• 한국응용과학기술학회지
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• 제28권1호
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• pp.6-9
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• 2011

Step feed process was analyzed stoichiometrically for the optimal operation conditions in this study. In case of optimal operation conditions, minimum R (sludge recycling) value, r (internal recycling ratio) value, and n (influent allocation ratio) value for the step feed process to acquire the maximum TN removal efficiency were identified by theoretical analysis. Maximum TN removal efficiency, based on stoichiometric reaction, can be obtained by controlling n value for the step feed process.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2011년도 춘계학술대회 초록집
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• pp.93.1-93.1
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• 2011

To obtain higher power efficiency of Residential Power Generation System(RPG), it is needed to operate system on optimized stoichiometric ratio of fuel and air. In this paper, optimizing stoichiometric ratio of fuel/air is conducted through systematic experiments and modeling. Based on fundamental principles and experimental data, constraints are chosen. Using these stoichiometric ratios as decision variables, maximum power efficiency of system could be found. As a result of research, power efficiency of RPG system is improved.

• 한국결정성장학회지
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• 제10권1호
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• pp.48-54
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• 2000

kaolin과 수산화알루미늄을 이용하여 mullite를 합성하는데 있어서 출발원료의 조성을 silica rich, stoichiometric, alumina rich 조성으로 준비하여 각각의 원료로부터 mullite를 합성할 때 mullite-seed가 미치는 영향을 연구하였다. 그 결과 silica rich 조성과 stoichiometric 조성에서는 mullite-seed의 첨가량이 증가할수록 꺾임강도값이 증가하며, alumina rich 조성에서는 mullite-seed의 첨가량이 증가할수록 꺾임강도값은 감소하는 경향을 보였다. 같은 양의 mullite-seed를 첨가했을 때 미세구조는 alumina 첨가 함량이 증가할수록 치밀도가 감소하고, aspect ratio는 증가하는 경향을 나타내었다. 순도면에서는 mullite정량결과 모든 조성에서 mullite-seed의 첨가량이 많을수록 합성된 mullite 결정상의 함량이 증가하는 경향을 보였다.

• 대한기계학회논문집
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• 제16권11호
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• pp.2119-2125
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• 1992

본 연구에서는 현재 사용되고 있는 산소센서의 단점을 극복할 수 있는 방법을 광역공연비센서처럼 공연비를 추정할 수 있는 방법을 연구한다. 그 방법으로 신경회 로망을 사용한 배기가스의 공연비 추정기(estimator)를 구성한다. 그리고 이 추정기 를 이용한 공연비 제어기를 설계하고 실제 MPI엔진에 적용하여 그 성능을 알아 보겠다.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 춘계학술대회논문집D
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• pp.79-84
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• 2001

The effect of spray characteristics on desulfurization yield was evaluated by performing experiments with pilot spray drying sorber (SDS). Among the variables of operating conditions, the slurry-spraying conditions were chosen as major parameters; Stoichiometric ratio and Sauter mean diameter of slurry droplet were varied for the different gas temperatures and $SO_{2}$ concentrations in the inlet gas flow. From the experimental results, we proposed semi-empirical models of desulfurization yield for both Stoichiometric ratio and Sauter mean diameter of droplets. The optimal condition of spray can be determined based on these results, which might be applied to the design or scale-up of SDS systems.

• International Journal of Automotive Technology
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• 제8권3호
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• pp.283-288
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• 2007

This paper presents the static characteristics of a urea-SCR system. The static characterization of the urea-SCR system was generated by sweeping urea flow rates at common engine torque/speed operating points. Several experiments were performed using engine operating points at different raw NOx emission levels, space velocities, and SCR catalyst temperatures. The recorded NOx emissions from the engine exhaust outlet and engine tailpipe are then compared. The urea-SCR static system results indicated that a $50{\sim}60%$ NOx conversion is achievable at most engine operating points using the stoichiometric $NH_3/NOx$ ratio, and a high 98% NOx conversion is possible by exceeding the stoichiometric $NH_3/NOx$ ratio. The effect of the pre-oxidation catalyst volume was also investigated and found to have a profound impact on experimental results, particularly the static NOx conversion.

• 대한기계학회논문집B
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• 제33권3호
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• pp.207-214
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• 2009

Crossover of nitrogen from cathode to anode is inevitable in typical membranes used in PEM fuel cells. This crossovered nitrogen normally accumulates in the hydrogen recirculation system at anode side channels. Excessive buildup of nitrogen in the anode side lowers the relative hydrogen concentration and finally affects the performance of fuel cell stack. So it is very important to analysis the nitrogen gas crossover at various operating conditions. In this study, characterization of nitrogen gas crossover in PEM fuel cell stack was investigated. The mass spectroscopy (MS) has been applied to measure the amount of the crossovered nitrogen gas at the anode exit. Results show that nitrogen gas crossover rate was affected by current density, anode and cathode stoichiometric ratio and operating pressure. Current density, anode stoichiometric ratio and anode operating pressure do not affect nitrogen crossover rate but anode exit concentration of nitrogen. Cathode pressure and stoichiometric ratio largely affect the nitrogen crossover rate.

• 대한환경공학회지
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• 제27권11호
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• pp.1222-1227
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• 2005

대표적인 질소제거 시스템인 무산소-산소공정을 대상으로 주어진 유입수 수질 조건에서 최대의 질소제거를 위한 최적의 슬러지 반송비를 질화/탈질 반응식을 이용하여 양론적으로 계산하였다. 양론적 계산에 고려된 수질 항목은 질화/탈질에 영향을 미치는 암모니아성 질소, 질산성질소, 알칼리도, COD, 용존산소로 설정하였다. 최대의 질소제거를 위한 최적의 슬러지 반송비를 앞의 5가지 유입수 항목으로 나타내었다. 양론적 계산에 의한 각 공정의 유출수와 최종 유출수 중의 TN농도가 실제 보고된 하 폐수 처리장의 TN농도와 잘 일치 하였다. 또한 양론적 계산에 의해 실제 처리장 최종 유출수 중의 TN농도를 ${\pm}5.0\;mg/L$ 내에서 예측 가능하였다.

• 한국수소및신에너지학회논문집
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• 제24권5호
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• pp.373-385
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• 2013

To obtain higher power efficiency of Residential Power Generation system(RPG), it is needed to operate system on optimized stoichiometric ratios of fuel and air. Stoichiometric ratios of fuel/air are closely related to efficiency of stack, reformer and power consumption of Balance Of Plant(BOP). In this paper, optimizing stoichiometric ratios of fuel/air are conducted through systematic experiments and modeling. Based on fundamental principles and experimental data, constraints are chosen. By implementing these optimum values of stoichiometric ratios, power efficiency of the system could be maximized.

• 한국분무공학회지
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• 제28권2호
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• pp.55-61
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• 2023

Natural gas is a high-octane fuel that is effective in controlling knocking combustion. In addition, as a low-carbon fuel with a high hydrogen-carbon ratio, it emits less carbon dioxide and almost no particulate matter compared to conventional fossil fuels. Stoichiometric combustion engines equipped with a three-way catalyst are useful in various fields such as transportation and power generation because of their excellent exhaust emission reduction performance. However, stoichiometric combustion engines have a disadvantage of lower thermal efficiency compared to lean combustion engines. In this study, a combination of high compression ratio and Atkinson cycle was implemented in a 11 liter, 6-cylinder, spark-ignition engine to improve the thermal efficiency of the stoichiometric engine. As a result, pumping and friction losses were reduced and the operating range was extended with optimized Atkinson camshaft. Based on the exhaust gas limit temperature of 730℃, the maximum load and thermal efficiency were improved to BMEP 0.66 MPa and BTE 35.7% respectively.