• Title/Summary/Keyword: substitute materials

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Production of C4-C6 for Bioenergy and Biomaterials (바이오에너지 및 바이오화학원료인 C4-C6 생산)

  • Kim, Byung-Chun;Yi, Sung Chul;Sang, Byoung-In
    • Applied Chemistry for Engineering
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    • v.22 no.5
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    • pp.447-452
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    • 2011
  • Depletion of petroleum increased the need of alternative energy and chemical resources. Biomass, a renewable resource, can be transformed to bioenergy and biomaterials, and the materials from biomass will ultimately substitute petroleum based energy and chemical compounds. In this perspective, production of C4-C6 compounds for bioenergy and biomaterials are described for understating of current research progress. n-Butanol and n-butyric acid, the major C4 compounds, are produced by Clostridium tyrobutyricum, Clostridium beijerinckii, and Clostridium acetobutylicum. n-Hexanoic acid, a typical C6 compound, is produced by Clostridium kluyveri and Megasphaera elsdenii. Reported maximum amount of n-butanol, n-butyric acid and n-hexanoic acid was 21, 55, and 19 g/L, respectively, and extraction of these C4-C6 compounds are induced increase production by those anaerobic bacteria. In addition, a new bacterium Clostridium sp. BS-1 produced 5 g/L of n-hexanoic acid using galactitol.

Study on the Austenite Formation and Mechanical Properties of AGI (Austempered Gray Cast Iron) According to Aluminum Content (알루미늄 함량에 따른 AGI (Austempered Gray Cast Iron)의 오스테나이트 형성 및 기계적 특성에 관한 연구)

  • Kim, Dong-Hyuk
    • Journal of Korea Foundry Society
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    • v.41 no.6
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    • pp.543-549
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    • 2021
  • Aluminum cast iron has excellent oxidation resistance and good resistance to sulfide and corrosion. Compared to Ti and Ni alloys, it is expected to be a substitute material for structural materials and stainless steels because it is relatively inexpensive to use Fe, which is a non-strategic element. This results in a weight reduction effect of about 30% as compared to the use of stainless steel. With regard to aluminum as an alloying material, it is an element that has been widely used for the alloying of cast iron in recent years. Practical use has been delayed owing to the resulting lack of ductility at room temperature and the sharp decrease in the strength above 600℃ of this alloy, however. The cause of the weak room temperature ductility is known to be environmental embrittlement by hydrogen, and the addition of various alloying elements has been attempted in order to mitigate these shortcomings. Although alloying elements such as vanadium, chromium, and manganese are mainly used to increase the hardness and wear resistance of gray cast iron, the price of finished products containing these elements and the problems associated with alloys with this material impose many limitations.

A comparative study to measure the sagittal condylar inclination using mechanical articulator, virtual articulator and jaw tracking device

  • Liya Ma;Fei Liu;Jiansong Mei;Jiarui Chao;Zhenyu Wang;Jiefei Shen
    • The Journal of Advanced Prosthodontics
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    • v.15 no.1
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    • pp.11-21
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    • 2023
  • PURPOSE. To compare the sagittal condylar inclination (SCI) in dentate individuals measured by the different methods with mechanical articulator (MA), virtual articulator (VA), and a jaw tracking device (JTD) system. MATERIALS AND METHODS. A total of 22 healthy dentate participants were enrolled in this study. For MA workflow, the SCI was obtained by a semi-adjustable articulator with protrusive interocclusal records. The SCI was also set on a VA by aligning intraoral scan (IOS) with cone beam computed tomography (CBCT) and facial scan (FS), respectively. These virtual workflows were conducted in a dental design software, namely VAIOS-CBCT and VAIOS-FS. Meanwhile, a JTD system was also utilized to perform the measurement. Intraclass correlation was used to assess the repeatability within workflows. The bilateral SCI values were compared by Wilcoxon matched-pairs signed rank test for each workflow, and Kruskal-Wallis test and post hoc p-value Bonferroni correction were used to compare the differences among four workflows. The agreement of VAIOS-CBCT, VAIOS-FS, and JTD compared with MA was evaluated by Bland-Altman analysis. RESULTS. Intraclass correlation of the SCI revealed a high degree of repeatability for each workflow. There were no significant differences between the left and right sides (P > .05), except for VAIOS-CBCT (P = .028). Significant differences were not found between MA and VAIOS-FS (P > .05). Bland-Altman plots indicated VAIOS-CBCT, VAIOS-FS, and JTD were considered to substitute MA with high 95% limits of agreement. CONCLUSION. The workflow of VAIOS-FS provided an alternative approach to measure the SCI compared with MA.

Comparative Study on Load Criteria by Class Based on Structural Analysis of 38ft HDPE Power Boat (38ft급 HDPE 파워보트 구조해석을 통한 선급별 하중 기준에 대한 비교 고찰)

  • Byungyoung Moon;Hyeonjin Hong;Dae-Hyeon Kim;Wonmin Lee;Sangmok Lee
    • Journal of the Society of Naval Architects of Korea
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    • v.60 no.1
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    • pp.38-47
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    • 2023
  • According to the government policy of environmental regulations, interest of ship, which made with High-Density Polyethylene (HDPE) as a low-carbon and eco-friendly material, is growing as a substitute for the existing fishery boat hull materials such as FRP, aluminum, steel etc. However, regulations related to the production of HDPE ship are still quite incomplete. Even there are no regulations related to structural analysis. Therefore, in this study, structural analysis is carried out by applying different design loads for each international classification for 38ft class HDPE power boats, and the results are compared and analyzed. According to this study, although there is a correlation between the based pressure value and the analysis result value of each class regulation, it is not necessarily proportional. Also, This analysis result shows a difference not only depending on the size of design load, but also application range of the load, the pressure adjustment factor and section shape. However, the occurrence point and trend of the maximum stress values were quite consistent. It is hoped that the results of this study will be used when establishing HDPE ship structure analysis procedures and standards in the future.

Behavioral analysis of Pacific abalone, Haliotis discus hannai, reveals its feeding preference and attraction potential for brown alga, Sargassum horneri

  • Chae-Eun Yu;Yeo-Reum Kim;Gyeong-Eon Noh;Jong-Myoung Kim
    • Fisheries and Aquatic Sciences
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    • v.26 no.5
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    • pp.355-365
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    • 2023
  • The Pacific abalone, Haliotis discus hannai, is a highly valued and industrially important aquaculture species with growing demands of the expanding abalone aquaculture industry. To explore the feasibility of using the brown alga, Sargassum horneri, as a potential substitute for abalone feed, it is important to identify the feed preference and attractant effect of S. horneri on Pacific abalone. Our experiments indicated that the feeding-associated movement of abalone could be detected using a video tracking system under indirect illumination with dim red light. To further analyze the attraction potentials of various test materials, preference analysis was performed using Avicel-coated glass plates with ground powders of various seaweeds (e.g., S. horneri, Saccharina japonica, and Undaria pinnatifida) and commercial abalone feed, together with coffee waste. Heat map analysis indicated greater attraction by the kelp S. japonica than by S. horneri and commercial feed, which showed similar preference levels. Feeding preference based on the area of Avicel eaten by abalone showed a significant preference for U. pinnatifida over S. horneri (feeding area: 68.6 ± 20.1% vs. 37.5 ± 22.4%, p < 0.05). Additionally, the feeding area was significantly greater for plates with S. japonica than for plates with S. horneri (44.0 ± 16.6% vs. 22.6 ± 15.4%, p < 0.05). There was no significant difference in feeding area between commercial feed and S. horneri (31.7 ± 11.6% vs. 31.6 ± 20.2%, p > 0.05). The methanol extracts attracted abalone in the following order: U. pinnatifida > S. horneri > S. japonica > commercial feed > coffee waste. To determine the attractive effects of the components of methanol extracts, mixtures of methanol extracts of commercial feed with increasing amounts of S. horneri were examined. The results showed a significant increase in feeding preference upon addition of S. horneri up to 50% and 75%, suggesting its potential for use as an appetite-enhancing feed additive. This study identified conditions that can be successfully used to monitor the movement of Pacific abalone; the results of preference analysis confirmed that abalone exhibited similar attraction and feeding preference for S. horneri, compared with commercial feed.

Interface between calcium silicate cement and adhesive systems according to adhesive families and cement maturation

  • Nelly Pradelle-Plasse;Caroline Mocquot;Katherine Semennikova;Pierre Colon;Brigitte Grosgogeat
    • Restorative Dentistry and Endodontics
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    • v.46 no.1
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    • pp.3.1-3.14
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    • 2021
  • Objectives: This study aimed to evaluate the interface between a calcium silicate cement (CSC), Biodentine and dental adhesives in terms of sealing ability. Materials and Methods: Microleakage test: 160 standardized class II cavities were prepared on 80 extracted human molars. The cavities were filled with Biodentine and then divided into 2 experimental groups according to the time of restoration: composite resin obturation 15 minutes after Biodentine handling (D0); restoration after 7 days (D7). Each group was then divided into 8 subgroups (n = 5) according to the adhesive system used: etch-and-rinse adhesive (Prime & Bond); self-etch adhesive 2 steps (Optibond XTR and Clearfil SE Bond); self-etch adhesive 1 step (Xeno III, G-aenial Bond, and Clearfil Tri-S Bond); and universal used as etch-and-rinse or self-etch (ScotchBond Universal ER or SE). After thermocycling, the teeth were immersed in a silver nitrate solution, stained, longitudinally sectioned, and the Biodentine/adhesive percolation was quantified. Scanning electron microscopic observations: Biodentine/adhesive interfaces were observed. Results: A tendency towards less microleakage was observed when Biodentine was etched (2.47%) and when restorations were done without delay (D0: 4.31%, D7: 6.78%), but this was not significant. The adhesives containing 10-methacryloyloxydecyl dihydrogen phosphate monomer showed the most stable results at both times studied. All Biodentine/adhesive interfaces were homogeneous and regular. Conclusions: The good sealing of the CSC/adhesive interface is not a function of the system adhesive family used or the cement maturation before restoration. Biodentine can be used as a dentine substitute.

Buckling Load and Mode Analysis of Symmetric Multi-laminated Cylinders with Elliptical Cross-section (다층 대칭배열된 타원형 적층관의 좌굴하중 및 모드해석)

  • Chun, Kyoung Sik;Son, Byung Jik;Ji, Hyo Seon
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.3A
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    • pp.457-464
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    • 2006
  • Fiber-reinforced composite materials due to their high specific strength, high stiffness and light weight are becoming increasingly used in many engineering industry, especially in the aerospace, marin and civil, etc. In this paper, the buckling load and mode shapes of composite laminates with elliptical cross-section including transverse shear deformations are analyzed. For solving this problems, a versatile flat shell element has been developed by combining a membrane element with drilling degree-of-freedom and a plate bending element. Also, an improved shell element has been established by the combined use of the addition of enhanced assumed strain and the substitute shear strain fields. The combined influence of shell geometry and elliptical cross-sectional parameter, fiber angle, and lay-up on the buckling loads of elliptical cylinder is examined. The critical buckling loads and mode shapes analyzed here may serve as a benchmark for future investigations.

Basic study on high gradient magnetic separation of nano beads using superconducting magnet for antibody purification

  • Jeongtae Kim;Insung Park;Gwantae Kim;Myunghwan Sohn;Sanghoon Lee;Arim Byun;Jin-sil Choi;Taekyu Kim;Hongsoo Ha
    • Progress in Superconductivity and Cryogenics
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    • v.25 no.4
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    • pp.60-64
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    • 2023
  • The manufacturing process of antibody drugs comprises two main stages: the upstream process for antibody cultivation and the downstream process for antibody extraction. The domestic bio industry has excellent technology for the upstream process. However, it relies on the technology of foreign countries to execute downstream process such as affinity chromatography. Furthermore, there are no domestic companies capable of producing the equipment for affinity chromatography. High gradient magnetic separation technology using a high temperature superconducting magnet as a novel antibody separation and purification technology is introduced to substitute for the traditional technology of affinity chromatography. A specially designed magnetic filter was equipped in the bore of the superconducting magnet enabling the continuous magnetic separation of nano-sized paramagnetic beads that can be used as affinity magnetic nano beads for antibodies. To optimize the magnetic filter that captures superparamagnetic nanoparticles effectively, various shapes and materials were examined for the magnetic filter. The result of magnetic separation experiments show that the maximum separation and recovery ratio of superparamagnetic nanoparticles are 99.2 %, and 99.07 %, respectively under magnetic field (3 T) and flow rate (600 litter/hr).

Development and validation of a clinical phantom reproducing various lesions for oral and maxillofacial radiology research

  • Han-Gyeol Yeom;Jo-Eun Kim;Kyung-Hoe Huh;Won-Jin Yi;Min-Suk Heo;Sam-Sun Lee
    • Imaging Science in Dentistry
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    • v.53 no.4
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    • pp.345-353
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    • 2023
  • Purpose: The objective of this study was to propose a method for developing a clinical phantom to reproduce various diseases that are clinically prevalent in the field of dentistry. This could facilitate diverse clinical research without unnecessarily exposing patients to radiation. Materials and Methods: This study utilized a single dry skull, which was visually and radiographically examined to evaluate its condition. Existing lesions on the dry skull were preserved, and other relevant lesions were artificially created as necessary. These lesions were then documented using intraoral radiography and cone-beam computed tomography. Once all pre-existing and reproduced lesions were confirmed by the consensus of 2 oral and maxillofacial radiologists, the skull was embedded in a soft tissue substitute. To validate the process, cone-beam computed tomography scans and panoramic radiographs were obtained of the fabricated phantom. All acquired images were subsequently evaluated. Results: Most lesions could be identified on panoramic radiographs, although some sialoliths and cracked teeth were confirmed only through cone-beam computed tomographic images. A small gap was observed between the epoxy resin and the bone structures. However, 2 oral and maxillofacial radiologists agreed that this space did not meaningfully impact the interpretation process. Conclusion: The newly developed phantom has potential for use as a standardized phantom within the dental field. It may be utilized for a variety of imaging studies, not only for optimization purposes, but also for addressing other experimental issues related to both 2- and 3-dimensional diagnostic radiography.

Investigation of Waste Shell Fine Aggregates on the Material Characteristics of Cement Mortars (패각 잔골재가 시멘트 모르타르 재료 특성에 미치는 영향 분석)

  • Oh, Seo-Eun;Choi, Seung-Ha;Kim, Kyuwon;Han, Soo-Ho;Chung, Sang-Yeop
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.44 no.1
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    • pp.33-39
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    • 2024
  • This study explores the utilization of common marine wastes, specifically seashells, such as oysters and cockles, as alternative fine aggregates in construction materials. The considered seashells were cleaned and pre-processed for use as a substitute for aggregate in mortar. Cement mortar specimens were prepared under different conditions, such as substitution ratios and the cleaning status of the seashells. The compressive strength of the mortars specimens was evaluated, and the solid and porous structures of each specimen were analyzed using microstructure analysis methods such as XRD, SEM, and micro-CT. The results confirmed that oyster and cockle seashells are composed of different calcium carbonate polymorphs, and their microstructural characteristics influence the mechanical properties of the cement mortar specimens.