• Advances in Computational Design
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• 제1권1호
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• pp.27-35
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• 2016

The influences of chloride-free components of the cement additive: triethanolamine, triisopropanolamine, sodium hyposulfite and calcium gluconate on the 1d, 3d and 28d compressive strength of cement were investigated by response surface methodology. It found the early strength activators, triethanolamine and sodium hyposulfite could enhance the 1d strength of cement effectively but they did not contribute to the 3d strength enhancement, and further their interaction was able to decrease the 28d strength of cement. Calcium gluconate was not that effective for the strength enhancement on 3 and 28 days when it's simply dosed. However the interaction effect of calcium gluconate with triisopropanolamine could strongly favor the strength enhancement of cement after 3 days. Results indicated it was necessary to focus attention on the potential interactions among the chemical components. And for the concern of four chemicals studied in this paper, it was feasible to formulated a kind of chloride-free cement additive that can be effective for the early strength of cement and its the strength after 3 days.

• 한국농공학회지
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• 제42권6호
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• pp.115-121
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• 2000

The purpose of this research is to investigate properties and field application of non-shrinkage high strength concrete containing expansive additive. Before the field applications, several basic laboratory test are performed to evaluate the characteristics of air content, workability and strength of the concrete using calcium sulfa aluminate(CSA) expansive additive. As a result, high strength concrete using CSA expansive additive show similar workability and compressive strength to that normal concrete, and the optimum replacement ratio of them is obtained by 10% CSA expansive additive. Accordingly, it can be concluded that the use of CSA expansive additive is effective to prevent shrinkage crack and to achieve volume stability of concrete structure.

• 한국세라믹학회지
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• 제44권4호
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• pp.230-234
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• 2007

Cordierite ceramics were fabricated via a reaction sintering process using ceramics-filled polysiloxane as a precursor for cordierite ceramics. In this study, the effects of the additive composition, additive content, and sintering temperature on the sintered density and compressive strength of cordierite ceramics have been investigated The sintered densities of reaction-sintered cordierite ceramics containing $TiO_2$ as an additive were insensitive to the additive composition, additive content, and sintering temperature and ranged from $1.92g/cm^3\;to\;2.06g/cm^3$. In contrast, the cordierite ceramics containing $Y_2O_3$ showed a maximal density of $2.21g/cm^3$ at 5 wt% addition and at a sintering temperature of $1400^{\circ}C$. The compressive strength of cordierite ceramics showed the same tendency with the density. Typical compressive strength of cordierite ceramics containing 5 wt% $Y_2O_3$ as a sintering additive and sintered at $1400^{\circ}C\;was\;{\sim}480MPa$.

• 폴리머
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• 제38권5호
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• pp.620-625
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• 2014

Polyvinyl alcohol/polyamide-epichlorohydrin(PVA/PAE) 복합 지력증강제 처리에 따른 종이의 건조 및 습윤인장강도와 표면특성 변화를 살펴보았다. PVA/PAE 복합 지력증강제를 사용하는 경우, PVA와 PAE를 각각 첨가제로 사용하는 것에 비하여 건조 및 습윤 인장강도 증가와 함께 치수안정성이 우수해 짐을 알 수 있었으며 이는 PVA와 PAE의 물리적인 가교에 의한 결과로 해석할 수 있었다. PVA/PAE의 복합화는 PAE 지력증강제 처리에 의하여 발생하는 종이의 표면 거칠기의 증가를 최소화하며 동시에 사이징도 증가시켜 종이 인쇄 시 색농도 증가에 기여함을 알 수 있다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1999년도 학회창립 10주년 기념 1999년도 가을 학술발표회 논문집
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• pp.77-80
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• 1999

Before the field applications, several basic laboratory test were the characteristics of workability and strength of the concrete containing CSA expansive additive. As a result, high strength concrete using CSA expansive additive show similar workability and compressive to that of plain concrete, the optimum replacement ratio of them to plain concrete were obtained for CSA expansive additive 10%. On the other hand, it can be concluded that the use of CSA component is effective to prevent shrinkage crack reducing concrete using superplasticizer and to achive volume stability of concrete structure.

• International Journal of Concrete Structures and Materials
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• 제9권4호
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• pp.391-399
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• 2015

This study modeled the compressive strength and elastic modulus of hardened cement that had been treated with an expansive additive to reduce shrinkage, in order to determine the mechanical properties of the material. In hardened cement paste with an expansive additive, hydrates are generated as a result of the hydration between the cement and expansive additive. These hydrates then fill up the pores in the hardened cement. Consequently, a dense, compact structure is formed through the contact between the particles of the expansive additive and the cement, which leads to the manifestation of the strength and elastic modulus. Hence, in this study, the compressive strength and elastic modulus were modeled based on the concept of the mutual contact area of the particles, taking into consideration the extent of the cohesion between particles and the structure formation by the particles. The compressive strength of the material was modeled by considering the relationship between the porosity and the distributional probability of the weakest points, i.e., points that could lead to fracture, in the continuum. The approach used for modeling the elastic modulus considered the pore structure between the particles, which are responsible for transmitting the tensile force, along with the state of compaction of the hydration products, as described by the coefficient of the effective radius. The results of an experimental verification of the model showed that the values predicted by the model correlated closely with the experimental values.

• 한국농공학회:학술대회논문집
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• 한국농공학회 1999년도 Proceedings of the 1999 Annual Conference The Korean Society of Agricutural Engineers
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• pp.283-288
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• 1999

This study is performed to evaluate slump , air content, compressive strength and length change ratio of non-shrinkage high strength ocncrete is achieved by 10% expansive additive contained. The length change ration of non-shrinkage high strength concrete which is in water curing, shows 0.055% expansion in 10% expansive additive contained concrete and 0.308 expansion in 20% expansion additive contained concrete when it is curing 28 days.

• 대한기계학회논문집A
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• 제32권11호
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• pp.957-962
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• 2008

Crack-healing behavior of $Si_3N_4$ composite ceramics has been studied as functions of heat-treatment temperature and amount of additive $SiO_2$ colloidal. Results showed that optimum amount of additive $SiO_2$ colloidal and coating of $SiO_2$ colloidal on crack could significantly increase the bending strength. The heat-treatment temperature has a profound influence on the extent of crack healing and the degree of strength recovery. The optimum heat-treatment temperature depends on the amount of additive $SiO_2$ colloidal. Crack healing strength was far the better cracked specimen with $SiO_2$ colloidal coating on crack surface. After heat treatment at the temperature 1,273 K in air, the crack morphology almost entirely disappeared by scanning prob microscope. At optimum healing temperature 1,273 K, the bending strength with additive $SiO_2$ colloidal 0.0 wt.% without $SiO_2$ colloidal coating recovered to the value of the smooth specimens at room temperature for the investigated crack sizes $100\;{\mu}m$. But that with $SiO_2$ colloidal coating increase up to 140 %. The amount of optimum additive $SiO_2$ colloidal was 1.3 wt.% and crack healed bending strength with $SiO_2$ colloidal coating increase up to 160 % to smooth specimen of additive $SiO_2$ colloidal 0.0 wt.%. Crack closure and rebonding of the crack due to oxidation of cracked surfaces were suggested as a dominant healing mechanism operating in $Si_3N_4$ composite ceramics.

• 한국도로학회논문집
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• 제19권2호
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• pp.137-142
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• 2017

PURPOSES :The objective of this study is to evaluate the performance of asphalt mixtures containing inorganic additive and a high content of reclaimed asphalt pavement (RAP). METHODS : The laboratory tests verified the superior laboratory performance of inorganic additive compared to cement, in cold recycled asphalt mixtures. To investigate the moisture susceptibility of the specimens, tensile strength ratio (TSR) tests were performed. In addition, dynamic modulus test was conducted to evaluate the performance of cold recycled asphalt mixture. RESULTS :It was determined that NaOH solution mixed with $Na_2SiO_3$ in the ratio 75:10 provides optimum performance. Compared to Type B and C counterparts, Type A mixtures consisting of an inorganic additive performed better in the Indirect tensile strength test, tensile strength ratio test, and dynamic modulus test. CONCLUSIONS : The use of inorganic additive enhances the indirect strength and dynamic modulus performance of the asphalt mixture. However, additional experiments are to be conducted to improve the reliability of the result with respect to the effect of inorganic additive.

• 콘크리트학회논문집
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• 제19권5호
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• pp.647-653
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• 2007

레디믹스트콘크리트 공장에서 동절기에 고분자 화학 혼화제, 특히 조기강도 확보를 위해 개발된 액상형 조강제를 사용할 경우, 해당 혼화제의 저장 안정성을 검토할 필요가 있다. 본 연구에서는 액상형 조강제의 동결 및 겔화 특성을 검토하고, 이를 방지할 수 있는 재료적, 설비적 해결 방안을 제시하여, 실무 적용시의 품질관리 방안으로 제시하고자 하였다. 검토 결과, 액상형 조강제의 동결온도는 $-11.8^{\circ}C$ 정도로 확인되어 콘크리트의 강도 발현 온도한계보다 낮은 온도 범위로서 안정적인 것을 확인하였으며, $SiO_2$와 $Na_2O$의 mol비를 0.31 수준으로 디자인한 sodium silicate를 $37{\pm}0.5%$ 포함시켜 제조함에 따라 저온에서의 겔화를 최소화하는 한편, 이의 저장 및 공급을 위해 고안된 설비 시설은 공급탱크의 온도를 $40^{\circ}C$ 정도로 설정하여 설비 전단계의 온도 분포가 실무 활용상 문제가 없음을 확인할 수 있었다.