• Title/Summary/Keyword: strontium

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Field Application of Low Heat Concrete Using Strontium Hydroxide Based Latent Heat Material (스트론튬계 잠열재를 사용한 저발열 콘크리트의 현장적용 평가)

  • Khil, Bae Su;Yun, Hyun Do;Jeong, Ok Ran
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.15 no.5
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    • pp.218-226
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    • 2011
  • Low heat concrete using strontium hydroxide based latent heat material was manufactured in ready-mixed concrete batcher plant and its fundamental properties were tested. As a result of B/P test, its applicability to the construction site was verified. After B/P test, low heat concrete using strontium hydroxide based latent heat material was applied to the real construction site of bridge footing. Through the analysis and the actual measurement of the hydration heat of the concrete footing, the reduction effect of hydration heat and thermal crack was confirmed.

Strontium-90 Levels in Milk

  • Park, Chan-Kirl;Yang, Kyung-Rin
    • Nuclear Engineering and Technology
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    • v.3 no.1
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    • pp.9-13
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    • 1971
  • The levels of strontium-90 in milk produced in Korea were determined during the past six years. Milk samples were collected from dairies and market shops in seoul area. Strontium-90 in milk was separated from calcium using fuming nitric acid and purified radiochemically. After seculear equilibrium was completed, the radioactivity of yttrium-90 was counted in a low background beta counting system. The determination of stable calcium in milk was also made by volu-metric method using 0. 1 N potassium permanganate solution. The highest value of 34.9 pCi $^{90}$ Sr/g-Ca was determined in August, 1966 and the lowest value was 7.5 pCi $^{90}$ Sr/g-Ca in August, 1967. From the result we can say that levels of strontium-90 are decreasing year after year and are far bellow the maximum permissible level recommended by International Committe on Radiation Protection.

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Assessment on Recovery of Cesium, Strontium, and Barium From Eutectic LiCl-KCl Salt With Liquid Bismuth System

  • Woods, Michael E.;Phongikaroon, Supathorn
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.4
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    • pp.421-437
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    • 2020
  • This study provides an assessment on a proposed method for separation of cesium, strontium, and barium using electrochemical reduction at a liquid bismuth cathode in LiCl-KCl eutectic salt, investigated via cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and scanning electron microscopy with energy dispersive X-ray spectrometry (SEM-EDS). CV studies were performed at temperatures of 723-823 K and concentrations of the target species up to 4.0wt%. Redox reactions occurring during potential sweeps were observed. Concentration of BaCl2 in the salt did not seem to influence the diffusivity in the studied concentration range up to 4.0wt%. The presence of strontium in the system affected the redox reaction of lithium; however, there were no distinguishable redox peaks that could be measured. Impedance spectra obtained from EIS methods were used to calculate the exchange current densities of the electroactive active redox couple at the bismuth cathode. Results show the rate-controlling step in deposition to be the mass transport of Cs+ ions from the bulk salt to the cathode surface layer. Results from SEM-EDS suggest that Cs-Bi and Sr-Bi intermetallics from LiCl-KCl salt are not thermodynamically favorable.

A Study on Effect of Electric Field for Carcinogenesis of Strontium 90 (Strontium 90의 골수 발암성에 대한 전계장의 영향에 관한 실험적 연구)

  • 정문호;두옥주
    • Journal of Environmental Health Sciences
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    • v.20 no.3
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    • pp.61-77
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    • 1994
  • Sprague Dawley rats were exposed to electric fields (6,000 V, 10 kV/m, 30 min/day, 6 days per week) and injected strontium 90 (681 kbq/rat, one time) through abdominal cavity (strontium 90 and electric field complexed exposure group). In parallel, series with the electric field exposure only, strontium 90 injection only and control groups were run. Every group was consisted of 110 rats (55 male and 55 female). This animal experiment was performed from May to December in 1993. This results were conducted to investigate the effect of electric field for 11 weeks. The results are summarized as follows: 1. Ornithine decarboxylase (ODC) activity in rat's bone marrow cells: The ODC values was significantly increased in Sr$^{90}$ injection group and Sr$^{90}$ and electric field complexed exposure group as compared with that of control group (p<0.05). The ODC value was significantly decreased in electric field and Sr$^{90}$ complexed exposure group in comparison with Sr$^{90}$ injection group (p<0.05). The ODC values of electric field only exposure group was not different to that of control group (p>0.05). 2. The amount of Sr$^{90}$ accumulation in the femur, kidney and spleen:The accumulation amount of Sr$^{90}$ in the femur of Sr$^{90}$ injection group represented higher value than that of electric field and Sr$^{90}$ complexed exposure group (p<0.05). In the kidney and spleen, the difference between electric field and Sr$^{90}$ complexed exposure group and Sr$^{90}$ injection group wasn't observed. 3. The counts of white cells in blood of Sr9?injection group was decreased as compared with the value from control group and electric field and Sr$^{90}$ complexed exposure group (p<0.05). The rat's body weight, red blood cell counts and the weight data of liver, kidney and spleen did not show differences among four groups.

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Effects of Strontium Gallate Additions on Sintering Behavior and Electrical Conductivity of Ce0.8Gd0.2O2-δ Ceramics (Strontium Gallate의 첨가에 따른 Ce0.8Gd0.2O2-δ 세라믹스의 소결거동과 전기전도도 특성)

  • Park Jin-Hee;Choi Kwang-Hoon;Ryu Bong-Ki;Lee Joo-Sin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.2
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    • pp.145-152
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    • 2006
  • The densification behavior and electrical conductivity of $Ce_{0.8}Gd_{0.2}O_{1.9}$ ceramics were investigated with the strontium gallate concentration ranging from 0 to $5\;mol\%$. Both the sintered density and grain size were found to increase rapidly up to $0.5\;mol\%$ $Sr_2Ga_2O_5$, and then to decrease with further addition. Dense $Ce_{0.8}Gd_{0.2}O_{1.9}$ ceramics with $97\%$ of the theoretical density could be obtained for $0.5\;mol\%$ $Sr_2Ga_2O_5$-added specimen sintered at $1250^{\circ}C$ for 5 h, whereas pure $Ce_{0.8}Gd_{0.2}O_{1.9}$ ceramics needed to be sintered at $1550^{\circ}C$ in order to obtain an equivalent theoretical density, Electrical conductivity was measured as a function of dopant content, over the temperature range of $350\;-\;600^{\circ}C$ in air. Total conductivity of $0.5\;mol\%$ $Sr_2Ga_2O_5$-added specimen showed the maximum conductivity of $2.37{\times}10^{-2}{{\Omega}-1}{\cdot}cm^{-1}$ at $500^{\circ}C$, The addition of strontium gallate was found to promote the sintering properties and electrical conductivities of $Gd_2O_3$-doped $CeO_2$.

Synthesis and Structure of a Second Polymorph of Strontium Germanium Nitride: β-Sr2GeN2

  • Park, Dong-Gon;Gal, Zoltan A.;DiSalvo, Francis J.
    • Bulletin of the Korean Chemical Society
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    • v.26 no.5
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    • pp.786-790
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    • 2005
  • A new ternary strontium germanium nitride, ${\beta}-Sr_2GeN_2$, was obtained as single crystal from constituent elements in molten Na. It crystallizes in space group Cmca (No. 64) with a = 5.441(1) $\AA$, b = 11.377(2) $\AA$, c = 12.229(2) $\AA$, and Z = 8. Its crystal structure is closely related to that of polymorphic companion, ${\alpha}-Sr_2GeN_2$, both of which contain isolated bent anions of ${GeN_2}^{4-}$.

Luminescent Properties of strontium aluminate phosphor (Strontium aluminate 형광체의 발광특성연구)

  • 한상혁;김영진
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.185-185
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    • 2003
  • 백색 LED를 실현하는 방법의 하나로 UV LED와 적, 녹, 청의 3색 형광체를 이용하는 방법이 주목받고 있다. 이것은 연색성과 색온도 제어 특성이 뛰어나다. 그러나 기존의 형광체는 단파장, 약 250nm 전후, 에서 여기되는 특성을 갖고 있기 때문에 near UV(nUV), 약 380-410nm, 의 LED에 응용하기에는 발광특성에 문제점을 갖고 있다. 본 연구에서는 nUV 여기가 가능한 strontium aluminate를 flux를 이용한 고상반응법으로 합성하고 발광 특성을 분석하였다. SrO와 A1$_2$ $O_3$의 조합비와 반응조건에 따라서 SrA1$_2$ $O_4$ 흑은 Sr$_4$Al$_{14}$ $O_{25}$ 가 합성되었고, 이들은 도핑과 함께 각각 약 520nm에서의 녹색발광과 약 480nm에서의 청녹색 발광 특성을 보이고 있었다. 도펀트로는 Eu, Dy, Ce, Pr 등이 단독 혹은 혼합되어 첨가되었고, 종류와 양에 따라서 발광 파장의 이동이 관찰 되었고, 강도도 이것에 크게 의존하고 있었다. 또한 발광강도는 여기 파장에도 의존하고 있었으며, 약 350-390nm의 nUV에서 가장 높은 발광강도가 관찰되었다.다.

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The Uptake and Loss of Strontium-90 by the Seaweed Undaria pinnatifida (미역에 의한 스트론튬-90의 농축 및 잔류)

  • Byung-Sun Yoo;Koon-Ja Lee;Su-Rae Lee
    • Nuclear Engineering and Technology
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    • v.14 no.3
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    • pp.116-121
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    • 1982
  • The uptake and retention of strontium-90 from seawater by the seaweed Undaria pinnatifda(sea mustard) varied depending on the plant part, exposure time, salinity, contents of stable strontium and calcium, and presence of chelating agent in the seawater. The concentration factors attained at equilibrium were in the range of 50 and it was evident that the bioaccumulation was largely due to the adsorption of the radionuclide on the surface of seaweed.

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Injectable Apatite for the Sequestration of Sr-90 in Groundwater

  • Jeen, Sung-Wook;Hyun, Yunjung
    • Journal of Soil and Groundwater Environment
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    • v.20 no.2
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    • pp.32-40
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    • 2015
  • Laboratory column experiments were conducted to evaluate the feasibility of injectable apatite method for the sequestration of Sr-90 in groundwater. The columns were tested to evaluate the rate of citrate biodegradation, the amounts of apatite formed, and the treatability of strontium by the sediment and apatite. The results showed the decreases in citrate, calcium, and phosphate concentrations and the increases in alkalinity and citrate degradation products (acetate and formate) in the columns, suggesting that the citrate degradation and formation of calcium phosphate are occurring. Although the calcium and phosphate were not completely consumed within the columns, some amounts of apatite were formed and it showed an ability to treat strontium in groundwater. This study provides a fundamental understanding of reaction mechanisms for the injectable apatite sequestration method for Sr-90 removal.

Chemical Preparation of Barium-Strontium Titanate

  • 노태용;김승원;이철
    • Bulletin of the Korean Chemical Society
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    • v.16 no.12
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    • pp.1180-1184
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    • 1995
  • The precursors of Ba1-xSrxTiO3(x=0.0-0.3) were prepared by the rapid addition of aqueous solution of titanyl oxalate to the mixed aqueous solution of barium and strontium at room temperature. The optimum pH was theoretically calculated from the equilibrium constants and solubility products. The chemical formula of the precursors obtained corresponded to Ba1-xSrxTiO(C2O4)2·4H2O(x=0.0-0.3) as determined by thermal gravimetric analysis. The precursors were converted to stoichiometric Ba1-xSrxTiO3(x=0.0-0.3) with a particle size of 0.01-0.04 μm. As increasing the amount of strontium substituted to barium sites, the structure of crystal changed from the tetragonal phase to the cubic and the unit cell volume was decreased.