• Title/Summary/Keyword: substitution

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Preparation and Characterization of $Bi_{4-x}Sm_xTi_3O_{12}(0<\leqx\geq2)$ Thin Films Using Sol-Gel Processing (졸겔공정을 이용한 $Bi_{4-x}Sm_xTi_3O_{12}(0<\leqx\geq2)$ 박막제조 및 특성평가)

  • 이창민;고태경
    • Journal of the Korean Ceramic Society
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    • v.34 no.8
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    • pp.897-907
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    • 1997
  • Thin films of Bi4-xSmxTi3O12(0$\leq$x$\leq$2) were prepared on Pt/Ti/SiO2/Si(100) at $700^{\circ}C$ using spin-coating with sols derived from Bi-Sm-Ti complex alkoxides. From X-ray diffraction analysis, it was observed that Sm-substituted phases resembled ferroelectric Bi4Ti3O12 in structure. Variations of their lattice parameters depending on the amount of Sm-substitution showed that an anomalous structural distortion might exist at x=1. The grain sizes of the thin films decreased from 0.115 ${\mu}{\textrm}{m}$ to 0.078${\mu}{\textrm}{m}$ with increasing the amount of Sm-substitution. The dielectric constants and the remanent polarizations of the thin films decreased with increasing the amount of the Sm-substitution, which were related to decrease of the stereo-active Bi3+ ion contributing to polarization. However, these values were exceptionally high at x=1, compared to those of the other substituted phases. Such an anomaly suggests that the phase of x=1 has 1:1 chemical ordering between Sm and Bi in structure. The thin films of all compositions except x=2 showed ferroelectricity. The thin film of x=2 was paraelectric, whose grains were too fine to exhibit ferroelectricity.

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A Study on the Conceptual Design for the Material Substitution of Rolling Stock Structures (소재대체를 이용한 철도 차량구조의 개념설계 연구)

  • 구정서
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.17 no.2
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    • pp.171-181
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    • 2004
  • This paper developed the theoretical method to predict structural performances and weight reduction rates of a carbody when its materials should be substituted. For the material substitution design of the carbody, the bending, axial and twisting deformations are evaluated under the constant stiffness and strength conditions. For the design of the primary structures such as the center beams, the cross beams and the cantrails, the bending and axial deformations are investigated under the condition of the constant bending stiffness, the constant bending or buckling strength by considering both the material properties and the cross sectional shapes. The developed indices to measure the weight reduction by the material substitution give good informations on the weak and strong points of a carbody design.

Substitution Characteristics of Carboxymethyl cellulose made from Hydrocellulose (수화(水化) 셀룰로오스로 제조(製造)한 카르복시메틸 세룰로오스의 치환(置換) 특성(特性))

  • Choi, Won-Sil;Ahn, Won-Yung
    • Journal of the Korean Wood Science and Technology
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    • v.20 no.2
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    • pp.81-90
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    • 1992
  • The effect of acid treatment of cellulose on the substitution charateristics of carboxymethylation was studied in this paper. Five samples of hydrocellulose(HC), all prepared from ${\alpha}$-cellulose by hydrolysis with five reaction times and determined on average molecular weight and polydispersity, were carboxymethylated to carboxymethyl cellulose (CMC). The CMCs from HCs were examined upon degree of substitution(DS), distribution of carboxymethyl groups in anhydroglucose units of the cellulose, and unsubstituted anhydroglucose(USAG) content. The DS of CMCs increased with increasing the hydrolysis time except CMC from HC at 1 hour hydrolysis time. In carboxymethylation the availability of hydroxyl groups on anhydroglucose units in HCs was the highest on OH(2), and the relative availability of OH(6) increased with the increasing of the hydrolysis time. The USAG contents were more deviated than that calculated based on Spurlin's model, and had a strong tendency of decreasing with increasing the hydrolysis time. The reactivity of HC was lower than that of ${\alpha}$-cellulose and the relative availability of OH(6) in HC increased with the hydrolysis time.

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Effect of Barley Flour Addition on Quality Characteristics of Vegetable Pancake (보릿가루의 첨가가 부침개의 품질특성에 미치는 영향)

  • Lee, In-Seon
    • Korean journal of food and cookery science
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    • v.33 no.3
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    • pp.333-341
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    • 2017
  • Purpose: This study investigated the quality characteristics of vegetable pancake prepared with various levels of barley flour. Methods: The pH level and spreadability of the batters as well as the color, texture, and sensory evaluation of the vegetable pancake were analyzed. Results: The results show that spreadability of batter significantly decreased as the substitution amount of barley flour increased (p<0.001). The pH level of the batter significantly decreased as the substitution amount of barley flour increased (p<0.001). Redness and yellowness increased as the substitution amount of barley flour increased. For texture, the sample groups with substituted barley flour showed high characteristics of hardness, gumminess, and chewiness. Principal component analysis showed that the sample group with a high substitution amount of barley flour was characterized by relatively high darkness, roasted grain aroma, bitterness, astringent, and chalkiness. Acceptance test found that the sample group with 15% barley flour received higher acceptance than the sample group with 0% barley flour in terms of color, texture, and overall acceptance. Conclusion: Acceptance test found that the sample group with 15% or 30% of barley flour had significantly higher or similar acceptance attributes than the sample group without barley flour, which suggests the possibility of developing vegetable pancake with barley flour.

The Effects of Al-substitution on Thermoelectric and Charge Transport Properties of BiCuOSe Compounds (Al 치환이 BiCuOSe의 열전 특성에 미치는 영향)

  • An, Tae-Ho;Lim, Young Soo;Seo, Won-Seon;Park, Cheol-Hee;Park, Chan
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.12
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    • pp.847-851
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    • 2015
  • The effects of Al-substitution on thermoelectric and charge transport properties of BiCuOSe compounds were investigated. The compounds were prepared by a solid-state reaction and consolidated by SPS (spark plasma sintering). In spite of the increase in the hole concentration with increasing Al amounts in BiCuOSe compound, the electrical conductivity at room temperature was kept constant due to the reduction of mobility. However, electrical conductivities of Al-substituted BiCuOSe compounds at elevated temperature (> 600 K) were higher than those of BiCuOSe, and this result was discussed in terms of it's the band gap energy. The Seebeck coefficient was drastically reduced when Al was substituted in Bi site, which indicated that the electronic structure was influenced by the Al-substitution into Bi-site.

Path Delay Test-Set Preservation of De Morgan and Re-Substitution Transformations (드모르간 및 재대입 변환의 경로지연고장 테스트집합 유지)

  • Yi, Joon-Hwan;Lee, Hyun-Seok
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.47 no.2
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    • pp.51-59
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    • 2010
  • Two logic transformations, De Morgan and re-substitution, are sufficient to convert a unate gate network (UGN) to a more general balanced inversion parity (BIP) network. Circuit classes of interest are discussed in detail. We prove that De Morgan and re-substitution transformations are test-set preserving for path delay faults. Using the results of this paper, we can easily show that a high-level test set for a function z that detects all path delay faults in any UGN realizing z also detects all path delay faults in any BIP realization of z.

Piezoelectric and Dielectric Properties of (Na,Li)$NbO_3$ Ceramics According to the $BaTiO_3$ substitution ($BaTiO_3$ 치환에 따른 (Na,Li)$NbO_3$ 세라믹스의 압전 및 유전특성)

  • Lee, Sang-Ho;Lee, Kab-Soo;Ryu, Ju-Hyun;Ryu, Sung-Lim;Song, Hyun-Seon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.272-273
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    • 2007
  • In this study, in order to develop the composition ceramics of lead-free ultrasonic motor, (Na,Li)$NbO_3-BaTiO_3$ ceramics were fabricated using a conventional mixed oxide process and their piezoelectric and dielectric characteristics were investigated according to the $BaTiO_3$, substitution. $BaTiO_3$ substitution enhanced density, dielectric constants$({\varepsilon}_r)$ and electromechanical coupling factor$(k_p)$. However, mechanical quality factor was deteriorated. At the $BaTiO_3$ substitution of 4mol%, density, electromechanical coupling factor$(k_p)$, dielectric constants$({\varepsilon}_r)$ and piezoelectric constant$(d_{33})$ of specimen showed the optimum value of $4.493g/cm^3$, 0.236, 175, 70pC/N, respectively.

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Dielectric and Piezoelectric Properties of (Na,K)$NbO3 Ceramics as a Function of SrTiO3 Substitution (SrTiO3 치환에 따른 (Na,K)NbO3계 세라믹스의 유전 및 압전특성)

  • Lee, Sang-Ho;Yoo, Ju-Hyun;Lee, Yeu-Yong;Song, Hyun-Seon;Mah, Suk-Burm;Kim, Seong-Goo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.6
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    • pp.484-488
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    • 2009
  • In this study, in order to develop the lead-free piezoelectric ceramics with high piezoelectric and dielectric properties, $[(K_{0.5}Na_{0.5})_{0.95}Li_{0.05}(Nb_{0.96}Sb_{0.04})]O_3$ ceramics were fabricated using $Ag_2O$ as sintering aid and a conventional mixed oxide process and their piezoelectric and dielectric characteristics were investigated according to the $SrTiO_3$ substitution. $SrTiO_3$ substitution enhanced density, dielectric constant(${\varepsilon}_r$) and electromechanical coupling factor($k_p$). However, mechanical quality factor was deteriorated. And also, Curie temperature ($T_c$), and phase transition temperature($T_p$) were rapidly decreased. At the 0.5 mol% $SrTiO_3$ substitution, density, electromechanical coupling factor($k_p$), dielectric constant(${\varepsilon}_r$) and piezoelectric constant($d_{33}$) of specimen showed the optimum value of $4.437\;g/cm^3$, 0.457, 1294, 265 pC/N, respectively.

An Improved Steganography Method Based on Least-Significant-Bit Substitution and Pixel-Value Differencing

  • Liu, Hsing-Han;Su, Pin-Chang;Hsu, Meng-Hua
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.14 no.11
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    • pp.4537-4556
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    • 2020
  • This research was based on the study conducted by Khodaei et al. (2012), namely, the least-significant-bit (LSB) substitution combined with the pixel-value differencing (PVD) steganography, and presented an improved irreversible image steganography method. Such a method was developed through integrating the improved LSB substitution with the modulus function-based PVD steganography to increase steganographic capacity of the original technique while maintaining the quality of images. It partitions the cover image into non-overlapped blocks, each of which consists of 3 consecutive pixels. The 2nd pixel represents the base, in which secret data are embedded by using the 3-bit LSB substitution. Each of the other 2 pixels is paired with the base respectively for embedding secret data by using an improved modulus PVD method. The experiment results showed that the method can greatly increase steganographic capacity in comparison with other PVD-based techniques (by a maximum amount of 135%), on the premise that the quality of images is maintained. Last but not least, 2 security analyses, the pixel difference histogram (PDH) and the content-selective residual (CSR) steganalysis were performed. The results indicated that the method is capable of preventing the detection of the 2 common techniques.

A review on the effect of marble waste on properties of green concrete

  • Rachid Djebien;Amel Bouabaz;Yassine Abbas;Yasser N. Ziada
    • Advances in concrete construction
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    • v.15 no.1
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    • pp.63-74
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    • 2023
  • All production and consumption activities produce wastes, which often cause damage to our environment and multiple risks to the human health. The valorization of these wastes in concrete technology is a future solution that will allow finding other construction materials sources, optimizing energy consumption and protecting the environment. Among these wastes, there is the marble waste. Every year, huge amount of marble waste is discarded as dust or aggregates form, in open-air storage areas causing serious problems for the environment and public health. In this context, the incorporation of marble waste as a replacement of ordinary aggregates or cement in concrete composition is actively investigated by researchers. This paper presents a comprehensive review of published studies over the last 20 years, dealing the effect of marble waste on fresh and hardened properties of concrete. Most of the studies carried out have used marble waste as dust with substitution rates between 5 and 20%. Besides the economic and ecological benefits, this review showed that marble waste can improve the physical, mechanical and durability properties of concrete. This improvement depends on the form (dust, fine aggregate or coarse aggregate), substitution method (as cement or aggregates replacement) and substitution rate of marble waste. Additionally, the review results showed that the use of 10-15% of marble waste dust as cement substitution can lead to increase the compressive strength.