• Title/Summary/Keyword: sulfur-component

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Dimethylsulfide as a Malordorous Component of a Waste Reclamation Site

  • Kim, Ki-Hyun;Lee, Gangwoong
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.E
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    • pp.39-43
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    • 1999
  • To help idntify the potential sources of volatile organic sulfur compounds within the continental environment, we have conducted preliminary measurements of dimethylsulfide(DMS) during field campains held from three reference sites. These sampling sites were located within a waste reclamation facility in Won Ju City, Kang Won Province. The results of our measurements showed that DMS levels spanned over 1 to 55 pptv with a mean and 1 standard deviation(1SD) of 12 and 18 pptv(N=13). In a comparison of the data derived from the strongest sources, i.e., oceanic environment, the DMS levels in thre reclamation facility were jpronouncingly low with high day-to-night concentration ratios. It was noted that a significant difference in DMS levels between daytime and nighttime periods was mainly driven by a few exceptional data measured during daytime. Despite limitations of our measurement data in deriving meaningful interpretations of spatiotemporal distributions of DMS in inland facilities, the existence of extraordinary trends, i.e., especially "lower-than-expectedL" DMS values, can be explained in terms of mixed effects of several factors. Most importantly, we can infer that the rates of DMS production and of its destruction in the study site are at or near steady-state condition. Another possibility is that DMS is not adequate enough to explain the generally malordorous environment of reclamation sites, of particular in Won Ju area.n Ju area.

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A Study on Influence of Fuel Cell Performance by Hydrogen Odorant (수소가스 부취제가 연료전지의 성능에 미치는 영향 연구)

  • Han, Sang-Won;Oh, Seok-Hwan;Kim, Young-Gyu;Lee, Sung-Hun;Chae, Jae-Ou
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.491-494
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    • 2008
  • The hydrogen fuel and fuel cell which have high energy efficiency and low pollutant emission are getting interest as an alternative energies due to the fossil fuel exhaust, green house effect and atmospheric pollutant problems. The hydrogen gas is very effective as an alternative energy. But, if it is leaked into the air it forms the mixed gas with the air then the danger of the explosion is risen up. So, the secure the safety is mostly important. In this research, to detect the leakage of the hydrogen rapidly, added the odorant materials which don't include the sulfur component into the hydrogen gas and researched on the effect of each odorant on the performance of the fuel cell. As the results, setting the cumulation electric power on the basis and comparing the pure hydrogen, 2,3-Butanedione 5ppm mixed gas 86.1%, 5-Ethylidene-2-Norbornene 17ppm mixed gas 88.2%, Isovaleraldehyde 10ppm mixed gas 74.8%, Ethyl Isobutyrate 2.2ppm mixed gas 93.5% of performance was shown.

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Component Analysis and Determination of Bioactivity of Oriental Therapeutic Drug for Hepatitis B (간염 치료제인 민간제제의 성분 분석 및 생리 활성 검색)

  • 김승호;이종우;이현선;함경수
    • Microbiology and Biotechnology Letters
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    • v.20 no.6
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    • pp.699-703
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    • 1992
  • An oriental drug, named NP-S, traditionally used as a therapeutic agent for hepatitis B was characterized by separating into volatile and non-volatile fractions. The volatile fraction contained ammonia as determined by ammonia kit and eight peaks when it was analyzed by gas chromatography that are not identified yet. The elemental analysis showed that the non-volatile fraction contained 15.5% carbon, 4.8% hydrogen, 11% nitrogen, and 10% sulfur along with a few trace elements such as Cl, Si, Mg and Zn. NP-S contained 6.7% peptide, 0.3% free amino acids such as Lys, Pro, Arg, lie, Tyr, Phe, His, Thr and Ser and 0.1% inorganic phosphate. The drug showed antimicrobial activity against Salmonella typhimurium, StaPhylococcus aureus and Candida albieans and also had antioxidant activity when thiobarbituric acid reacting substances(TBARS) method was applied.

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Studies on the Heavy Metal Content of Ginkgo Leaves Growing in All Around Seoul (서울지역 은행엽중 중금속 함량에 관한 연구)

  • 김민영;강희곤;길혜경
    • Environmental Analysis Health and Toxicology
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    • v.4 no.1_2
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    • pp.35-45
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    • 1989
  • Studies on the heavy metal content of ginkgo leaves growing in all around Seoul. This study was carried out to investigate the concentration of heavy metals and soluble sulfur in ginkgo leaves. These leaves are found growing in park, residential, commercial and industrial areas all around Seoul. These analyzed the quantity of Cd, Co, Cu, Fe, Mn, Ni, Pb, Zn, Hg and soluble surfur in separate samples of washed and unwashed leaves. The results were as follows: 1. This order of heavey metal concentration was found in Seoul area,: Fe>Mn>Zn>Ni>Pb>Cu>Co>Cd>Hg. 2. Pb concentration was higher in the commercial area than in the other areas, and it concentration in washed leaves was higher 96~100% and unwashed leaves 85~170%. 3. In the residential area Ni concentration was significantly higer where about seven times more Ni as found on the top part of the leaves. 4. Water soluble surfur was higest in the inudstrial area, but the percentage on top of the leaves was only 0.04~0.05% simillar with other area. 5. Fe, Zn and Ni were almost positively correlated to each component but negatively correlated between Mn and souble sulfer. All of content except Mn and Ni were significance between each area in washed and unwashed leaves.

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Characteristics of Cr(III)-based Conversion Coating Solution to Apply Aluminum Alloys for Improving Anti-corrosion Properties

  • Shim, Byeong Yun;Kim, Hanul;Han, Chang Nam;Jang, Young Bae;Yun, Jeong Woo
    • Journal of the Microelectronics and Packaging Society
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    • v.23 no.4
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    • pp.79-85
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    • 2016
  • It is imperative to find environment-friendly coatings as an alternative to the currently used hexavalent chromate conversion coatings for the purpose of improving the anti-corrosion properties of aluminum alloys. Hence, in this study, the corrosion properties of a trivalent chromate conversion coating solution are analyzed and measured. Because of the presence of multiple components in trivalent chromate conversion coating solutions, it is difficult to control plating, attributed to their mutual organic relationship. It is of significance to determine the concentrations of the components present in these coatings; hence, qualitative and quantitative analysis is required. The coating solution contained not only an environment-friendly component chromium(III), but also zirconium, fluorine, sulfur, and potassium, in the coating film. These metals are confirmed to produce a film with improved corrosion resistance to form a thin layer. The excellent corrosion resistance for the trivalent chromate solution is attributed to various inorganic and organic additives.

The Nutritional Composition of Bamboo Shoots and the Effects of its Fiber on Intestinal Microorganisms (죽순의 영양성분 및 죽순의 식이섬유가 장내미생물에 미치는 영향)

  • Park, Eun-Jin;Jhon, Deok-Young
    • Journal of the Korean Society of Food Culture
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    • v.28 no.5
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    • pp.502-511
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    • 2013
  • This study evaluated the composition two popular species of edible bamboo shoots in Korea (Phyllostachyspubescens and Sinoarundinarianigra) and the effect of their abundant dietary fiber on intestinal microorganisms in healthy young women. The ranges of total moisture, crude protein, crude lipid, crude ash, and dietary fiber content were 87.190.8, 2.943.5, 0.150.39, 0.411.05, and 4.206.15% (wet weight basis), respectively. Moisture and crude ash content increased after heat treatment; however, crude protein, crude lipid, and dietary fiber content were reduced after heating. The major minerals found in bamboo shoots were potassium, phosphorous, sulfur, magnesium, and calcium. In addition, glucose and fructose were abundant free sugars, while asparagine and tyrosine were the most abundant free amino acids. Approximately 70% of the total free fatty acids found in bamboo shoots were linoleic acid and linolenic acid. The ascorbic acid content was 6.60~17.56 mg/100 g (wet weight basis), and one phenolic compound, p-hydroxy benzoic acid, was 0.10.2% (wet weight basis) and detected by HPLC analysis. The intake of bamboo shoots for seven days significantly increased viable cell counts of Lactobacillus spp. and reduced viable cell counts of Bacteriodes spp. in feces (p<0.05). In our data, bamboo shoots may be useful in the food industry as high dietary fiber ingredients.

Altered Sulfate Metabolism of Arabidopsis Caused by Beet Severe Curly Top Virus Infection

  • Lee, Hong-Gun;Park, Sung-Hee;Kim, Dong-Giun;Lee, Taek-Kyun;Yum, Seung-Shic;Auh, Chung-Kyoon;Lee, Suk-Chan
    • The Plant Pathology Journal
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    • v.21 no.4
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    • pp.355-360
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    • 2005
  • Sulfur, an important component of plants, is regulated by a variety of stresses in sulfate assimilation and metabolism. Increase has been observed in the expression of O-acetylserine(thiol)lyase (OASTL) through two-dimensional electrophoresis with the shoot tips of Arabidopsis infected by beet severe curly top geminivirus (BSCTV). With the three- to six-fold increases in the transcript expression of OASTL, serine acetyltransferase (SAT) and $\gamma$-glutmylcysteine synthetase (GSH) were induced over the mock-inoculated organization in each organization through real-time RT-PCR analysis. The expression of those genes might affect the accumulation of anthocyanin in symptomatic tissues and the induction of abnormal callus-like structures formed by additional cell divisions as typical disease symptoms of BSCTV-infected Arabidopsis. This is the first report to describe the collaborative induction of OASTL, SAT, and GSH in virus-infected plants. The changed expressions of OASTL, SAT, and GSH in Arabidopsis infected with BSCTV raises new aspects regarding the biological function of symptomatic tissues related to sulfate metabolism.

Ecology of Algal Mats from Hypersaline Ponds in the British Virgin Islands

  • Jarecki, Lianna;Sarah M. , Burton-MacLeod;Garbary, David J.
    • ALGAE
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    • v.21 no.2
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    • pp.235-243
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    • 2006
  • Benthic sediment samples ranging from poorly aggregated sand to complex, stratified mats were collected from six hypersaline ponds from March and July 1995 in the British Virgin Islands. Assemblages were analyzed with respect to species composition and abundance within visibly distinct layers in each mat sample. In individual ponds there was no apparent association between changing depth and the development of the benthic mats. Some species were present in all samples (e.g. Oscillatoria sp.) while others were restricted to single sites (e.g. Johannesbaptistia pellucida). Primary species included Microcoleus chthonoplastes, Phormidium spp., Coccochloris stagnina, and purple sulfur bacteria. Quantitative analysis of community structure included cluster and principal component analysis. Samples from individual ponds were often clustered; however, this was subject to seasonal variation. Mats collected in March were generally thicker and contained more layers than those in July. Variation among sites was not explained by the measured variation in environmental factors such as average pond salinity, depth, and oxygen concentration (mg/L). This study provides a detailed analysis of mat communities in hypersaline ponds and compares them with similar mat communities from other areas.

Influence of Microbial Activity on the Long-Term Alteration of Compacted Bentonite/Metal Chip Blocks

  • Lee, Seung Yeop;Lee, Jae-Kwang;Kwon, Jang-Soon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.19 no.4
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    • pp.469-477
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    • 2021
  • Safe storage of spent nuclear fuel in deep underground repositories necessitates an understanding of the long-term alteration of metal canisters and buffer materials. A small-scale laboratory alteration test was performed on metal (Cu or Fe) chips embedded in compacted bentonite blocks placed in anaerobic water for 1 year. Lactate, sulfate, and bacteria were separately added to the water to promote biochemical reactions in the system. The bentonite blocks immersed in the water were dismantled after 1 year, showing that their alteration was insignificant. However, the Cu chip exhibited some microscopic etch pits on its surface, wherein a slight sulfur component was detected. Overall, the Fe chip was more corroded than the Cu chip under the same conditions. The secondary phase of the Fe chip was locally found as carbonate materials, such as siderite (FeCO3) and calcite ((Ca, Fe)CO3). These secondary products can imply that the local carbonate occurrence on the Fe chip may be initiated and developed by an evolution (alteration) of bentonite and a diffusive provision of biogenic CO2 gas. These laboratory scale results suggest that the actual long-term alteration of metal canisters/bentonite blocks in the engineered barrier could be possible by microbial activities.

Investigation of the Effect of Calculation Method of Offset Correction Factor on the GEMS Sulfur Dioxide Retrieval Algorithm (GEMS 이산화황 산출 현업 알고리즘에서 오프셋 보정 계수 산정 방법에 대한 영향 조사)

  • Park, Jeonghyeon;Yang, Jiwon;Choi, Wonei;Kim, Serin;Lee, Hanlim
    • Korean Journal of Remote Sensing
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    • v.38 no.2
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    • pp.189-198
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    • 2022
  • In this present study, we investigated the effect of the offset correction factor calculation method on the sulfur dioxide (SO2) column density in the SO2 retrieval algorithm of the Geostationary Environment Monitoring Spectrometer (GEMS) launched in February 2020. The GEMS operational SO2 retrieval algorithm is the Differential Optical Absorption Spectroscopy (DOAS) - Principal Component Analysis (PCA) Hybrid algorithm. In the GEMS Hybrid algorithm, the offset correction process is essential to correct the absorption effect of ozone appearing in the SO2 slant column density (SCD) obtained after spectral fitting using DOAS. Since the SO2 column density may depend on the conditions for calculating the offset correction factor, it is necessary to apply an appropriate offset correction value. In this present study, the offset correction values were calculated for days with many cloud pixels and few cloud pixels, respectively. And a comparison of the SO2 column density retrieved by applying each offset correction factor to the GEMS operational SO2 retrieval algorithm was performed. When the offset correction value was calculated using radiance data of GEMS on a day with many cloud pixels was used, the standard deviation of the SO2 column density around India and the Korean Peninsula, which are the edges of the GEMS observation area, was 1.27 DU, and 0.58 DU, respectively. And around Hong Kong, where there were many cloud pixels, the SO2 standard deviation was 0.77 DU. On the other hand, when the offset correction value calculated using the GEMS data on the day with few cloud pixels was used, the standard deviation of the SO2 column density slightly decreased around India (0.72 DU), Korean Peninsula (0.38 DU), and Hong Kong (0.44 DU). We found that the SO2 retrieval was relatively stable compared to the SO2 retrieval case using the offset correction value on the day with many cloud pixels. Accordingly, to minimize the uncertainty of the GEMS SO2 retrieval algorithm and to obtain a stable retrieval, it is necessary to calculate the offset correction factor under appropriate conditions.