• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2017년도 제48회 춘계학술대회논문집
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• pp.628-631
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• 2017

정상초음파가 인가된 탄화수소계 연료별/공기 혼합물의 당량비에 따른 연소특성 비교를 실험적 연구 결과로 제시한다. 전파화염의 이미지는 고속카메라를 이용하여 획득하였으며, 이미지 후처리를 통해 연료별 연소특성을 면밀히 관찰하였다. 정상초음파를 인가하면 탄화수소계 연료/공기 예혼합기의 이론당량비조건에서 연소반응을 촉진시킨다는 점을 확인하였다.

• 한국자동차공학회논문집
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• 제11권5호
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• pp.15-21
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• 2003

The liquid phase LPG injection engine is a new technology to make good use of LPG as a clean energy. However, it is difficult to precisely control air/fuel ratio in the system because of variation of fuel composition, change of temperature and flash boiling injection mechanism. This study newly suggests an injector control logic for liquid phase LPG injection systems. This logic compensates a number of effects such as variations of density, stoichiometric air/fuel ratio, injection delay time, injection pressure, release pressure which is formed by flash boiling of fuel at nozzle exit. This logic can precisely control air/fuel ratio with only two parameters of intake air flow rate and injection pressure without considering fuel composition, fuel temperature.

• 대한전기학회논문지
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• 제45권1호
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• pp.81-85
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• 1996

Microwave dielectric properties of 0.15(B $a_{x}$S $r_{0.05}$)O-0.15(S $m_{2}$(1-y)N $d_{2y}$) $O_{3}$-0.7Ti $o_{2}$(x=o.9~0.1[mol.], y=6[m/o]) ceramics were investigated with BaO compositional ratio. Sintered density and resistivity of specimens were independent on the BaO compositional ratio. In the specimen with x=0.975[mol.], dielectric constant, quality factor and temperature coefficient of resonant frequency had good values of 76.52, 3001(at 3[GHz]) and +0.71[ppm/.ceg. C], respectively. By comparing with the stoichiometric compositions of 78.14, 2938(at 3[GHz])+14.19[ppm/.ceg. C], dielectric constant and quality factor showed similar properties, but the temperature coefficient of resonant frequency was highly improved. (author). refs., figs., tabs.s.s.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2003년도 제20회 춘계학술대회 논문집
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• pp.270-273
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• 2003

The characteristic of constant volume micro combustor was investigated experimentally. The shape of micro combustor was cylindrical and has row aspect ratio or has relatively large diameter compared with chamber height. Diameter and chamber height was varied to investigate the geometric effect of combustor on the flame propagation. Diameter of 15 mm and 7.5 mm was designed while chamber height was designed to be 1mm, 2mm, and 3mm. The effect of initial pressure was also investigated parametrically from 1bar to 3bar. The gas used in this study was stoichiometric mixture of methane and air. The maximum pressure achieved in down scaled combustors was lower than that of conventional combustor because heat loss to wall was dominant as expected. The maximum pressure responded favorably with the change of height of combustor and the initial pressure, the maximum pressure was also increased. The flame propagation was possible when the specific condition was satisfied. Although the quenching distance of stoichiometric mixture of CH4 and Air is 2.5 mm, the flame could propagate even under quenching distance as the initial pressure increased.

• 열처리공학회지
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• 제11권3호
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• pp.177-185
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• 1998

The purpose of this research is to investigate the effects of Co, Co-Ti addition on the sintering characteristic of $(Ti_{1-x}Alx)N$ material synthesized by the direct nitriding method for a application as a cermet material. The observed shrinkage rates of $(Ti_{1-x}Alx)N$ pellets increase with the additive (Co, Co-Ti) content, temperature and time, and also the pellets with the same additive content exhibit the shrinkage behavior that depends on the Ti/Al ratio. However, although the shrinkage rates in this study is the mast higher (36%), the density of the sintered $(Ti_{1-x}Alx)N$ pellet is below 80% density in theory because of the partial segregation and the dense band defect of AlCo compound. Consequentely, it is considered that Co was not effective as a binder material because the wettability of liquid Co metal on $(Ti_{1-x}Alx)N$ materials is poor, In $(Ti_{1-x}Alx)N$ with Ti-Co additive, the stoichiometric TiN is transformed by the under-stoichiometric TiNx(x<1.0) during sintering, leading to the good properties such as hardnees and hot oxidation.

• 대한기계학회논문집B
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• 제29권1호
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• pp.55-62
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• 2005

Combustion Characteristics and quenching criteria of micro combustor in various condition was exploited experimentally. Two different gases were used, and various geometric matrixes were considered to figure out quenching characteristic of micro combustor. The micro combustor studied in this study was constant volume, and has cylindrical shape. Geometric parameter of combustor was defined to be combustor height and diameter. The effect of height was exploited parametrically as 1 mm, 2mm and 3mm and the effect of diameter was parameterized to be 7.5mm and 15mm. Three different combustibles. (1) Stoichiometric mixture of methane and are, (2) Stoichiometric mixture of hydrogen and air and (3) Mixture of hydrogen and air with fuel stoichiometry of two were used. Pressure transition during combustion process was recovered. The ratio of maximum pressure to initial pressure responded favorably with the change of height of combustor and the initial pressure, the maximum pressure was also increased. The flame propagation was observed only when a specific condition was satisfied. From the experiment the condition that guarantees stable propagation of flame was tabulated. The tabulated results includes criteria of quenching according to combustor height, combustor diameter, species of fuel and initial pressure.

• 한국세라믹학회지
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• 제50권6호
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• pp.446-450
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• 2013

TRISO coated particles with a ZrC barrier layer were fabricated by a fluidized-bed chemical vapor deposition (FBCVD) method for a use in a very high temperature gas-cooled reactor (VHTR). The ZrC layer was deposited by the reaction between $ZrCl_4$ and $CH_4$ gases at $1500^{\circ}C$ in an $Ar+H_2$ mixture gas. The amount of free carbon codeposited with in ZrC was changed by controlling the dilution gas ratio. Near-stoichiometric ZrC phase was also deposited when an impeller was employed to a $ZrCl_4$ vaporizer which effectively inhibited the agglomeration of $ZrCl_4$ powders during the deposition process. A near-stoichiometric ZrC coating layer had smooth surface while ZrC containing the free carbon had rough surface with tumulose structure. Surface roughness of ZrC increased further as the amount of free carbon increased.

• Bulletin of the Korean Chemical Society
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• 제30권4호
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• pp.853-856
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• 2009

Highly polycrystalline copper indium diselenide (CuInSe2, CIS) thin films were deposited on glass or ITO glass substrates by two-stage metal organic chemical vapor deposition (MOCVD) at relatively mild conditions, using Cuand In/Se-containing precursors. First, pure Cu thin film was prepared on glass or ITO glass substrates by using a single-source precursor, bis(ethylbutyrylacetate)copper(II) or bis(ethylisobutyrylacetato)copper(II). Second, on the resulting Cu films, tris(N,N-ethylbutyldiselenocarbamato)indium(III) was treated to produce CuInSe2 films by MOCVD method at 400 ${^{\circ}C}$. These precursors are very stable in ambient conditions. In our process, it was quite easy to obtain high quality CIS thin films with less impurities and uniform thickness. Also, it was found that it is easy to control the stoichiometric ratio of relevant elements on demands, leading to Cu or In rich CIS thin films. These CIS films were analyzed by XRD, SEM, EDX, and Near-IR spectroscopy. The optical band gap of the stoichiometric CIS films was about 1.06 eV, which is within an optimal range for harvesting solar radiation energy.

• 한국재료학회지
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• 제16권12호
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• pp.719-724
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• 2006

Ultrafine mullite powder was prepared from aluminium-secbutoxide and tetraethyl orthosilicate(TEOS) in the molar $Al_2O_3/SiO_2$=3/2. Sol-gel method by partial hydrolysis technique, as it were, first, TEOS was partially hydrolysized and then mixed with Al-secbutoxide for complete hydrolysis was used. X-ray diffraction, infrared spectroscopy and transmission electron microscopy, etc. confirmed that the mullite powder prepared by this method is in the stoichiometric $Al_2O_3/SiO_2$ ratio. Al-Si spinel was formed at $980^{\circ}C$ and ultrafine mullite powder with about 20 nm particle size was obtained above $1,200^{\circ}C$. Also mullite powders calcined at $1,600^{\circ}C$ had a stoichiometric composition, $3Al_2O_3{\cdot}2SiO_2$ and the lattice constants of the mullite powders calcined above $1,200^{\circ}C$ were almost coincided with theoretical values.

• Korean Chemical Engineering Research
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• 제59권1호
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• pp.138-151
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• 2021

The effect of a reactant ratio on the growth of a buoyancy-driven instability in an irreversible A+B→C reaction system is analyzed theoretically and numerically. Taking a non-stoichiometric reactant ratio into account, new linear stability equations are derived without the quasi-steady state assumption (QSSA) and solved analytically. It is found that the main parameters to explain the present system are the Damköhler number, the dimensionless density difference of chemical species and the ratio of reactants. The present initial grow rate analysis without QSSA shows that the system is initially unconditionally stable regardless of the parameter values; however, the previous initial growth rate analysis based on the QSSA predicted the system is unstable if the system is physically unstable. For time evolving cases, the present growth rates obtained from the spectral analysis and pseudo-spectral method support each other, but quite differently from that obtained under the conventional QSSA. Adopting the result of the linear stability analysis as an initial condition, fully nonlinear direct numerical simulations are conducted. Both the linear analysis and the nonlinear simulation show that the reactant ratio plays an important role in the onset and the growth of the instability motion.