• Proceedings of the Optical Society of Korea Conference
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• 2004.02a
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• pp.330-331
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• 2004

• Journal of Korean Society of Environmental Engineers
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• v.27 no.11
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• pp.1222-1227
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• 2005

Optimal sludge recycling ratio for maximum total nitrogen(TN) removal efficiency was calculated stoichiometrically using nitrification and denitrification reaction with given influent water qualities in anoxic-oxic process which was one of the popular nitrogen removal system. The water quality items for stoichiometric calculation were ammonia, nitrite, nitrate, alkalinity, COD, and dissolved oxygen which could affect nitrification and denitrification. Optimal sludge recycling ratio for maximum TN removal efficiency was expressed by those five influent water qualities. TN concentration calculated stoichiometrically had kept good relationship with reported TN concentration in each tank and final effluent. In addition, it was possible to expect the TN concentration in final effluent by stoichiometric calculation within ${\pm}5.0\;mg/L$.

• Fire Science and Engineering
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• v.27 no.3
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• pp.47-51
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• 2013

The explosion limit is one of the major combustion properties used to determine the fire and explosion hazards of the flammable substances. The explosion limit of organic acids have been shown to be correlated the heat of combustion and the chemical stoichiometric coefficients. In this study, the lower explosion and upper explosion limits of organic acids were predicted by using the heat of combustion and chemical stoichiometric coefficients. The values calculated by the proposed equations agreed with literature data within a few percent. From the given results, using the proposed methodology, it is possible to predict the explosion limits of the other organic acids.

• Journal of the Korean Ceramic Society
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• v.53 no.6
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• pp.610-614
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• 2016

Tyranno SA (SiC-polycrystalline fiber, Ube Industries Ltd.) shows excellent heat-resistance up to $2000^{\circ}C$ with relatively high mechanical strength. This fiber is produced by the conversion process from a raw material (amorphous Si-Al-C-O fiber) into SiC-polycrystalline fiber at very high temperatures over $1500^{\circ}C$ in argon. In this conversion process, the degradation reaction of the amorphous Si-Al-C-O fiber accompanied by a release of CO gas for obtaining a stoichiometric composition and the subsequent sintering of the degraded fiber proceed. Furthermore, vaporization of gaseous SiO, phase transformation and active diffusion of the components of the Si-Al-C-O fiber competitively occur. Of these changes, vaporization of the gaseous SiO during the conversion process results in an abnormal SiC-grain growth and also leads to the non-stoichiometric composition. However, using a modified Si-Al-C-O fiber with an oxygen-rich surface, vaporization of the gaseous SiO was effectively prevented, and then consequently a nearly stoichiometric SiC composition could be obtained.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.10 no.1
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• pp.48-54
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• 2000

Influence of seed addition on the mullite synthesis was investigated from mixture powders of kaolin and aluminium trihydroxide which contain various $Al_2O_3$/SiO_2$ ratio (silica rich, stoichiometric, alumina rich). The flexural strength increases with the increase of the mullite-seed content in case of silica rich and stoichiometric mullite, but flexural strength decreases with the increase of the mullite-seed content in case of alumina rich mullite. Microstructural investigation revealed that aspect ratio of mullite grains increased with higher alumina content, along with lower sintered density. Mullite contents of specimens are increased with seed content regardless of $Al_2O_3$/SiO_2$ ratio of the mixture composition.

• Journal of the Korean Institute of Gas
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• v.19 no.2
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• pp.5-11
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• 2015

The explosion limit is one of the major combustion properties used to determine the fire and explosion hazards of the flammable substances. The explosion limit of aldehydes have been shown to be correlated the heat of combustion and the chemical stoichiometric coefficients. In this study, the lower explosion and upper explosion limits of aldehydes were predicted by using the heat of combustion and chemical stoichiometric coefficients. The values calculated by the proposed equations agreed with literature data above determination coefficient 0.99. From the given results, using the proposed methodology, it is possible to predict the explosion limits of the aldehydes.

• Journal of the Korean Society for Heat Treatment
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• v.8 no.2
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• pp.137-148
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• 1995

The nitridation kinetics of titanium powder were studied by isothermal and non-isothermal (dynamic) methods in high purity nitrogen under I atm pressure. For the comparison with nitridation, the oxidation kinetics of titanium powder were also studied in dry oxygen at I atm pressure. An automatic recording electrobalance was used to measure the weight gain as a function of time and temperature. For the reaction with nitrogen, the nitride was formed at over $700^{\circ}C$. The reaction with nitrogen followed the parabolic rate law, and the activation energy was calculated to be 31 kcal/mol in the isothermal method (above $900^{\circ}C$). The non-stoichiometric TiNx has been synthesized by the nitridation at a proper temperature and time, followed by the homogenizing treatment above $1100^{\circ}C$. In comparison with the stoichiometric $TiN_{1.0}$ and the non-stoichiometric TiNx ($TiN_{0.5}$ and $TiN_{0.65}$), the hot oxidation characteristics of the former is superior to that of the latter. However, both non-stoichiometric nitrides make little difference in the hot oxidation characteristics.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.16 no.6
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• pp.235-239
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• 2006

ZnO-doped near-stoichiometric $LiNbO_3$ single crystals of $0.8{\sim}1.0mm$ diameter and $30{\sim}35mm$ length were grown by the micro-pulling down (U-PD) method. The structure of the grown crystals was confirmed by powder x-ray diffraction (XRD) patterns. Electron probe micro analysis (EPMA) showed that Zn ions were homogeneously incorporated In grown crystals. The threshold in ZnO doping level was confirmed that an abrupt change in the features of $OH^-$ absorption band as doping level reaching about 2 mol%.

• Fire Science and Engineering
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• v.22 no.3
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• pp.228-233
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• 2008

Detonation limit is one of the major physical properties used to determine the fire and explosion hazards of the flammable substances. In this study, the lower detonation limits (LDL) and the upper detonation limits (UDL) of the flammable substances predicted with the appropriate use of the heat of combustion and the stoichiometric coefficient. The values calculated by the proposed equations were a good agreement with literature data within a few percent. From a given results, It is to be hoped that this methodology will contribute to the estimation of the detonation limits of for other flammable substances.

• Bulletin of the Korean Chemical Society
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• v.26 no.11
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• pp.1761-1766
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• 2005

Solvolysis rates of isopropenyl chloroformate (3) in water, $D_2O$, $CH_3OD$ and in aqueous methanol, ethanol, 2,2,2-trifluoroethanol (TFE), acetone, 1,4-dioxane as well as TFE-ethanol at 10 ${^{\circ}C}$ are reported. Additional kinetic data for pure water, pure ethanol and 80%(w/w) 2,2,2-trifuoroethanol (T)-water (W) at various temperatures are also reported. These rates show the phenomena of maximum rates in specific solvents (30% (v/v) methanol-water and 20% (v/v) ethanol-water) and, variations in relative rates are small in aqueous alcohols. The kinetic data are analyzed in terms of GW correlations, steric effect, kinetic solvent isotope effects (KSIE), and a third order model based on general base catalysis (GBC). Solvolyses based on predominately stoichiometric solvation effect relative to medium solvation are proceeding in 3 and the results are remarkably similar to those for p-nitrobenzoyl chloride (4) in mechanism and reactivity.