• Title/Summary/Keyword: strong and weak interactions

Search Result 26, Processing Time 0.037 seconds

Coupled Mode Analysis of Phase-Locked CSP Laser Arrays (위상이 고착된 CSP 레이저 어레이의 결합 모우드 해석)

  • 吳煥述
    • Journal of the Korean Institute of Telematics and Electronics
    • /
    • v.24 no.1
    • /
    • pp.133-139
    • /
    • 1987
  • A phase-locked Channel-Substrate-Planar(CSP) laser arrays is described. Arrays of emitters with weak coupling are operated in a set of discrete modes determined by the number and spacing of the emitters. The interactions between emitters lead to a splitting of the wave-length and gain which are calculated from the coupling strength. Phase-locked arrays has exhibited to CW output-power as high as 80 m W and the highest order mode will have preferred oscillation. A strong hole burning is occurred at p=30m W. The most stable lasing mode is occurred at element spacing S=3.5\ulcornerm and there is no coupling at S>7 \ulcornerm.

  • PDF

Analysis of the Relationship of Cold Air Damming with Snowfall in the Yeongdong Region (영동 지역 한기 축적과 강설의 연관성 분석)

  • Kim, Mi-Gyeong;Kim, Byung-Gon;Eun, Seung-Hee;Chae, Yu-Jin;Jeong, Ji-Hoon;Choi, Young-Gil;Park, Gyun-Myeong
    • Atmosphere
    • /
    • v.31 no.4
    • /
    • pp.421-431
    • /
    • 2021
  • The Yeongdong region is frequently vulnerable to heavy snowfall in winter in terms of societal and economical damages. By virtue of a lot of previous efforts, snowfall forecast has been significantly improved, but the performance of light snowfall forecast is still poor since it is very conducive to synoptic and mesoscale interactions, largely attributable to Taeback mountains and East Sea effects. An intensive observation has been made in cooperation with Gangwon Regional Meteorological Office and National Institute of Meteorological Studies in winter seasons since 2019. Two distinctive Cold Air Damming (CAD) events (14 February 2019 and 6 February 2020) were observed for two years when the snowfall forecast was wrong specifically in its location and timing. For two CAD events, lower-level temperature below 2 km ranged to lowest limit in comparisons to those of the previous 6-years (2014~2019) rawinsonde soundings, along with the stronger inversion strength (> 2.0℃) and thicker inversion depth (> 700 m). Further, the northwesterly was predominant within the CAD layer, whereas the weak easterly wind was exhibited above the CAD layer. For the CAD events, strong cold air accumulation along the east side of Taeback Mountains appeared to prevent snow cloud and convergence zone from penetrating into the Yeongdong region. We need to investigate the influence of CAD on snowfall in the Yeongdong region using continuous intensive observation and modeling studies altogether. In addition, the effect of synoptic and mesoscale interactions on snowfall, such as nighttime drainage wind and land breeze, should be also examined.

Air Quality Modeling of Ozone Concentration According to the Roughness Length on the Complex Terrain (복잡지형에서의 지표면 거칠기에 따른 오존 농도 수치모의)

  • Choi, Hyun-Jung;Lee, Hwa-Woon;Sung, Kyoung-Hee
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.23 no.4
    • /
    • pp.430-439
    • /
    • 2007
  • The objective of this work is the air quality modeling according to the practical roughness length using the building information as surface boundary conditions. As accurate wind and temperature field are required to produce realistic urban air quality modeling, comparative simulations by various roughness length are discussed. The prognostic meteorological fields and air quality field over complex areas of Seoul, Korea are generated by the PSU/NCAR mesoscale model (MM5) and the Third Generation Community Multi-scale Air Quality Modeling System (Models-3/CMAQ), respectively. The simulated $O_3$ concentration on complex terrain and their interactions with the weak synoptic flow had relatively strong effects by the roughness length. A comparison of the three meteorological fields of respective roughness length reveals substantial localized differences in surface temperature and wind folds. Under these conditions, the ascended mixing height and weakened wind speed at night which induced the stable boundary stronger, and the difference of simulated $O_3$ concentration is $2{\sim}6\;ppb$.

Inhibitory Effects of 12 Ginsenosides on the Activities of Seven Cytochromes P450 in Human Liver Microsomes

  • Jo, Jung Jae;Shrestha, Riya;Lee, Sangkyu
    • Mass Spectrometry Letters
    • /
    • v.7 no.4
    • /
    • pp.106-110
    • /
    • 2016
  • Ginseng, a traditional herbal drug, has been used in Eastern Asia for more than 2000 years. Various ginsenosides, which are the major bioactive components of ginseng products, have been shown to exert numerous beneficial effects on the human body when co-administered with drugs. However, this may give rise to ginsenoside-drug interactions, which is an important research consideration. In this study, acassette assay was performed the inhibitory effects of 12 ginsenosides on seven cytochrome P450 (CYP) isoforms in human liver microsomes (HLMs) using LC-MS/MS to predict the herb-drug interaction. After incubation of the 12 ginsenosides with seven cocktail CYP probes, the generated specific metabolites were quantified by LC-MS/MS to determine their activities. Ginsenoside Rb1 and F2 showed strong selective inhibitory effect on CYP2C9-catalyzed diclofenac 4'-hydroxylation and CYP2B6-catalyzed bupropion hydroxylation, respectively. Ginsenosides Rd showed weak inhibitory effect on the activities of CYP2B6, 2C9, 2C19, 2D6, 3A4, and compound K, while ginsenoside Rg3 showed weak inhibitory effects on CYP2B6. Other ginsenosides, Rc, Rf, Rg1, Rh1, Rf, and Re did not show significant inhibitory effects on the activities of the seven CYPs in HLM. Owing to the poor absorption of ginsenosides after oral administration in vivo, ginsenosides may not have significant side effects caused by interaction with other drugs.

Non-axisymmetric Features of Dwarf Elliptical Galaxies

  • Kwak, Sungwon;Kim, Woong-Tae;Rey, Soo-Chang;Kim, Suk
    • The Bulletin of The Korean Astronomical Society
    • /
    • v.41 no.1
    • /
    • pp.39.3-39.3
    • /
    • 2016
  • About one tenth of dwarf elliptical galaxies found in the Virgo cluster have a disk component, and some of them even possess substructures such as bars, lens, and spiral arms. We use N-body simulations to study the formation of these non-axisymmetric features in disky dwarf elliptical galaxies. By mimicking VCC 856, a bulgeless dwarf galaxy with embedded faint spiral arms, we construct 11 sets of initial conditions with slight dynamical variations based on observational data. Our standard model starts slowly to form a bar at ~3 Gyr and then undergoes buckling instability that temporarily weakens the bar although the bar strength continues to grow afterward. We find 9 of our models are unstable to bar formation and undergo buckling instability. This suggests that disky dwarf elliptical galaxies are intrinsically unstable to form bars, accounting for a population of barred dwarf galaxies in the outskirts of the Virgo cluster. To understand the origin of the faint grand-design spiral arms, we additionally construct 6 sets of models that undergo tidal interactions with their neighbors. We find that faint spiral arms consistent with observations develop when tidal forcing is relatively weak although strong encounter still results in bar formation. We discuss our results in light of the dynamical evolution of dwarf elliptical galaxies including mergers.

  • PDF

Theoretical Studies of the Gas-Phase Identity Nucleophilic Substitution Reactions of Cyclopentadienyl Halides

  • Lee, Ik-Choon;Li, Hong-Guang;Kim, Chang-Kon;Lee, Bon-Su;Kim, Chan-Kyung;Lee, Hai-Whang
    • Bulletin of the Korean Chemical Society
    • /
    • v.24 no.5
    • /
    • pp.583-592
    • /
    • 2003
  • The gas phase identity nucleophilic substitution reactions of halide anions (X = F, Cl, Br) with cyclopentadienyl halides (1) are investigated at the B3LYP/6-311+G**, MP2/6-311+G** and G2(+)MP2 levels involving five reaction pathways: σ-attack $S_N2$, β-$S_N$2'-syn, β-$S_N$2'-anti, γ-$S_N$2'-syn and γ-$S_N$2'-anti paths. In addition, the halide exchange reactions at the saturated analogue, cyclopentyl halides (2), and the monohapto circumambulatory halide rearrangements in 1 are also studied at the same three levels of theory. In the σ-attack $S_N2$ transition state for 1 weak positive charge develops in the ring with X = F while negative charge develops with X = Cl and Br leading to a higher energy barrier with X = F but to lower energy barriers with X = Cl and Br than for the corresponding reactions of 2. The π-attack β-$S_N$2' transition states are stabilized by the strong $n_C-{\pi}^{*}_{C=C}$ charge transfer interactions, whereas the π-attack γ-$S_N$2' transition states are stabilized by the strong $n_C-{\sigma}^{*}_{C-X}$ interactions. For all types of reaction paths, the energy barriers are lower with X = F than Cl and Br due to the greater bond energy gain in the partial C-X bond formation with X = F. The β-$S_N$2' paths are favored over the γ-$S_N$2' paths only with X = F and the reverse holds with X = Cl and Br. The σ-attack $S_N2$ reaction provides the lowest energy barrier with X = Cl and Br, but that with X = F is the highest energy barrier path. Activation energies for the circumambulatory rearrangement processes are much higher (by more than 18 kcal $mol^{-1}$) than those for the corresponding $S_N2$ reaction path. Overall the gas-phase halide exchanges are predicted to proceed by the σ-attack $S_N2$ path with X = Cl and Br but by the β-$S_N$2'-anti path with X = F. The barriers to the gas-phase halide exchanges increase in the order X = F < Br < Cl, which is the same as that found for the gas-phase identity methyl transfer reactions.

Soil Physical and Hydraulic Properties over Terrace Adjacent Four Major Rivers

  • Lee, Kyo Suk;Lee, Jae Bong;Lee, Myoung Yun;Joo, Ri Na;Lee, Dong Sung;Chung, Doug Young
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.49 no.3
    • /
    • pp.235-241
    • /
    • 2016
  • The soil does not only serve as a medium for plant growth but also for engineering construction purposes. It is very weak in tension, very strong in compression and fails only by shearing. The behaviour of the soil under any form of loading and the interactions of the earth materials during and after any engineering construction work has a major influence on the success, economy and the safety of the work. Soils and their management have therefore become a broad social concern. A limitless variety of soil materials are encountered in both agronomy and engineering problems, varying from hard, dense, large pieces of rock through gravel, sand, silt and clay to organic deposits of soft compressible peat. All these materials may occur over a range of physical properties, such as water contents, texture, bulk density and strength of soils. Therefore, to deal properly with soils and soil materials in any case requires knowledge and understanding of these physical properties. The desired value of bulk density varies with the degree of stability required in construction. Bulk density is also used as an indicator of problems of root penetration,soil aeration and also water infiltration. This property is also used in foundation engineering problems. While not conforming to standard test procedures, this work attempts to add to the basic information on such important soil parameters as water content, bulk density.

The Effects of Fashion Mobile Word-of Mouth -Focus on Facebook- (패션제품에 대한 모바일 구전효과 -페이스북을 중심으로-)

  • Jung, Jieun;Choo, Ho Jung;Lee, Ha Kyung
    • Journal of the Korean Society of Clothing and Textiles
    • /
    • v.37 no.2
    • /
    • pp.186-201
    • /
    • 2013
  • This study investigates the effects of information type, direction of information, method of suggestion, tie strength, and interactions among these variables on the acceptance and diffusion of fashion product information in the mobile Facebook environment. Two subsequent studies were conducted to test the relationships among mobile SNS WOM factors. Two independent on-line surveys were implemented. Six hundred forty consumers aged between 20 and 39 were recruited for Study 1, and four hundred and eighty for Study 2. We manipulated the WOM delivery situation by information type (factual/evaluative), information directionality (positive/negative), tie-strength (strong/weak), and information presentation method (text/image/rink). Eight scenarios were developed and randomly assigned to the research participants. Frequency analysis, reliability, factor analysis, regression analysis, and ANOVA were implemented using SPSS 18.0. The Analysis of experiment data produced interesting results. Most WOM factors (including the information type, information presentation method, and tie strength) influence WOM acceptance; however, only the tie strength effected WOM activity. It was also proven that people are prone to accept information that is more realistic, objective, and negative, and they tend to accept information with visual factors, such as images and video clips rather than a simple text message. In this study, we offer a practical perspective to fashion industry and marketers who have an interest in SNS marketing. We have defined the distinct characteristics of mobile WOM that have been formed by a combination of former on/off-line WOM characteristics. To examine the moderating roles of two types of consumer innovativeness, fashion innovativeness and technology innovativeness were also measured and found to have significant moderating effects between mobile SNS WOM factors and their consequences. The paper concludes with a discussion on managerial implications and limitations.

Analysis of Microcystis Bloom in Daecheong Reservoir using ELCOM-CAEDYM (ELCOM-CAEDYM을 이용한 대청호 Microcystis Bloom 해석)

  • Chung, Se Woong;Lee, Heung Soo
    • Journal of Korean Society on Water Environment
    • /
    • v.27 no.1
    • /
    • pp.73-87
    • /
    • 2011
  • An abnormal mono-specific bloom of the cyanobacterium Microcystis aeruginosa had developed at a specific location (transitional zone, monitoring station of Hoenam) in Daecheong Reservoir from middle of July to early August, 2001. The maximum cell counts during the peak bloom reached 1,477,500 cells/mL, which was more than 6~10 times greater than those at other monitoring sites. The hypothesis of this study is that the timing and location of the algal bloom was highly correlated with the local environmental niche that was controled by physical processes such as hydrodynamic mixing and pollutant transport in the reservoir. A three-dimensional, coupled hydrodynamic and ecological model, ELCOM-CAEDYM, was applied to the period of development and subsequent decline of the bloom. The model was calibrated against observed water temperature profiles and water quality variables for different locations, and applied to reproduce the algal bloom event and justify the limiting factor that controled the Microcystis bloom at R3. The simulation results supported the hypothesis that the phosphorus loading induced from a contaminated tributary during several runoff events are closely related to the rapid growth of Microcystis during the period of bloom. Also the physical environments of the reservoir such as a strong thermal stratification and weak wind velocity conditions provided competitive advantage to Microcystis given its light adaptation capability. The results show how the ELCOM-CAEDYM captures the complex interactions between the hydrodynamic and biogeochemical processes, and the local environmental niche that is preferable for cyanobacterial species growth.

Structure of Water-Methanol Mixtures Studied by NIR Spectroscopy

  • Adachi, Daisuke;Katsumoto, Yukiteru;Sato, Harumi;Ozaki, Yukihiro
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
    • /
    • 2001.06a
    • /
    • pp.1283-1283
    • /
    • 2001
  • NIR spectroscopy has been used extensively to investigate the structure of water, alcohol and other self-associate molecules because the frequencies of NIR bands due to OH and NH groups strength of hydrogen bonds. We have studied the structure of water -methanol mixtures by use of NIR spectroscopy. Strong features in the 7200-6300 $cm^{-1}$ / region consist of a number of overlapped bands due to the combination of OH antisymmetric and symmetric stretching modes of water and the first overtone of the OH stretching modes of free and hydrogen bonded methanol, while weak fratures in the 6000-5800 cm-1 region are ascribed to the first overtones of $CH_3$ stretching modes of methanol. We will focus the discussion on the $CH_3$ stretching bands. They seem to show a significant shift is not clear from the spectra shown in figure 1(a). Figure 1(b) depicts the second derivative in the 6000-5700 $cm^{-1}$ / region. Now, it is clear from the second derivative that there are two major bands near 5950 and 5900 $cm^{-1}$ / and that they do show a shift be about 30 $cm^{-1}$ / Why do the $CH_3$ bands show the shift with increasing concentration of methanol\ulcorner Probably, the CH, group interacts directly with OH groups of water. The results in figure 1(b) demonstrate the usefulness of the second derivative in resolution enhancement as well as the potential of NIR spectroscopy in the studies of molecular interactions.(Figure omitted).

  • PDF