• Title/Summary/Keyword: structural reaction

Search Result 1,075, Processing Time 0.026 seconds

Structure and Histochemistry of Skin of Mud Loach, Misgurnus anguillicaudatus (Pisces, Cobitidae), from Korea (한국산 미꾸리 Misgumus anguillicaudatus (Pisces, Cobitidae) 피부 구조 및 조직화학적 특징)

  • Park, Jong-Young;Kim, Ik-Soo
    • Korean Journal of Ichthyology
    • /
    • v.11 no.2
    • /
    • pp.109-116
    • /
    • 1999
  • The structure of skin of a mud loach Misgurnus anguillicaudatus was described in relation with their histochemical nature from four regions of the skin. The epidermis has a strongly thick layer of two glandular cells, consisting of a elongate mucous cell and club cell, and a thin layer of superficial layer. The secretion of the elongated mucous cell was acid mucopolysaccharides in nature but the club cell did not give any histochemical reaction. A well defined lymphatic system, comprising small lymphocytes was present in the stratum germinativum layer of the epidermis. A pit organ of a pear-shaped structure was present below the epithelial cells and lie directly on the basement membrane. The organ has blood vessels serving the sense organs of the epidermis. There was a definite area showing acid mucopolysaccharides in the stratum laxum layer of the dermis. Small scales are present deep in the dermis except the top of the head. A great number of blood capillaries were found just under basement membrane. These structural features of skin in M. anguillicaudatus seem to be closely related with cutaneous respiration using air.

  • PDF

Enhanced NH3-SCR Activity of V/TiO2 Catalyst Prepared by Various Ball Mill Method (다양한 Ball Mill Method에 의해 제조된 V/TiO2 촉매의 NH3-SCR 활성 증진연구)

  • Kim, Dong Ho;Seo, Phill Won;Hong, Sung Chang
    • Clean Technology
    • /
    • v.23 no.1
    • /
    • pp.64-72
    • /
    • 2017
  • In this study, the selective catalytic reduction (SCR) for NOx removal was investigated in the temperature range of $150{\sim}400^{\circ}C$. XRD, BET and XPS analyses to determine the structural properties and valence state characteristics of the catalyst were performed. Various ball mill method were shown to a difference in activity at a low temperature below $250^{\circ}C$. Based on the catalyst with the highest denitrification efficiency, the ball mill time was the best result at 3 h. As a result of XPS analysis, the presence of the non-stoichiometric vanadium species and the increase of the number of atoms were attributed to a positive effect in the SCR reaction. it was confirmed that the correlation between the amount of lattice oxygen and the denitrification efficiency through the $O_2$ on-off experiment, and it was in a proportional relationship to each other.

Photoelectrochemical Cell Study on Closely Arranged Vertical Nanorod Bundles of CdSe and Zn doped CdSe Films

  • Soundararajan, D.;Yoon, J.K.;Kwon, J.S.;Kim, Y.I.;Kim, S.H.;Park, J.H.;Kim, Y.J.;Park, D.Y.;Kim, B.C.;Wallac, G.G.;Ko, J.M.
    • Bulletin of the Korean Chemical Society
    • /
    • v.31 no.8
    • /
    • pp.2185-2189
    • /
    • 2010
  • Closely arranged CdSe and Zn doped CdSe vertical nanorod bundles were grown directly on FTO coated glass by using electrodeposition method. Structural analysis by XRD showed the hexagonal phase without any precipitates related to Zn. FE-SEM image showed end capped vertically aligned nanorods arranged closely. From the UV-vis transmittance spectra, band gap energy was found to vary between 1.94 and 1.98 eV due to the incorporation of Zn. Solar cell parameters were obtained by assembling photoelectrochemical cells using CdSe and CdSe:Zn photoanodes, Pt cathode and polysulfide (1M $Na_2S$ + 1M S + 1M NaOH) electrolyte. The efficiency was found to increase from 0.16 to 0.22 upon Zn doping. Electrochemical impedance spectra (EIS) indicate that the charge-transfer resistance on the FTO/CdSe/polysulfide interface was greater than on FTO/CdSe:Zn/polysulfide. Cyclic voltammetry results also indicate that the FTO/CdSe:Zn/polysulfide showed higher activity towards polysulfide redox reaction than that of FTO/CdSe/polysulfide.

Social media big data analysis of Z-generation fashion (Z세대 패션에 대한 소셜미디어의 빅데이터 분석)

  • Sung, Kwang-Sook
    • Journal of the Korea Fashion and Costume Design Association
    • /
    • v.22 no.3
    • /
    • pp.49-61
    • /
    • 2020
  • This study analyzed the social media accounts and performed a Big Data analysis of Z-generation fashion using Textom Text Mining Techniques program and Ucinet Big Data analysis program. The research results are as follows: First, as a result of keyword analysis on 67.646 Z-generation fashion social media posts over the last 5 years, 220,211 keywords were extracted. Among them, 67 major keywords were selected based on the frequency of co-occurrence being greater than more than 250 times. As the top keywords appearing over 1000 times, were the most influential as the number of nodes connected to 'Z generation' (29595 times) are overwhelmingly, and was followed by 'millennials'(18536 times), 'fashion'(17836 times), and 'generation'(13055 times), 'brand'(8325 times) and 'trend'(7310 times) Second, as a result of the analysis of Network Degree Centrality between the key keywords for the Z-generation, the number of nodes connected to the "Z-generation" (29595 times) is overwhelmingly large. Next, many 'millennial'(18536 times), 'fashion'(17836 times), 'generation'(13055 times), 'brand'(8325 times), 'trend'(7310 times), etc. appear. These texts are considered to be important factors in exploring the reaction of social media to the Z-generation. Third, through the analysis of CONCOR, text with the structural equivalence between major keywords for Gen Z fashion was rearranged and clustered. In addition, four clusters were derived by grouping through network semantic network visualization. Group 1 is 54 texts, 'Diverse Characteristics of Z-Generation Fashion Consumers', Group 2 is 7 Texts, 'Z-Generation's teenagers Fashion Powers', Group 3 is 8 Texts, 'Z-Generation's Celebrity Fashions' Interest and Fashion', Group 4 named 'Gucci', the most popular luxury fashion of the Z-generation as one text.

Nonstoichiometric Effects in the Leakage Current and Electrical Properties of Bismuth Ferrite Ceramics

  • Woo, Jeong Wook;Baek, SeungBong;Song, Tae Kwon;Lee, Myang Hwan;Rahman, Jamil Ur;Kim, Won-Jeong;Sung, Yeon Soo;Kim, Myong-Ho;Lee, Soonil
    • Journal of the Korean Ceramic Society
    • /
    • v.54 no.4
    • /
    • pp.323-330
    • /
    • 2017
  • To understand the defect chemistry of multiferroic $BiFeO_3-based$ systems, we synthesized nonstoichiometric $Bi_{1+x}FeO_{3{\pm}{\delta}}$ ceramics by conventional solid-state reaction method and studied their structural, dielectric and high-temperature charge transport properties. Incorporation of an excess amount of $Bi_2O_3$ lowered the Bi deficiency in $BiFeO_3$. Polarization versus electric field (P-E) hysteresis loop and dielectric properties were found to be improved by the $Bi_2O_3$ addition. To better understand the defect effects on the multiferroic properties, the high temperature equilibrium electrical conductivity was measured under various oxygen partial pressures ($pO_2{^{\prime}}s$). The charge transport behavior was also examined through thermopower measurement. It was found that the oxygen vacancies contribute to high ionic conduction, showing $pO_2$ independency, and the electronic carrier is electron (n-type) in air and Ar gas atmospheres.

Interfacing Silicate Layer Between MoO3 Ribbon and Pt Metaldots Boosts Methanol Oxidation Reaction

  • Lee, Dohun;Jeong, Juwon;Manivannan, Shanmugam;Kim, Kyuwon
    • Journal of Electrochemical Science and Technology
    • /
    • v.11 no.3
    • /
    • pp.273-281
    • /
    • 2020
  • Constructing and making highly active and stable nanostructured Pt-based catalysts with ultralow Pt loading are still electrifying for electrochemical applications such as water electrolysis and fuel cells. In this study, MoO3 ribbons (RBs) of few micrometer in length is successfully synthesized via hydrothermal synthesis. Subsequently, 3-dimentional (3D)-silicate layer for about 10 to 15 nm is introduced via chemical deposition onto the pre-formed MoO3 RBs; to setup the platform for Pt metaldots (MDs) deposition. In comparison with the bare MoO3 RBs, the MoO3-Si has served as a efficient solid-support for stabilizing and accommodating the uniform deposition of sub-2 nm Pt MDs. Such a structural design would effectively assist in improving the electronic conductivity of a fabricated MoO3-Si-Pt catalyst towards MOR; the interfaced, porous and 3D silicate layer has assisted in an efficient mass transport and quenching the poisonous COads species leading to a significant electrocatalytic performance for MOR in alkaline medium. Uniformly decorated, sub-2 nm sized Pt MDs has synergistically oxidized the MeOH in association with the MoO3-Si solid-support hence, synergistic catalytic activity has been achieved. Present facile approach can be extended for fabricating variety of highly efficient Metal Oxide-Metal Nanocomposite for energy harvesting applications.

Performance Evaluation of Vibration Control of High-rise Buildings Connected by Sky-Bridge (스카이브릿지로 연결된 고층건물의 진동제어 성능평가)

  • Kim, Hyun-Su;Yang, Ah-Ram;Lee, Dong-Guen;Ahn, Sang-Kyung;Oh, Jung-Keun
    • Journal of Korean Association for Spatial Structures
    • /
    • v.8 no.4
    • /
    • pp.91-100
    • /
    • 2008
  • In this study, the vibration control performance of high-rise building structures connected by a sky-bridge has been investigated. The philosophy of vibration control using sky-bridges is to allow structures with different dynamic characteristics to exert control forces upon one another through sky-bridges to reduce the overall responses of the system. The the high-rise building structure connected by sky-bridge with 49 and 42 stories was used in this study to investigate the displacement, acceleration, reaction of bearings and stress of sky-bridge by analytical methods. To this end, historical earthquakes, an artificial earthquake and wind force time histories obtained from wind tunnel tests were used. Based on the analytial results, the use of sky-bridge can be effective in reducing the structural responses of high-rise buildings against wind and seismic loads.

  • PDF

The Effect of the Variation of a Wind Speed on the Stability of a Container Crane (풍속변화가 컨테이너 크레인의 안전성에 미치는 영향)

  • Lee, Seong-Wook;Shim, Jae-Joon;Han, Dong-Seop;Han, Geun-Jo;Kim, Tae-Hyung
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
    • /
    • v.29 no.1
    • /
    • pp.433-438
    • /
    • 2005
  • This study was carried out to analyze the effect of the variation of a wind speed on the stability of a container crane. The wind load according to 'The Requirement of Port Facilities and Equipments / Specification for the design of crane structures (KS A 1627)' and 'Load Criteria of Structures' enacted by the ministry of construction & transportation was evaluated. And the uplift forces of a container crane under this wind load were calculated by analyzing reaction forces at each supporting point and compared with each other. The analytic model was a container crane with uplift capacity of 50ton which was widely used in port.

  • PDF

Superconducting Properties of the Mg-Bi(Pb)SrCaCuO (110 K Phase) Composite System focusing on the Microstructure (Mg가 혼합된 Bi(Pb)SrCaCuO(110 K 상) 고온초전도체의 미세구조에 따른 초전도 특성 변화에 대한 연구)

  • 이정화;최봉수;이민수
    • Journal of the Korean Ceramic Society
    • /
    • v.40 no.6
    • /
    • pp.530-538
    • /
    • 2003
  • Samples with the nominal composition, B $i_{1.84}$P $b_{0.34}$S $r_{1.91}$C $a_{2.03}$C $u_{3.06}$ $O_{10+}$$\delta$/ (110 K phase) high $T_{C}$ superconductors containing MgO as an additive were fabricated by a solid-state reaction method. Samples with 5~50 wt% MgO were sintered at 820~86$0^{\circ}C$ for 24 h. The structural characteristics, critical temperature and grain size of the samples with different MgO contents were analyzed by XRD and SEM. As the MgO content increased, the intensity of MgO peaks and ratio of Bi-2212 phase in superconductors were intensified and the proportion of the phase transition from Bi-2223 to Bi-2212 was increased.d.creased.d.

Basemat Uplifting Effects on Seismic Response of Soil-Structure Interaction System (기초의 부분적 들림이 지반-구조물상호작용 시스템의 지진응답에 미치는 영향)

  • Joe, Yang Hee;Chang, Sung Pil
    • KSCE Journal of Civil and Environmental Engineering Research
    • /
    • v.10 no.1
    • /
    • pp.37-45
    • /
    • 1990
  • An analytical procedure is proposed for the seismic analysis of a soil-structure interaction system with besemat uplift, including the effects of concurrent vertical seismic ground motion, nonlinear distribution of bearing soil pressure under the basemat, and 3-dimensional behavior of the system. The soil-structure interaction system is assumed to have rectangular-shaped basemat on elastic half-space. Nonlinearity of soil spring constants and soil damping coefficients induced by the base mat uplift is modeled by considering not only the reduction of contact area between soil and structure but also the effects of rigid body rotational motion of the superstructure, and the shift in the point of action of the resultant reaction on the basemat. Throught various parametric studies. it has been confirmed that the seismic responses of the superstructure reduce notably while response at the basemat increases considerably. The results also show that the effects of concurrent vertical ground motion. nonlinear soil pressure distribution under basemat, and 3-dimensional behavior of the system shall be included in uplift analysis in order to obtain the correct structural responses.

  • PDF