• 제목/요약/키워드: sulfur gas

검색결과 569건 처리시간 0.026초

박용 디젤기관의 배기규제 및 배기 배출물 저감 대책 (Emissions Limits and Measures for Reducing Exhaust Emissions in Marine Diesel Engines)

  • 배명환
    • Journal of Advanced Marine Engineering and Technology
    • /
    • 제25권3호
    • /
    • pp.471-486
    • /
    • 2001
  • The principal trends in the course of emission control legislation are reviewed in this paper. In order to keep such a regulation, moreover, an inquiry ito the concrete technical possibility is conducted through review articles, Also, the composition of exhaust gases emitted from a marine diesel engine are investigated as several samples and the measures that can satisfy the value of regulation are handled with laying stress on the control methods discussed to date. It was concluded that various combined systems can be made to reduce NOx emissions without deteriorating substantially navigation costs since many technologies for reducing NOx emissions are being developed. All heat engines suffer from SOx emissions. There are two methods for reducing SOx emissions: desulfurization from exhaust gas and removal of sulfur composition from fuel oil. However it is necessary to watch the development of these technologies to evaluate which method is more favorable. Heat engines have a big problem in the regulation of environmental pollution from exhaust emissions. In the near future, however, diesel engines may be superior to other heat engines, owing to the high thermal efficiency, although the sales of individual models in dises engines may be prosperous and declining.

  • PDF

시판 밴댕이젓의 Aroma-Active 성분의 구명 (Identification of Aroma-Active Components in Salt-Fermented Big-Eyed Herring on the Market)

  • 차용준;김훈;장성민;유영재
    • 한국식품영양과학회지
    • /
    • 제27권6호
    • /
    • pp.1053-1058
    • /
    • 1998
  • Volatile flavor compounds in salt fermented big eyed herring were analyzed by vacuum simultaneous distillation solvent extraction/gas chromatography/mass spectrometry/olfactometry and aroma extract dilution anlaysis. A total of 44 volatile compounds were detected by GC/O analysis. Of these, 23 were positively identified, and composed of aldehydes(7), esters(5), ketones(4), sulfur containing compounds (3), aromatic hydrocarbons(2), alcohol(1) and nitrogen containing compound(1). Predominant odorants (Log3FD$\geq$5) in sample were ethyl butanoate(bubble gum /sweet candy-like), 3 methylbutyl butanoate (almond /nutty), 1 octen 3 one(earthy/mushroom like), (E,E) 2,6 nonadienal(roasted wheat/grainy), dimethyl trisulfide(soy sauce /cooked cabbage like), 2 acetylpyrazine(nutty/baked potato like) and unidentified compound(RI=1867, seaweed like).

  • PDF

저온 디젤 연소에서 T90 온도가 배기가스에 미치는 영향 (The Effect of T90 Temperature on Exhaust Emissions in Low-temperature Diesel Combustion)

  • 한만배
    • 한국자동차공학회논문집
    • /
    • 제19권4호
    • /
    • pp.72-77
    • /
    • 2011
  • This study is to investigate the effect of the distillation temperature in ultra low sulfur diesel fuel on exhaust emissions in the low-temperature diesel combustion with 1.9L common rail direct injection diesel engine. Low temperature diesel combustion was achieved by adopting an external high EGR rate with a strategic injection control. The engine was operated at 1500 rpm 2.6 bar BMEP. The 90% distillation recovery temperature (T90) was $270^{\circ}C$ and $340^{\circ}C$ for the respective cetane number (CN) 30 and 55. It was found that there exists no distinctive discrepancy on exhaust emissions with regards to the different T90s. The high CN (CN55) fuels follow the similar trend of exhaust emissions as observed in CN30 fuels' except that high T90 fuel (CN55-T340) produced higher PM compared to low T90 fuel (CN55-T270). This may come from that high T90 plays an active role in aggravating the degree of fuel-air mixture preparedness before ignition.

LNT 촉매 후단의 NH3 생성 특성 (NH3 Generation Characteristics of a LNT Catalyst Downstream)

  • 서충길
    • 동력기계공학회지
    • /
    • 제20권1호
    • /
    • pp.18-23
    • /
    • 2016
  • As diesel engines have high power and good fuel economy on top of less $CO_2$ emissions, their market shares are increasing not only in commercial vehicles but also in passenger cars. LNT, urea-SCR and combination of them have been developed for after-treatment of the exhaust gas to reduce NOx on diesel vehicles. The aim of this study is to investigate the $NH_3$ generation characteristics of LNT catalyst downstream. It was found from the experiments of the LNT catalyst that $H_2$ was useful as a reductant in SCR catalyst because it can enhance the de-NOx performance and improve $NH_3$ selectivity. The $NH_3$ generation of the LNT, when hydrothermally aged at $900^{\circ}C$ for 18 hr, increased to about 90ppm at $300^{\circ}C$ due to Pt sintering and Ba agglomeration. LNT catalyst was most sulfur poisoning at $500^{\circ}C$. The $NH_3$ slip increased due to the reduction of residence time according to SV increase.

Fluorescence Characteristic Spectra of Domestic Fuel Products through Laser Induced Fluorescence Detection

  • Wu, Ting-Nien;Chang, Shui-Ping;Tsai, Wen-Hsien;Lin, Cian-Yi
    • 한국지하수토양환경학회지:지하수토양환경
    • /
    • 제19권5호
    • /
    • pp.18-25
    • /
    • 2014
  • Traditional investigation procedures of soil and groundwater contamination are followed by soil gas sampling, soil sampling, groundwater sampling, establishment of monitoring wells, and groundwater monitoring. It often takes several weeks to obtain the analysis reports, and sometimes, it needs supplemental sampling and analysis to delineate the polluted area. Laser induced fluorescence (LIF) system is designed for the detection of free-phase petroleum pollutants, and it is suitable for on-site real-time site investigation when coupling with a direct push testing tool. Petroleum products always contain polycyclic aromatic hydrocarbon (PAH) compounds possessing fluorescence characteristics that make them detectable through LIF detection. In this study, LIF spectroscopy of 5 major fuel products was conducted to establish the databank of LIF fluorescence characteristic spectra, including gasoline, diesel, jet fuel, marine fuel and low-sulfur fuel. Multivariate statistical tools were also applied to distinguish LIF fluorescence characteristic spectra among the mixtures of selected fuel products. This study successfully demonstrated the feasibility of identifying fuel species based on LIF characteristic fluorescence spectra, also LIF seemed to be uncovered its powerful ability of tracing underground petroleum leakages.

Thermal Stability of $MnOx-WO_3-TiO_2$ Catalysts Prepared by the Sol-gel Method for Low-temperature Selective Catalytic Reduction

  • 신병길;이희수
    • 한국재료학회:학술대회논문집
    • /
    • 한국재료학회 2011년도 추계학술발표대회
    • /
    • pp.28.2-28.2
    • /
    • 2011
  • The selective catalytic reduction (SCR) of NOx by $NH_3$ is well known as one of the most convenient, efficient, and economical method to prevent NOx emission in flue gas from stationary sources. The degradation of the reactivity is the obstacle for its real application, since high concentrations of sulfur dioxide and thermal factor would deactivate the catalyst. It is necessary to develop high stability of catalysts for low-temperature SCR. Among the transition metal oxides, $WO_3$ is known to exhibit high SCR activity and good thermal stability. The $MnOx-WO_3-TiO_2$ catalysts prepared by sol-gel method with various $WO_3$ contents were investigated for low-temperature SCR. These catalysts were observed in terms of micro-structure and spectroscopy analyses. The $WO_3$ catalyst as a promoter is used to enhance the thermal stability of catalyst since it increases the phase transition temperature of $TiO_2$ support. It was found that the addition of tungsten oxides not only maintained the temperature window of NO conversion but also increased the acid sites of catalyst.

  • PDF

과냉질소 냉각시스템 가압용 기체의 절연내력특성 분석 (Analysis on the Dielectric Characteristics of Various Insulation Gases for Developing a Sub-cooled Liquid Nitrogen Cooling System)

  • 강형구;고태국
    • 한국초전도ㆍ저온공학회논문지
    • /
    • 제13권1호
    • /
    • pp.27-30
    • /
    • 2011
  • A sub-cooled liquid nitrogen cooling system is known as a most promising method to develop large scale superconducting apparatuses such as superconducting fault current limiters and superconducting cables [1]. Gaseous helium (GHe), gaseous nitrogen ($GN_2$) and sulfur hexafluoride ($SF_6$) are commonly used for designing an high voltage applied superconducting device as an injection gaseous medium [2, 3]. In this paper, the analysis on the dielectric characteristics of GHe, $GN_2$ and $SF_6$ are conducted by designing and manufacturing sphere-to-plane electrode systems. The AC withstand voltage experiments on the various gaseous insulation media are carried out and the results are analyzed by using finite element method (FEM) considering field utilization factors (${\xi}$). It is found that the electric field intensity at sparkover ($E_{MAX}$) of insulation media exponentially decreases according to ${\xi}$ increases. Also, the empirical expressions of the functional relations between $E_{MAX}$ and ${\xi}$ of insulation media are deduced by dielectric experiments and computational analyses. It is expected that the electrical insulation design of applied superconducting devices could be performed by using the deduced empirical formulae without dielectric experiments.

Effect of Refrigerated and Thermal Storage on the Volatile Profile of Commercial Aseptic Korean Soymilk

  • Kim, Hun;Cadwallader, Keith R.;Jeong, Eun-Jeong;Cha, Yong-Jun
    • Preventive Nutrition and Food Science
    • /
    • 제14권1호
    • /
    • pp.76-85
    • /
    • 2009
  • This study determined the effect of refrigerated and thermal storage on the volatile profile of commercial aseptic soymilk. Volatile components in commercial aseptic soymilk stored either under refrigerated ($4^{\circ}C$) or thermal ($55^{\circ}C$) conditions for 30 days were periodically analyzed by combined solvent-assisted flavor evaporation-gas chromatography-mass spectrometry (SAFE-GC-MS). The concentrations of most of the volatile components, including aldehydes, ketones, alcohols, acids, nitrogen- and sulfur-containing compounds, alkylfurans, furan derivatives and phenolic compounds, were affected to a greater extent by thermal storage compared with refrigerated storage. Profound increases in some volatile compounds with low odor detection thresholds, such as hexanal, octanal, (E)-2-octenal, (E,E)-2,4-decadienal, 1-octen-3-ol, 3-ethyl-2,5-dimethylpyrazine, 2,3-diethyl-5-methylpyrazine, 2-pentylfuran, 4-hydroxy-2,5-dimethyl-3(2H)-furanone, dimethyl trisulfide, guaiacol, 4-vinylguaiacol and 4-vinylphenol, were observed in thermal stored soymilk. The volatile profile changes caused by thermal storage may influence the aroma quality of thermal-stored aseptic soymilk.

탄성지지된 엔진, 고정지지된 발전기 및 탄성 커플링으로 구성된 발전기 세트의 엔진 본체 진동 특성에 관한 사례 연구 (A Case Study on the Engine Body Vibration Characteristics of Generator Set consists of Engine-resilient-mounted, Generator-rigid-mounted and Flexible-coupling)

  • 김효정;김상환;이돈출
    • 한국소음진동공학회:학술대회논문집
    • /
    • 한국소음진동공학회 2014년도 춘계학술대회 논문집
    • /
    • pp.443-446
    • /
    • 2014
  • Recently the demand for natural gas as clean and safe energy due to concerns about global warming and interests in green ship is increasing. The dual fuel(DF) engine, one of environmentally friendly engines, is preferred for general merchant ships and power plants as well as LNG carriers. This is for the reasons of having higher efficiency and lower nitrogen and sulfur oxides emissions by operating on LNG fuel with a small amount of light fuel oil. In this study, the engine body vibration characteristics of 12V50DF in a generator set with engine-resilient-mounted, generator-rigid-mounted and flexible-coupling configuration are investigated through theoretical analysis and comprehensive vibration measurement. This analysis showed the dynamic behavior of engine excitation forces and seismic waves. And the suitable countermeasures for reducing vibration and safe operation are proposed.

  • PDF

간염 치료제인 민간제제의 성분 분석 및 생리 활성 검색 (Component Analysis and Determination of Bioactivity of Oriental Therapeutic Drug for Hepatitis B)

  • 김승호;이종우;이현선;함경수
    • 한국미생물·생명공학회지
    • /
    • 제20권6호
    • /
    • pp.699-703
    • /
    • 1992
  • 본 연구에서는 간염치료제로 효과가 있는 민간제제(NS-P)의 성분 분석 및 항균 활성과 항산화 활성을 연구하였다. 이 NP-S는 그람 양성균인 Staphylococcus aureus와 그람 음성균인 Salmonella typhimurium 그리고 진균인 Candida albcans에 항균 활성을 보여 주었을 뿐만 아니라, 지질의 과산화를 억제하는 항산화 활성을 나타냈다. 이러한 NP-S는 C/H/N/S의 원소비가 15.5/4.8/11/10으로 황(S)이 상당히 많이 존재하고 있으며, 휘발성 물질인 암모니아를 2.11M 함유하고 있었다. 이 외에도 6.7의 펩타이드, 0.3의 유리 아미노산, 0.1의 무기 인산염을 함유하고 있으며, 미량 원소로서 Cl, Si, Mg, Zn도 함유하고 있다.

  • PDF