• Title/Summary/Keyword: sub-exponential

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Combustion Kinetics of Pulverized Indian Coal-Char in Different CO2-O2 Mixture Isothermally (여러 CO2-O2 혼합기체에서 인도산 분말숯의 등온 연소반응)

  • Saravanan, V.;Shivakumar, R.;babu, P. Niruguna;Ramakrishna
    • Journal of the Korean Chemical Society
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    • v.53 no.6
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    • pp.635-639
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    • 2009
  • Experimental work was carried out to study the combustion kinetics of the Indian coal-char in the varying mixture of carbon dioxide-oxygen ($CO_2-O_2$). The coal sample was pulverized and sieved to less than 58 microns and charred using volatile furnace by passing the nitrogen gas. The experiments were carried out using the Thermo Gravimetric Analyzer (TGA-50) at CPRI, Bangalore, different proportions of ($CO_2-O_2$) gas was allowed in to the TGA-50 (80-20, 60-40, 40-60, 20-80) mole basis were used to study the combustion kinetics of coal Isothermally, kinetic parameters like Activation energy (E) and the pre-exponential factors (A) are calculated using the unification approach and modified Arrhenius equation.

Assessing the long-term durability and degradation of rocks under freezing-thawing cycles

  • Seyed Zanyar Seyed Mousavi;Mohammad Rezaei
    • Geomechanics and Engineering
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    • v.34 no.1
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    • pp.51-67
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    • 2023
  • In this research, the degradation rate of physical properties of the Angouran pit bedrock (calc-schist) is first investigated under the specific numbers of freeze-thaw (F-T) cycles. Then, the durability of calc-schist specimens against the F-T cycle number (N) is examined considering the mechanical parameters, and using the decay function and half-time techniques. For this purpose, point load strength (IS(50)), second durability index (Id2), Brazilian tensile strength (BTS), and compressive (VP) and shear (VS) wave velocities of calc-schist specimens are measured after 0, 7, 15, 40, and 75 N. For comparing the degradation rate of mechanical properties of available rock types on the Angouran mine walls, these tests are also carried out on the limestone and amphibolite schist specimens beside the calc-schist. According to test results, the exponential regression models are developed between the mechanical parameters of rock specimen's and N variable. Also, the long-term durability of each rock type versus N is studied using the decay function and half-time techniques. Results indicated that the degradation rate differs for the above rock types in which amphibolite schist and calc-schist specimens have the highest and least resistance against the N, respectively. The obtained results from this study can play a key role in the optimal design of the mine's final walls.

Time-Dependent Corrosion Behavior of High Chromium White Cast Iron in an Acidic Solution (산성 용액에서 전기화학적 특성과 침지 시간에 따른 고크롬 백주철의 부식 거동)

  • Jun-Seob Lee;Ochgerel Baasanjav;Jun-Seok Oh;Je-hyun Lee
    • Corrosion Science and Technology
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    • v.23 no.4
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    • pp.310-314
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    • 2024
  • The corrosion behavior of high chromium white cast iron was studied in 0.5 mol dm-3 H2SO4 + 0.01 mol dm-3 HCl solution over time through electrochemical and immersion experiments. Potentiodynamic and potentiostatic polarizations revealed active-passivation transition behavior, with critical current densities observed at -0.27 VSSE and 0.00 VSSE, repectively. The former potential showed preferential dissolution of primary γ phases, while the latter one showed preferential dissolution of eutectic γ phases. Immersion tests showed an exponential increase in corrosion rate, with significant acceleration observed around 1000 seconds due to the onset of eutectic γ phase dissolution. Over a 24-hour immersion period, both γ phases exhibited extensive corrosion, leaving carbides largely intact. These findings elucidate distinct corrosion behaviors of high chromium white cast iron in acidic environments, providing critical insights into material performance evaluation. Understanding these mechanisms is essential for predicting the longevity and durability of materials in corrosive conditions, thereby informing better material design and application strategies.

Impact of the Crossed-Structures Installed in Streams and Prediction of Fish Abundance in the Seomjin River System, Korea (하천에 설치된 횡구조물의 영향 및 섬진강 수계의 어류 풍부도 예측)

  • Moon, Woon Ki;Noh, Da Hye;Yoo, Jae Sang;Lim, O Young;Kim, Myoung Chul;Kim, Ji Hye;Lee, Jeong Min;Kim, Jai Ku
    • Ecology and Resilient Infrastructure
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    • v.9 no.2
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    • pp.100-106
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    • 2022
  • The relationships between river length and weir density versus fish species observed were analyzed for 210 local rivers in the Seomjin River system (SJR). A nonlinear exponential relationship between river length and number of fish species were observed. Model coefficient was 0.03 and coefficient of determinant (R2) was 0.59, meaning that about 59.0% of total variance was explained by river length variable. Predicted value by model and observed number of species showed a difference. About 110 local rivers (about 52.4%) showed lower value than predictive value. The average index of weir's density (IWD) in the SJR was about 2.7/km, which was significantly higher than that of other river basins. As a result of nonparametric 2-Kimensional Kolmogorov-Smirnov (2-DKS) analysis based on the IWD, the threshold value affecting fish diversity was about 2.5/km (Dmax=0.048, p<0.05). Above the threshold value, it means that the number of fish species would be decreased. In fact, the ratio of the expected species to the observed species was lowered to less than 70%, when the IWD is higher than the threshold value. To maintain aquatic ecological connectivity in future, it is necessary to manage IWD below the threshold value.

Redundancy Minimizing Techniques for Robust Transmission in Wireless Networks

  • Kacewicz, Anna;Wicker, Stephen B.
    • Journal of Communications and Networks
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    • v.11 no.6
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    • pp.564-573
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    • 2009
  • In this paper, we consider a wireless multiple path network in which a transmitting node would like to send a message to the receiving node with a certain probability of success. These two nodes are separated by N erasure paths, and we devise two algorithms to determine minimum redundancy and optimal symbol allocation for this setup. We discuss the case with N = 3 and then extend the case to an arbitrary number of paths. One of the algorithms minimum redundancy algorithm in exponential time is shown to be optimal in several cases, but has exponential running time. The other algorithm, minimum redundancy algorithm in polynomial time, is sub-optimal but has polynomial worstcase running time. These algorithms are based off the theory of maximum-distance separable codes. We apply the MRAET algorithm on maximum-distance separable, Luby transform, and Raptor codes and compare their performance.

Study on the Critical Storm Duration Decision of the Rivers Basin (중소하천유역의 임계지속시간 결정에 관한 연구)

  • Ahn, Seung-Seop;Lee, Hyeo-Jung;Jung, Do-June
    • Journal of Environmental Science International
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    • v.16 no.11
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    • pp.1301-1312
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    • 2007
  • The objective of this study is to propose a critical storm duration forecasting model on storm runoff in small river basin. The critical storm duration data of 582 sub-basin which introduced disaster impact assessment report on the National Emergency Management Agency during the period from 2004 to 2007 were collected, analyzed and studied. The stepwise multiple regression method are used to establish critical storm duration forecasting models(Linear and exponential type). The results of multiple regression analysis discriminated the linear type more than exponential type. The results of multiple linear regression analysis between the critical storm duration and 5 basin characteristics parameters such as basin area, main stream length, average slope of main stream, shape factor and CN showed more than 0.75 of correlation in terms of the multi correlation coefficient.

Corrosion Behavior of Inconel X-750 for Carbon Anode Oxide Reduction Application

  • Jeon, Min Ku;Kim, Sung-Wook;Lee, Sang-Kwon;Choi, Eun-Young
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.3
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    • pp.355-362
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    • 2020
  • The corrosion behavior of the Inconel X-750 alloy was investigated for its potential application under a Cl2-O2 mixed gas flow in an Ar atmosphere. The corrosion rate was found to be negligible at temperatures up to 400℃ under a flow rate of 30 mL·min-1 Cl2 + 170 mL·min-1 Ar, whereas an exponential increase was observed in the corrosion rate at temperatures greater than 500℃. The suppression of the corrosion reaction due to the presence of O2 was verified experimentally at flow rates of 30 mL·min-1 Cl2 (4.96 g·m-2·h-1), 20 mL·min-1 Cl2 + 10 mL·min-1 O2 (2.02 g·m-2 ·h-1), and 10 mL·min-1 Cl2 + 20 mL·min-1 O2 (1.34 g·m-2·h-1) under a constant Ar flow rate of 170 mL·min-1 at 600℃ for 8 h. The surface morphology analysis results revealed that porous surfaces with tunnel-type holes were produced under the Cl2-O2 mixed-gas condition. Furthermore, the effects of the Cl2 flow rate on the corrosion rate were investigated, indicating that its impact was negligible within the range of 5-30 mL·min-1 Cl2 at 600℃.

Internal and External Changes in Reactive Oxygen Species (ROS) During the Growth Stages of Harmful Algal Bloom Species (적조생물의 성장단계에 따른 세포 내·외 Reactive Oxygen Species (ROS) 변화)

  • Minji Lee;Danbi Bang;Seong-Su Shin;Yoonja Kang
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.57 no.4
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    • pp.389-396
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    • 2024
  • Reactive oxygen species (ROS) generated by harmful algal blooms (HABs) exert detrimental effects on aquaculture systems. Fish gill cells deteriorate upon exposure to HABs, suggesting that internally generated ROS in HABs influences the external environment. Therefore, we investigated the internal and external changes in ROS concentrations during growth using fluorescence staining of four representative HABs: Alexandrium affine, Chattonella marina, Karenia mikimotoi, and Margalefidinium polykrikoides. The concentrations of H2O2 and O2- produced by A. affine were low; H2O2 from M. polykrikoides was primarily detected internally throughout the experiments, and O2- was not detected. High H2O2 and O2- concentrations were observed in K. mikimotoi during the death phase, with weak external O2- concentrations. Regarding C. marina, which produces large amounts of ROS, H2O2 was observed internally during the exponential phase, whereas weak O2- concentrations were measured externally in the stationary phases. Collectively, our results highlight that ROS concentrations and internal/external distributions are functions of HABs and growth stage. These differences indicate the potential allelopathic mechanisms of proliferating HABs and suggest a possible impact of ROS on aquaculture organisms.

Micro gadolinium oxide dispersed flexible composites developed for the shielding of thermal neutron/gamma rays

  • Boyu Wang;Xiaolin Guo;Lin Yuan;Qinglong Fang;Xiaojuan Wang;Tianyi Qiu;Caifeng Lai;Qi Wang;Yang Liu
    • Nuclear Engineering and Technology
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    • v.55 no.5
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    • pp.1763-1774
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    • 2023
  • In this study, a series of flexible neutron/gamma shielding composites are fabricated through the doping of Gd2O3 into the matrix of SEBS with (MGd2O3: MSEBS) % from 5% to 100%. Neutron transmittance test shows an exponential attenuation with the increase of areal density of Gd, in which the transmittance T ranges from 59.1440% to 35.3026%, with standard deviation less than 2.2743%, mass attenuation coefficient 𝜇m from 0.3194 cm2/g to 0.4999 cm2/g, and half value layer-HVL value from 2.4530 mm to 1.1313 mm. Shielding efficiency of the Gd2O3/SEBS composites is basically improved in comparison with that of B4C/SEBS. The transmittance T, mass/linear attenuation coefficient 𝜇m and 𝜇, HVL and effective atomic number Zeff for the shielding of γ rays (39 keV, 59 keV and 122 keV) are measured and calculated with XCOM as well as MCX programs. Finally, plots of the three dimensional relationships between transmittance, doping amount and thickness are provided to the guidance for engineering shielding design. In summary, the Gd2O3/SEBS composite is proved to be an effective flexible neutron/low energy γ rays shielding material, which could be of potential applications in the field of nuclear technology and nuclear engineering.

Exploiting W. Ellison model for seawater communication at gigahertz frequencies based on world ocean atlas data

  • Tahir, Muhammad;Ali, Iftikhar;Yan, Piao;Jafri, Mohsin Raza;Jiang, Zexin;Di, Xiaoqiang
    • ETRI Journal
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    • v.42 no.4
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    • pp.575-584
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    • 2020
  • Electromagnetic (EM) waves used to send signals under seawater are normally restricted to low frequencies (f) because of sudden exponential increases of attenuation (𝛼) at higher f. The mathematics of EM wave propagation in seawater demonstrate dependence on relative permeability (𝜇r), relative permittivity (𝜀r), conductivity (𝜎), and f of transmission. Estimation of 𝜀r and 𝜎 based on the W. Ellison interpolation model was performed for averaged real-time data of temperature (T) and salinity (S) from 1955 to 2012 for all oceans with 41 088 latitude/longitude points and 101 depth points up to 5500 m. Estimation of parameters such as real and imaginary parts of 𝜀r, 𝜀r', 𝜀r", 𝜎, loss tangent (tan 𝛿), propagation velocity (Vp), phase constant (𝛽), and α contributes to absorption loss (La) for seawater channels carried out by using normal distribution fit in the 3 GHz-40 GHz f range. We also estimated total path loss (LPL) in seawater for given transmission power Pt and antenna (dipole) gain. MATLAB is the simulation tool used for analysis.