• Title/Summary/Keyword: subcritical

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Volatile Fatty Acid Production from Saccharina japonica Extracts by Anaerobic Fermentation: Evaluation of Various Environmental Parameters for VFAs Productivity (혐기성 발효에 의한 다시마 추출물로부터 휘발성 유기산 제조: 휘발성 유기산 생산성에 대한 환경적 영향인자 평가)

  • Choi, Jae Hyung;Song, Min Kyung;Chun, Byung Soo;Lee, Chul Woo;Woo, Hee Chul
    • Clean Technology
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    • v.19 no.2
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    • pp.148-155
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    • 2013
  • Volatile fatty acids (VFAs) production from marine brown algae, Saccharina japonica, was investigated in anaerobic dark fermentation. In order to evaluate the VFAs productivity, various experimental parameters (i.e., physicochemical pre-treatment, microorganism inoculation ratio, substrate concentration, and pH) were evaluated. According to the physicochemical pre-treatment methods, the maximum concentrations of VFAs were obtained in the order of sulfuric acid, subcritical water and subcritical water with lipid-extraction. Also, we investigated the operating parameters such as microorganism inoculation ratio (MV/M = 10 to 30), the substrate concentration (18.0 to 72.0 g/L) and pH (6.0 to 7.0) in sulfuric acid pre-treatment method. When the substrate concentrations were 18.0, 36.0, 54.0 and 72.0 g/L at $35^{\circ}C$, microorganism inoculation ratio 15, pH 7.0 for 372 hours, the maximum concentrations of VFAs were respectively 9.8, 13.9, 18.6 and 22.3 g/L. The change in VFAs concentrations was detected that acetic- and propionic acids increased according to increasing pH, while the butyric acid increased with decreasing pH. The VFAs obtained from concentration and separation process may be used as basic chemistry materials and bio-fuel, and they will expect to produce alternative energy of fossil fuel.

Thermo-chemical Conversion of Poplar Wood (Populus alba × glandulosa) to Monomeric Sugars by Supercritical Water Treatment (초임계수에 의한 현사시나무의 당화 특성)

  • Choi, Joon-Weon;Lim, Hyun-Jin;Han, Kyu-Sung;Choi, Don-Ha
    • Journal of the Korean Wood Science and Technology
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    • v.34 no.6
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    • pp.44-50
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    • 2006
  • To characterize thermo-chemical feature of su gar conversion of woody biomass poplar wood (Populus alba${\times}$glandulosa ) by sub- and supercritical water was treated for 60s under subcritical (23 MPa, 325 and $350^{\circ}C$) and supercritical (23 MPa, 380, 400, and $425^{\circ}C$) conditions, respectively. Among degradation products undegraded poplar wood solids existed in aqueous products. As the treatment temperature increased, the degradation of poplar wood was enhanced and reached up to 83.1% at $425^{\circ}C$. The monomeric sugars derived from fibers of poplar wood by sub- and supercritical treatment were analyzed by high performance anionic exchange chromatography (HPAEC). Under the subcritical temperature ranges, xylan, main hemicellulose component in poplar wood, was preferentially degraded to xylose, while cellulose degradation started at the transition zone between sub and supercritical conditions and was remarkably accelerated at the supercritical condition. The highest yield of monomeric sugars amounts to ca. 7.3% based on air dried wood weight (MC 10%) at $425^{\circ}C$.

Time-dependent Reduction of Sliding Cohesion due to Rock Bridges along Discontinuities (암석 브리지에 의한 불연속면 점착강도의 시간의존성에 관한 연구)

  • 박철환;전석원
    • Tunnel and Underground Space
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    • v.14 no.3
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    • pp.167-174
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    • 2004
  • This paper is to introduce an article published in Rock Mechanics and Rock Engineering, 2003. In this research, a fracture mechanics model is developed to illustrate the importance of time-dependence far brittle fractured rock. In particular a model is developed fer the time-dependent degradation of rock joint cohesion. Degradation of joint cohesion is modeled as the time-dependent breaking of intact patches or rock bridges along the joint surface. A fracture mechanics model is developed utilizing subcritical crack growth, which results in a closed-form solution for joint cohesion as a function of time. As an example, a rock block containing rock bridges subjected to plane sliding is analyzed. The cohesion is found to continually decrease, at first slowly and then more rapidly. At a particular value of time the cohesion reduces to value that results in slope instability. A second example is given where variations in some of the material parameters are assumed. A probabilistic slope analysis is conducted, and the probability of failure as a function of time is predicted. The probability of failure is found to increase with time, from an initial value of 5% to a value at 100 years of over 40%. These examples show the importance of being able to predict the time-dependent behavior of a rock mass containing discontinuities, even for relatively short-term rock structures.

Amino Acid Recovery from Brown Seaweed(Undaria pinnatifida) Using Subcritical Water Hydrolysis (아임계 수 가수분해를 이용한 미역으로부터 아미노산 회수)

  • Kwon, Kyung-Tae;Jung, Go-Woon;Chun, Byung-Soo
    • Korean Chemical Engineering Research
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    • v.48 no.6
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    • pp.747-751
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    • 2010
  • The objective of this research were to produce amino acids from freezing-dried brown seaweed(Undaria pinnatifida) powder by sub- and supercritical water hydrolysis and to characterize the products. The hydrolysis was carried out in a batch type reactor consisting of 4.6 cm inside diameter and $200cm^3$ vessel and stir made of Hastelloy 276. A stir inside the reactor was continuously moving at 100 rpm. Brown seaweed powder and 100 mL of 1% acetic acid in distilled water were charged into the reactor at a ratio of 1:100(w/v). The applied conditions were $180{\sim}374^{\circ}C$, respectively for 1 hour. The total amino acid content was found to be significantly higher in brown seaweed hydrolyzed by low temperature comparing to high temperature. The amounts of low molecular weight amino acids(glycine, alanine, serine etc) were higher than that of high molecular weight amino acids. The maximum yields of amino acids were produced at low temperature($220^{\circ}C$) with acid catalyst.

Technical Review on Thorium Breeding Cycle (토륨 핵연료 주기 기술동향)

  • Noh, Taewan
    • Journal of Energy Engineering
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    • v.25 no.2
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    • pp.52-64
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    • 2016
  • The production of nuclear energy from thorium which is non-fissile material was a main issue until the middle of 1970's, because of the thorium's abundance as energy resources, its capability of breeding fissile material U233, and the reduction of long-lived actinides. However, to use thorium as nuclear fuel, some obstacles such as the necessities of external neutron source and long-term neutron irradiation for effective breeding, and the production of high radioactive isotopes in the course of thorium breeding cycle should be overcome. The difficulties to resolve these cons of thorium cycle became the reason of interruption of the related researches in the middle of 1970's. But in the 21st century, the change of societal perspective regarding nuclear energy and the appearance of accelerator-driven nuclear reactor shift those cons into pros and rehabilitate the study of thorium. The high activity of thorium cycle turned out to be a good option as higher resistance and easier detectibility of nuclear proliferation and the employment of subcritical accelerator-driven reactor as external neutron sources is considered to enhance the nuclear safety. In this study we compare the thorium cycle with the currently-used uranium cycle and analyze the technical status and perspective of thorium researches which use accelerator-driven reactors.

A Welding Characteristics of Large Caliber-Thick Plate Pressure Vessel Low Alloy Steel (Mn-Mo) (대구경-후판 압력용기용 저 합금강(Mn-Mo)의 용접특성)

  • Ahn, Jong-Seok;Park, Jin-Keun;Yoon, Jae-Yeon
    • Journal of Welding and Joining
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    • v.30 no.6
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    • pp.10-14
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    • 2012
  • Recently the low alloy steel plate made with manganese-molybdenum is used widely in steam drum and separator of the new coal-fired power plant boiler. This material is suitable for the vapor storage of high pressure and high temperature. The high temperature creep strength of Mn-Mo alloy is higher than the carbon plate(SA516) that used in the subcritical pressure boiler. It reduces the thickness of the pressure vessel and makes the lightweight possible. Recently in the power plant boiler operation and production process, the damage has happened frequently in the heat affected zone and base material according to the hydrogen crack and delayed crack. This paper describes the research result about the damage case experienced in the boiler steam drum production process and present the optimum manufacture method for the similar damage prevention of recurrence.

A Study on the Operating Characteristics by Heat Flow Analysis of HYPER Beam Window (HYPER 빔창의 열수력 해석에 의한 운전특성에 관한 연구)

  • Song, Min-Geun;Choi, Jin-Ho;Ju, Eun-Sun;Song, Tae-Young
    • Proceedings of the KSME Conference
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    • 2001.06d
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    • pp.915-920
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    • 2001
  • A spent fuel problem has prevented the nuclear power from claiming to be a completely clean energy source. The nuclear transmutation technology to incinerate the long lived radioactive nuclides and produce energy during the incineration process is believed to be one or the best solutions. HYPER(Hybrid Power Extraction Reactor) is the accelerator driven transmutation system which is being developed by KAERI(Korea Atomic Energy Research Institute). Some major feature of HYPER have been developed and employed. On-power fueling concepts are employed to keep system power constant with minimum variation of accelerator power. A hollow cylinder-type metal fuel is designed for the on-line refueling concept. Lead-bismuth(Pb-Bi) is adopted as a coolant and Spallation target material. HYPER is a subcritical reactor which needs an external neutron source. 1GeV proton beam is irradiated to Lead-bismuth(Pb-Bi) target inside HYPER, and spallation neutrons are produced. When proton beams are irradiated, much heat is also deposited in the Pb-Bi target and beam window which separates Pb-Bi and accelerator vacuum. Therfore, an effective cooling is needed for HYPER target. In this paper, we performed the thermal-hydraulic analysis of HYPER target using FLUENT code, and also calculated thermal and mechanical stress of the beam window using ANSYS code.

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Study of the Operation Characteristics of the Supersonic Steam Ejector System (초음속 증기 이젝터 시스템의 작동 특성에 관한 연구)

  • Kim, H.D.;Lee, J.H.;Woo, S.H.;Choi, B.G.
    • Proceedings of the KSME Conference
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    • 2001.06e
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    • pp.329-334
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    • 2001
  • In order to investigate the operating characteristics of a supersonic steam ejector, the axisymmetric, compressible, Reynolds-averaged, Navier-Stokes computations are performed using a finite volume method. The secondary and back pressures of the ejector system with a second throat are changed to investigate their effects on the suction mass flow. Three operation modes of the steam ejector system, the critical mode, subcritical mode and back flow mode, are discussed to predict the critical suction mass flow. The present computations are validated with some experimental results. The secondary and back pressures of the supersonic steam ejector significantly affect the critical suction mass flow. The present computations predict the experimented critical mass flow with fairly good accuracy. A good correlation is obtained for the critical suction mass flow. The present results show that provided the primary nozzle configuration and secondary pressure are known, we can predict the critical mass flow with good accuracy.

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Effects of Ni additions on Graphitization in High carbon steel (고탄소강의 흑연화에 미치는 Ni첨가의 영향)

  • Park, Young-Koo;Woo, Kee-Do;Jin, Young-Chul;Ryu, Jae-Hwa;Park, Jong-Hyun
    • Journal of the Korean Society for Heat Treatment
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    • v.12 no.1
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    • pp.55-65
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    • 1999
  • Graphitization of cementite in high carbon steels at subcritical temperature is reported. We have studied about the effects of Ni in these steels on graphitization. The chemical compositions of the specimens were Fe-(0.54, 0.7)%-C-1.0%Si-0.1%Mn-(0.2~1.0)%Ni. After annealing at $650^{\circ}C$, $680^{\circ}C$ and $700^{\circ}C$ during various time the microstructures and hardness change were observed. In order to recover the initial hardness of high carbon steel, dissolution treatment of graphite was performed at $870^{\circ}C$. In case of 0.7%C steel, graphitization was accelerated rather 1.0%Ni addition steel than 0.2% and 0.54%Ni addition steels but the graphite is coarser. In case of 0.54%C-0.2%Ni steel, graphite particles were distributed relatively homogeniously and finely. Nickel addition promotes graphitization of these steels but makes graphite blocky.

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Evaluation of base shield plates effectiveness in reducing the drag of a rough circular cylinder in a cross flow

  • EL-Khairy, Nabil A.H.
    • Wind and Structures
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    • v.11 no.5
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    • pp.377-389
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    • 2008
  • An experimental investigation has been conducted to determine the effectiveness of base shield plates in reducing the drag of a rough circular cylinder in a cross flow at Reynolds numbers in the range $3{\times}10^4{\leq}Re{\leq}10.5{\times}10^4$. Three model configurations were investigated and compared: a plane cylinder (PC), a cylinder with a splitter plate (MC1) and a cylinder fitted with base shield plates (MC2). Each configuration was studied in the sub and supercritical flow regimes. The chord of the plates, L, ranged from 0.22 to 1.50D and the cavity width, G, between the plates was in the range from 0 to 0.93D. It is recognized that base shield plates can be employed more effectively than splitter plates to reduce the aerodynamic drag of circular cylinders in both the sub- and supercritical flow regimes. For subcritical flow regime, one can get 53% and 24% drag reductions for the MC2 and MC1 models with L/D=1.0, respectively, compared with the PC model. For supercritical flow regime however, the corresponding drag reductions are 38% and 7%.