• Title/Summary/Keyword: substitution

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Superconductivty and magnetic properties of $(Ru_{1-x}Nb_x)Sr_2(Sm_{1.4}Ce_{0.6})Cu_2O_z$

  • Lee, H.K.;Bae, S.M.;Lee, J.M.
    • Progress in Superconductivity and Cryogenics
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    • v.15 no.3
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    • pp.1-4
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    • 2013
  • We investigated the effect of Nb substitution for Ru on the structural and magnetic properties of $(Ru_{1-x}Nb_x)\;Sr_2(Sm_{1.4}Ce_{0.6})Cu_2O_z$ Samples. X-ray diffraction measurements indicated that nearly single-phase samples are formed in the range from x = 0 to 1.0. The superconducting transition temperature determined from the inflection in the field-cooled magnetic susceptibility decreased only slightly from $T_c$ = 25 K for x = 0 to $T_c$ = 22 K for x = 1.0, in consistent with the change in room temperature thermopower of the samples. However, the Nb substitution for Ru above x = 0.25 significantly suppressed the weak ferromagnetic component of the field-cooled magnetic susceptibility. It was also found that the Nb substitution for Ru results in an enhanced diamagnetic susceptibility with Nb content above x = 0.5 in both zero field-cooled and field-cooled magnetization measurements, in contrast to the behavior of the samples with $x{\leq}0.5$ in which the diamagnetic susceptibility decreases as the Nb content increases.

Piezoelectric and Dielectric Properties of (Na,K)$NbO_3$ Ceramics as a Function of $SrTiO_3$ substitution ($SrTiO_3$ 치환에 따른 (Na,K)$NbO_3$ 세라믹스의 압전 및 유전 특성)

  • Lee, Sang-Ho;Kim, Do-Hyung;Lee, Il-Ha;Yoo, Ju-Hyun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.175-176
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    • 2008
  • In this study, in order to develop the composition ceramics for lead-free ultrasonic motor, $[(K_{0.5}Na_{0.5})_{0.95}Li_{0.05}(Nb_{0.96}Sb_{0.04})]O_3$ ceramics were fabricated using $Ag_2O$ as sintering aid and a conventional mixed oxide process and their piezoelectric and dielectric characteristics were investigated according to the $SrTiO_3$ substitution. $SrTiO_3$ substitution enhanced density, dielectric constant$(\varepsilon_r)$ and electromechanical coupling factor$(k_p)$. However, mechanical quality factor was deteriorated. At the 0.5mol% $SrTiO_3$ substitution, density, electromechanical coupling factor$(k_p)$, dielectric constant$(\varepsilon_r)$ and piezoelectric constant$(d_{33})$ of specimen showed the optimum value of 4.437g/$cm^3$, 0.457, 1294, 265pC/N, respectively.

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Implementation of the modified-signed digit(MSD) number adder using triple rail-coding input and symbolic substitution (Triple rail-coding 입력과 기호치환을 이용한 변형부호화자리수 가산기 구현)

  • Shin, Chang-Mok;Kim, Soo-Joong;Seo, Dong-Hoan
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.41 no.6
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    • pp.43-51
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    • 2004
  • An optical parallel modified signed-digit(MSD) number adder system is proposed by using triple rail-coding input patterns and serial arrangement method of symbolic substitution. By combing overlapped arithmetic results. which are produced by encoding MSD input as triple rail-coding patterns. into the same patterns, symbolic substitution rules are reduced and also by using serialized and space-shifted input patterns in optical experiments, the optical adder without space-shifting operation, NOR operation and threshold operation is implemented.

Effects of Dietary Levels of Fermented Poultry Manure on the Growth and Nutrient Availability of Broiler Chicks (계분 발효사료가 육계의 성장과 영양소 이용율에 미치는 영향)

  • 장윤호;김정우;김인호;김춘수
    • Korean Journal of Poultry Science
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    • v.25 no.3
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    • pp.147-155
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    • 1998
  • Dietary levels of fermented poultry manure(FPM) 0%, 5%, 10% and 20% were included in experimental diets. It is to examine the effects of diets containing different levels of FPM on the performance of broiler chicks, including the nutrient availabilities, compared with that of the commercial diet. In order to evaluate the nutritive value of FPM, feeding and metabolism trials were conducted with a total of 160 broiler chicks for a period of 4 weeks. Contents of CP, crude fat, crude ash, crude fiber and NFE of FPM were 19.43, 2.43, 15.44, 16.57 and 38.31 %, respectively. Although there were no statistical difference in the body weight gain among treatments, weight gain achieved by the group fed diets of 5% substitution of FPM was slightly better than others. The amount of feed intake was significantly higher for FPM included groups than for control group, especially in the group fed diets of 10% substitution of FPM. The feed efficiency tended to be better for the control group than the FPM groups. The feed efficiency tended to get worse as the levels of FPM increased. The digestibility of DM, CP and NFE tended to be similar among treatments, especially it was lower for the group fed diets of 20% substitution of FPM compared with that of another groups. In conclusion, up to 10% substitution of FPM to the diet can be utilized effectively as a broiler feed ingredient, without adversely affecting growth performance.

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Superconducting and Magnetic Properties of the $(Ru_{1-x}Ta_x)Sr_2(Gd_{1.4}Ce_{0.6})Cu_2O_z$ System ($(Ru_{1-x}Ta_x)Sr_2(Gd_{1.4}Ce_{0.6})Cu_2O_z$ 계의 초전도 및 자기적 특성)

  • Lee, H.K.
    • Progress in Superconductivity
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    • v.13 no.3
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    • pp.163-168
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    • 2012
  • The effects of Ta substitution on the superconducting and magnetic properties of the $(Ru_{1-x}Ta_x)Sr_2(Gd_{1.4}Ce_{0.6})Cu_2O_z(0{\leq}x{\leq}0.5)$ system have been investigated. The X-ray diffraction measurements indicate that the Ta ion replaces Ru sites up to x = 0.4. It is found that the Ta substitution for Ru significantly reduces the weak-ferromagnetic component of the field-cooled magnetic susceptibility without an appreciable change of room temperature thermopower at lower Ta doping level below x = 0.2. The resistive transition temperature tends to decrease monotonically from 27 K for the x = 0 sample to 16 K (9 K) for the x = 0.4 (x = 0.5) sample. These results suggest that superconductivity of the $(Ru_{1-x}Ta_x)Sr_2(Gd_{1.4}Ce_{0.6})Cu_2O_z$ compound is not significantly affected by the magnetic state of the Ru sublattice. The experimental results are discussed in connection with previous reports on the effects of Nb substitution.

An Experimental Study on the Quality of Mortar Strength using the Quenched Blast-Furnace Slag (수재사 모르터의 강도특성에 관한 연구)

  • 임남기;이영도;양범석;김영회;최문식;정상진
    • Proceedings of the Korea Concrete Institute Conference
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    • 1997.10a
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    • pp.207-214
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    • 1997
  • Strength experimental on mortar which use Quenched Blast-Furnace Slag as aggregate was carried our for a fundamental study of application possibility of Quenched Blast-Furnace Slag as aggregate. It gives the following results. The strength of mortar use Quenched Blast-Furnace Slag is decrease as substitution rate is higher. As W/C rate increase, the strength decrease, but the strength decrease of fine aggregate rate 1:3 is lower than 1:2. The relation with fine aggregate is that the amount of fine aggregate is inversely proportional to strength. Th relation with age is proportional to strength and strength rate of going is lower than general mortar in 28 age the change of strength proportionately with W/C rate is that as W/C rate increases, th strength is drop ; it shows that it has same tendency as general mortar sand or crushed sand, but while W/C rate increase the strength is as high as general mortar. The reason can be assumed that water content per unit needed to Quenched Blast-Furance Slag is more than in case of sand. In addition, the relation with substitution rate is that the strength is the strongest at substitution rate 25% and 50% ; that is , sometimes it is higher than mortar which use sand 100%. In addition, long age strength of mortar which use Quenched Blast-Furnace Slag as aggregate is about to be studied in the last.

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Structural characteristics and electronic properties of GaN with $N_V,\;O_N,\;and\;N_V-O_N$: first-principles calculations

  • Lee, Sung-Ho;Chung, Yong-Chae
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.17 no.5
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    • pp.192-195
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    • 2007
  • Structural and electronic properties of bulk GaN with nitrogen vacancy($V_N$), oxygen substitution on nitrogen site($O_N$), and complex of nitrogen vacancy and oxygen substitution on nitrogen site($V_N-O_N$) were investigated using the first principle calculations. It was found that stability of defect formation is dependent on the epilayer growth conditions. The complex of $V_N-O_N$ is energetically the most favorable state in a condition of Ga-rich, however, oxygen substitution in nitrogen site is the most favorable state in N-rich condition. The electronic property of complex with negative charge states at $\Gamma$ point was changed from semiconductor to metal. On the contrary, the properties of nitrogen vacancy except for neutral charge state have shown the semiconductor characteristics at $\Gamma$ point. In the oxygen substitution on nitrogen site, the energy differences between conduction band minimum and Fermi level were smaller than that of defect-free GaN.

A study on Dielectric and Electrical Properties using PMN Ceramics with $La_{2}O_{3}$ substitution ($La_{2}O_{3}$ 치환된 PMN계 세라믹스의 유전 및 전기적특성에 관한 연구)

  • Ji, S.H.;Kim, B.S.;Lee, N.H.;Lee, H.K.;Kim, Y.H.;Lee, D.C.
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1621-1623
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    • 1996
  • The dielectric and polarizable properties of 0.85Pb$Mg_{1/3}Nb_{2/3}$)$O_3$-$0.125PbTiO_3$-$0.25BaTiO_3$ Ceramics have been investigated as a addition of the amount of $La_{2}O_{3}$($0{\leq}x{\geq}0.05$). The Temperature-dependant electrostictive characteristics of 0.85PMN-0.125PT-0.25BT relaxor ferroelectic system were improved by enhencing the extent of the diffuse phase transition(DPT). This was achieved using PMN-PT-BTceramics by the partial substitution of La at the Pb site. The curie temperature and the maximum dielectic permittivity decreased by substituting $La_{2}O_{3}$ and the electic field-related hysteresis phenomena decreased with increasing $La_{2}O_{3}$ substitution amount. It is showed decreasing in induced strain for electric field with increasing $La_{2}O_{3}$ substitution.

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Piezoelectric and Dielectric Properties of NaNbO3-LiNbO3 Ceramics according to the BaTiO3 Substitution (BaTiO3 치환에 따른 NaNbO3-LiNbO3 세라믹스의 압전 및 유전특성)

  • Lee, Sang-Ho;Yoo, Ju-Hyun;Mah, Suk-Burm;Kim, Seang-Goo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.3
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    • pp.205-209
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    • 2009
  • In this study, in order to develop the composition ceramics for lead-free ultrasonic motor, (1-x-0.09)$NaNbO_{3-x}BaTiO_3-0,09LiNbO_3$ ceramics were fabricated using a conventional mixed oxide process and their piezoelectric and dielectric characteristics were investigated according to the $BaTiO_3$ substitution. All the specimens showed orthorhombic phase structure without secondary phase, $BaTiO_3$ substitution enhanced density, dielectric constant(${\epsilon}_r$) and electromechanical coupling factor($k_p$), However, mechanical quality factor was deteriorated. Curie temperature of specimens was observed as about $380^{\circ}C$. At the $BaTiO_3$ substitution of 4 mol%, density, electromechanical coupling factor($k_p$), dielectric constant(${\epsilon}_r$) and piezoelectric constant($d_{33}$) of specimen showed the optimum value of $4.493g/cm^3$, 0.236, 175, 70 pC/N, respectively.

Nanocrystallization Behavior of Al-Y-Ni with Cu Additions (Cu 첨가에 따른 Al-Y-Ni의 나노결정화 거동)

  • 홍순직;천병선;강세선;이임렬
    • Journal of Powder Materials
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    • v.9 no.1
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    • pp.19-24
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    • 2002
  • This paper reports the results of an investigation into the effect of Cu additions upon the nano-crystallization behaviour of an Al-Y-Ni alloy. 1 at.% Cu was added to a base alloy of Al/sub 88/Y₄Ni/sub 8/ either by substitution for Al to form Al/sub 87/Y₄Ni/sub 8/Cu₁, or by substitution for Ni to form Al/sub 88/Y₄Ni/sub 7/Cu₁. Consistent with previous findings in the literature, the substitution of Cu for Al was found to increase the thermal stability of the amorphous phase whereas the substitution of Cu for Ni was found to decrease its thermal stability. Comparing the microstructures of these alloys after heat treatment to produce equivalent volume fractions of Al nanocrystals showed average grain sizes of 14 nm, 12 nm and 9 nm for the alloys Al/sub 88/Y₄Ni/sub 8/, Al/sub 87/Y₄Ni/sub 8/Cu₁respectively. The effect of Cu in refining the size of the nanocrystals was attributed to enhanced nucleation increasing the number density of the nanocrystals, rather than diffusion limited or interface limited growth.