CHOL group. Three weeks of feeding hot water and sub-supercritical extract resulted in a decrease in serum triglyceride and total cholesterol level. The level of HDL-cholesterol in the 0.5% CHOL group was significantly (p<0.05) reduced compared to the CON group, but it had a tendency to increase with pine needle extract supplementation. Blood passage time of the pine needle extracts supplemented group was higher than the 0.5% CHOL group. Microscopic observation showed that whole blood passed smoothly through the micro channels in pine needle extracts supplemented groups. The platelet aggregation ability of the groups treated with pine needle extracts was less than that of the 0.5% CHOL group. All these results suggest that pine needle extracts might improve blood homeostasis mediated via antiplatelet activities.

• 한국해양학회지
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• v.29 no.1
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• pp.50-63
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• 1994

A three-dimensional time-dependent coastal ocean model experiment of two different turbulence parameterizations is conducted. One of the turbulence parameterization is the constant eddy-mixing formulation, C1, and the other a stratification dependent eddy-mixing formulation, C2. The flow in C2 in strongly baroclinic, and limits vertical mixing of fresh and saline waters. The outflow discharged from an estuary is highly inertial and form a strong front of plume in C2 than that in C1. Because of the stronger outflow in C2, supercritical flow state, for which the near surface outflow velocity exceeds the baroclinic phase speed, can exist off the mouth of the estuary. The adjustment process of flow in the less saline waters are quite different for C1 and C2, which is dictated by the strongly baroclinic nature of the flow in C2.

• 유체기계공업학회:학술대회논문집
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• 2006.08a
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• pp.187-190
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• 2006

In the present study, effects of tree-stream turbulence and surface trip wire on the flow past a sphere at $Re\;=\;0.4\;{\times}\;10^5\;{\sim}\;2.8\;{\times}\;10^5$ are investigated through wind tunnel experiments. Various types of grids are installed upstream of the sphere in order to change the tree-stream turbulence intensity. In the case of surface trip wire, 0.5mm and 2mm trip wires are attached from $20^{\circ}\;{\sim}\;90^{\circ}$ at $10^{\circ}$ interval along the streamwise direction. To investigate the flow around a sphere, drag measurement using a load cell, surface-pressure measurement, surface visualization using oil-flow pattern and near-wall velocity measurement using an I-type hot-wire probe are conducted. In the variation of free-stream turbulence, the critical Reynolds number decreases and drag crisis occurs earlier with increasing turbulence intensity. With increasing Reynolds number, the laminar separation point moves downstream, but the reattachment point after laminar separation and the main separation point are fixed, resulting in constant drag coefficient at each free-stream turbulence intensity. At the supercritical regime, as Reynolds number is further increased, the separation bubble is regressed but the reattachment and the main separation points are fixed. In the case of surface trip wire directly disturbing the boundary layer flow, the critical Reynolds number decreases further with trip wire located more downstream. However, the drag coefficient after drag crisis remains constant irrespective of the trip location.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2010.11a
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• pp.729-732
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• 2010

The present study has been motivated by the development of a reliable numerical methodology for simulation of kerosene/LOx coaxial swirl injectors. To deal with thermodynamic non-ideality and anomalies of transport properties pronounced at supercritical pressures, a set of subroutine libraries has been constructed based on the cubic equations of state, and applied to an existing flamelet analysis code. For computational efficiency, two-dimensional axisymmetric RANS formulation with swirl was adopted and validated successfully against an isothermal coaxial swirling jet. For the actual problem with high pressure combustion, however, numerical results show that the RANS models yield excessive production of turbulence probably due to high density gradient magnitude in the vicinity of mixing layer of swirling film flow, and imply strongly further improvement of the turbulence models.

• Korean Journal of Medicinal Crop Science
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• v.11 no.1
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• pp.19-23
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• 2003

The optimum extraction condition of pungent component from Zanthoxylum piperitum D.C pericarps by using supercritical fluid extraction(SFE) was investigated. The optimum condition of SFE was $300kg/cm^2$ of pressure, $60\;^{\circ}C$ of extraction temperature, 80% of $CO_2$ fluid, 20% of modifier(methanol) volume and 20 min of extraction time. The extraction efficiency between the classical solvent extraction method and SFE was studied. About 40% of extraction efficiency was improved when SFE was applied.