• Journal of the Korean Geosynthetics Society
• /
• v.5 no.2
• /
• pp.17-22
• /
• 2006

This paper presents preliminary field investigations on the electrokinetic (EK) remediation coupled with permeable reactive barrier (PRB) system. unregulated and old-fashioned landfills are one of the primary contributors to various contaminated soil problems. In-situ EK remediation technology has been successfully applied to the environs of unregulated landfill site, located in Kyeong-Ki province, Korea. Atomizing slag was adopted as a PRB reactive material for the remediation of groundwater contaminated with inorganic and/or organic substances. From the preliminary investigations, the coupled technology of EK with PRB system would be effecitve to remeidate contaminated grounds without the extraction of pollutants from subsurface due to the reactions between the reactive materials and contaminants.

• Journal of the Korean Geotechnical Society
• /
• v.26 no.10
• /
• pp.61-68
• /
• 2010

A pilot-scale model test was performed to estimate the availability of new material, Fe-loaded zeolite, as the filling material in permeable reactive barrier (PRB) against the contaminated groundwater with both Cd and Cr(VI). Aquifer was simulated by filling up a large scale soil tank with sands, and mobilizing the water flow by the head difference of water level in both ends of the tank. Then, the mixture of concentrated Cd and Cr(VI) solution was injected into the aquifer to form a contaminant plume, and its behavior through Fe-loaded zeolite barrier was monitored. The test results showed that Fe-loaded zeolite barrier successfully treated the contaminant plume containing both Cd and Cr(VI) and that the immobilized contaminants in the barrier were not desorbed or released. The results indicated that the Fe-loaded zeolite could be a promising material in PRBs against the multiple contaminants with different ionic forms like Cr(VI) and Cd.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
• /
• 2002.04a
• /
• pp.58-61
• /
• 2002

An alternative to pump and treat groundwater remediation is the use of reactive barriers. Zero valent iron (ZVI) is particularly useful as a reductant of chlorinated hydrocarbons because of its low cost and lack of toxicity ZVI can drive the dechlorination of chlorinated organic compounds and the reduction of chromium from the Cr(Ⅵ) to the Cr(III) state. The contaminants in subsurface environment usually exist as the mixed compounds. Therefore, the objective of this research is to study the effect of the other compounds on TCE removal by ZVI. The removal mechanism of TCE by ZVI is separated the dechlorination and sorption. TCE removal by ZVI slightly increased in presence of naphthalene as the non-reduced compound. TCE removal by ZVI remarkable decreased in presence of carbon tetrachloride, nitrate, and chromate as the reduced compounds. This research suggests that the effect of the coexisted compounds on the removal chlorinated compounds by reactive barrier technology should be considered for practical application.

• Journal of the Korean Society of Groundwater Environment
• /
• v.3 no.2
• /
• pp.95-100
• /
• 1996

Schlumberger electrical soundings and Coincident loop time-domain electromagnetic soundings were made on the Nanji-do landfill to investigate the nature of fills and the subsurface structure. The measured data were transformed into apparent resistivity values and then inverted in terms of 1-D resistivity models. At 6 points, both measurements were carried out to check the validity of the interpreted subsurface electrical structures. Interpreted layered models from each method show a good agreement. Obtained models show that a conductive zone exist below the shallow resistive zone. Conductive zone, which is considered to be influenced by decomposition of organic waste materials and infiltration of precipitation, is terminated by resistive zone which is considered as basement. Considering the fact that conductive zone extends to the basement and there exist no barrier layers such as clay layers, contaminant plumes are likely to flow into the groundwater directly.

• Journal of Korean Society on Water Environment
• /
• v.20 no.5
• /
• pp.512-519
• /
• 2004

Hybrid barriers using reduction and immobilization were tested to remediate the groundwater contaminated with multi-pollutants in this study. Iron filings and HDTMA(hexadecyltrimethylammonium)-bentonite were simulated in columns to assess the performance of hybrid barriers for remediation of trichloroethylene(TCE)-contaminated water. TCE reduction rate for the mixture of iron filings and HDTMA-bentonite was about 7 times higher than that for iron filings, only suggesting the reduction of TCE was accelerated when HDTMA-bentonite was mixed with iron filings. TCE reduction rate for the two layers of iron and HDTMA-bentonite was nearly similar to that for iron filings alone, but the partition coefficient($K_d$) for the two layers was 4.5 times higher than for that iron filings only. TCE was immobilized in the first layer with HDTMA-bentonite, and then dechlorinated in the second layer with iron filings. HDTMA-bentonite may contribute to the increase in TCE concentration on iron surface so that more TCE can be reduced. Also, TCE removal in the hybrid barriers was not affected by chromate and naphthalene while the reduction rate of TCE with the co-existing contaminants by iron filings was significantly decreased. Significant TCE removal in this research indicates that the proposed hybrid barrier system has the potential to become the effective remediation alternative during the occurrence of oil shock. Also, if subsurface environments are contaminated with multi-pollutants that contain non-reducible compounds as well as reducible compounds such as TCE, the conventional reactive barriers cannot be applied to this subsurface environment, while the proposed hybrid system can be applied successfully.

• Journal of the Korean earth science society
• /
• v.28 no.3
• /
• pp.343-356
• /
• 2007

This paper explored the characteristics of the interannual sea surface temperature (SST) variability in the equatorial Pacific by analyzing the simulated data from a newly coupled general circulation model (CGCM). The CGCM simulates well the realistic ENSO variability as well as the mean climatologies including SST, seasonal cycle, precipitation, and subsurface structures. It is argued that the zonal gradient of SST in the equatorial Pacific is responsible for the over-energetic SST variability near the equatorial western boundary in the model. This variability could also be related to the strong westward propagation of SST anomalies which resulted from the enhanced the zonal advection feedback. The simple two-strip model supports this by sensitivity tests. Analysis of the relationship between zonal mean thermocline depth and NINO3 SST index suggested that the ENSO variability is controlled by the recharge-discharge oscillator of the model. The lead-lag regression result reveals that heat buildup process in the western equatorial Pacific associated with the increase of the barrier layer thickness (BLT) is a precedent condition for El $Ni\widetilde{n}o$ to develop.

• Journal of Soil and Groundwater Environment
• /
• v.9 no.1
• /
• pp.63-69
• /
• 2004

Hematite-coated sand was examined for the application of the PRB (permeable reactive barrier) to the arsenic-contaminated subsurface in the metal mining areas. The removal efficiency of As in a batch and a flow system was investigated through the adsorption isotherm, removal kinetics and column experiments. Hematite-coated sand followed a linear adsorption isotherm with high adsorption capacity at low level concentrations of As (＜1.0 mg/L). In the column experiments, high content of hematite-coated sand enhanced the removal efficiency, but the amount of the As removal decreased due to the higher affinity of As (V) than As (III) and reduced adsorption kinetics in the flow system. Therefore. the amount of hematite-coated sand, the adsorption affinity of As species and removal kinetics determined the removal efficiency of As in a flow system.

• Proceedings of the Korean Magnestics Society Conference
• /
• 2011.12a
• /
• pp.14-14
• /
• 2011

Limited understanding of the surface properties of $Pt_3Ni$ for the oxygen reduction reaction (ORR) in polymer electrolyte membrane fuel cell (PEMFC) has motivated the study of magnetic properties and electronic structures of Pt segregated $Pt_3Ni$ (111) surface during adsorption of oxygen molecule on it. The first principle method based on density functional theory (DFT) is carried out. Nonmagnetic Pt has induced magnetic moment due to strong hybridization between Ni 3d and Pt 5d. It is found that an oxygen molecule prefers bridge site with Pt rich subsurface environment for adsorption on the surface of Pt segregated $Pt_3Ni$ (111). It is seen that there is very small charge transfer from $O_2$ to Pt. The curve of energy versus magnetic moment of the oxygen explains the magnetic moments in transition states. We found the dissociation barrier of 1.07eV significantly higher than dissociation barrier 0.77eV on Pt (111) suggesting that the dissociation is more difficult on Pt segregated $Pt_3Ni$ (111) surface. The spin polarized densities of states are presented in order to understand electronic structures of Pt and $O_2$ during the adsorption in detail.

• Journal of the Korean earth science society
• /
• v.29 no.5
• /
• pp.396-407
• /
• 2008

Hydrogeologic properties of a well field around middle mountainous areas in Pyosun, Jeju volcanic island were examined based on water level monitoring, geologic logging and pumping test data. Due to the alternating basaltic layers with varying permeability in the subsurface, it is difficult to analyze the hydraulic responses to artificial pumping and/or natural precipitation. The least permeable layer, detrital materials with clay, is found at a depth of 200 m below surface, but it is not an upper confining bed for lower main aquifer. Nevertheless, this layer may serve as a natural barrier to vertical percolation and to contaminant migration. Water levels of the production wells are dominantly affected by pumping frequently, while those of the remote observation wells are controlled by ambient precipitation. Results of pumping tests revealed a possible existence of horizontal anisotropy of transmissivity. However, some results of this study include inherent limitations enforced by field conditions such as the consistent of groundwater production and the set of time periods for the cessation of the pumping prior to pumping tests.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
• /
• v.15 no.4
• /
• pp.301-312
• /
• 2017

The concept of deep borehole disposal (DBD) for high-level nuclear wastes has been around for about 40 years. Now, the Department of Energy (DOE) in the United States (U.S.) is re-examining this concept through recent studies at Sandia National Laboratory and a field test. With DBD, nuclear waste will be emplaced in boreholes at depths of 3 to 5 km in crystalline basement rocks. Thinking is that these settings will provide nearly intact rock and fluid density stratification, which together should act as a robust geologic barrier, requiring only minimal performance from the engineered components. The Nuclear Waste Technical Review Board (NWTRB) has raised concerns that the deep subsurface is more complicated, leading to science, engineering, and safety issues. However, given time and resources, DBD will evolve substantially in the ability to drill deep holes and make measurements there. A leap forward in technology for drilling could lead to other exciting geological applications. Possible innovations might include deep robotic mining, deep energy production, or crustal sequestration of $CO_2$, and new ideas for nuclear waste disposal. Novel technologies could be explored by Korean geologists through simple proof-of-concept experiments and technology demonstrations.