• Title/Summary/Keyword: stirring effect

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Effects of Secondary Forming Process on Mechanical Properties of $SiC_p$/Al Composites Fabricated by Squeeze Casting (용탕단조법에 의하여 제조한 $SiC_p$/Al 복합재료의 2차 성형공정이 기계적 성질에 미치는 영향)

  • Seo, Y.H;Kang, C.G
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.20 no.11
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    • pp.3474-3490
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    • 1996
  • A metal matrix composites(MMCs) for A16061 reinforced with silicon carbide particles is fabricated by melt-stirring method. The primary products of MMCs billets are prepared by volume fractions 5 vol% to 20 vol% and particle size $13\mu m$ to $22\mu m$.This paper will be made to examine the microstructure and mechanical properties of fabricated $SiC_p$/Al 6061 composite by melt-stirring and squeeze casting method. The MMC billets is extruded at $500^{\circ}C$ under the constant extrusion velocity $V_e$=2mm/min using curved shape die. Extrusion force, particle rearrangement, micro structure and mechanical properties of extruded composites will be investigated. The mechanical properties of primary billets manufactured by melt-stirring and squeeze casting method will be compared with extrusion specimen. The effect of volume fraction and size of the reinforcements will be studied. The increase in uniformity of particle dispersion is the major reason for an improvement in reliability due to hot extrusion with optimal shape die. Experimental Young's modulus and 0.2% offset yield strength for the extruded MMCs will be compared with theretical values calculated by the Eshelby method. A method will be proposed for the prediction of Young's modulus and yield strength in $SiC_p$ reinforced MMCs.

Polymorphism of Sulpiride and Its Pharmaceutical Applications ( III ) -Dissolution Kinetics of Sulpiride Polymorphs- (Sulpiride의 Polymorphism 및 그 약제학적(藥劑學的) 연구(硏究) (제3보)(第三報) -Polymorph에 따른 용출속도(溶出速度)-)

  • Lee, Min-Hwa;Kim, Kil-Soo
    • Journal of Pharmaceutical Investigation
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    • v.12 no.3
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    • pp.55-63
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    • 1982
  • The dissolution kinetics for polymorphs of sulpiride, the effect of polyethylene glycol 4000 on the dissolution kinetics of sulpiride polymorphs and the dissolution rate difference between the tablets of polymorph form I and form II were investigated. The results could be summerized as followings: 1. The dissolution rates of two polymorphs of sulpiride were significantly different and the thermodynamic parameters calculated from dissolution kinetics were as follows; transition temperature $98^{\circ}C$, enthalpy change, -2.108 kcal/mole, free energy change, -783 cal/mole $(31.0^{\circ}C)$. 2. The dissolution rates of the two polymorphs of sulpiride containing polyethylene glycol 4000 were significantly diefferent in 0.01N HCl but the effect of polyethylene glycol on the dissolution rates of two polymorphs was not significant at low concentration of polyethylene glycol 4000. The study on the effect by stirring speed showed that at lower stirring speed the promotion rate of dissolution of polymorph form I is greater than that of form II. 3. In the case of tablets the dissolution rates of polymorph form I of sulpiride was two fold as compared with the results obtained from form II.

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Defect Prediction in Part Fabrication Process of Metal Matrix Composites by Thixoforging Process (Thixoforging을 이용한 중공형 금속복합재료 부품의 성형공정에 있어서 결함예측)

  • 윤성원;김병민;강충길
    • Transactions of Materials Processing
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    • v.12 no.2
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    • pp.102-109
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    • 2003
  • In the manufacturing process of metal matrix composites parts, thixoforging is one of the most effective forming processes. The major purpose of the current study is to provide the proper conditions such as the die shape, the forging velocity, the forging time, the forging pressure and reinforcement injection velocity and pressure on various defects in thixoforged cylinder liner, filling tests were performed by MAGMA S/W. In order to evaluate the effectiveness of the calculated conditions which is given by computer aided engineering, A357, A380 and SiC$_{p}$/A380 cylind~5$mu extrm{m}$r liner were fabricated under the calculated conditions. SiC$_{p}$/A380 composite billets were fabricated by both the mechanical stirring and electrical magnetic stirring process. Incase fo SiC$_{p}$/A380 composite cylinder liner, reinforcement distribution and effect of reinforcement(SiC$_{p}$) content(10~20 vol. %)and size(5.5~14${\mu}{\textrm}{m}$) on the mechanical properties were investigatedstigated.

Reheating Process of Particulates Reinforced Metal Matrix Composites for Thixoforming (Thixoforming을 위한 입자강화형 금속복합재료의 Reheating 공정)

  • 이동건;안성수;강충길
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2000.04a
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    • pp.218-223
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    • 2000
  • A both mixing process of electro-magnetic stirring and mechanical process technique were used to fabricate particulate metal matrix composites(PMMCs) for variation of particle size. The PMMCs were tested for their tensile test for with and without heat treatment with T6. PMMCs fabrication processing conditions for both electrical and mechanical process are also suggested. In order to thixoforming of PMMCs, fabricated billet are reheated by using the optimal coil designed as a function of length between PMMC billet and coil surface, coil diameter and billet length. The effect of reinforcement distribution on billet temperature variation are investigated with calculated solid fraction theory proposed as a function of matrix alloy and volume fraction of reinforcement.

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Effects of Stirring and Addition of Chemical Compounds on Glycerolysis of Triglyceride in Reversed Micelles

  • Chang, Pahn-Shick
    • Journal of Microbiology and Biotechnology
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    • v.1 no.3
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    • pp.197-201
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    • 1991
  • Glycerolysis of triolein by lipase from Chromobacterium viscosum lipase was studied batchwise in AOT-isooctane reversed micelles. The reaction mixture was extracted with chloroform and the content of triolein, 1, 2-diolein, 1, 3-diolein, 1-monoolein, and free fatty acid in the condensed chloroform solution was determined using high performance liquid chromatography (HPLC). The effect of agitation speed on the initial rate of conversion was examined. As the speed of agitation increased up to 700 rpm, the reaction rate increased. However, above 700 rpm, the rate approached maximum and did not increase that much. The glycerolysis activity and the stability of the enzyme were affected by stirring and addition of histidine or copper. Addition of histidine and copper increased the rates of glycerolysis but they are detrimental to the operational stability in reversed micelles.

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Effect of the Extrusion Ratios on Fiber Breakage and Orientation in Hot Extrusion Process in Metal Matrix Composites (금속복합재료의 열간압출공정에 있어서 압출비가 섬유의 파단 및 배향에 미치는 영향)

  • Kang, C.G.;Kang, S.S.;Kim, B.H.
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.17 no.7 s.94
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    • pp.1740-1750
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    • 1993
  • The aluminar short fiber reinforced composite materials for hot extrusion were fabricated by semi-solid stirring method, and extruded at extrusion temperature $400^{\circ}C$ with various extrusion ratio. The hot extrusion load of volume fraction 15% metal matrix composites and base alloy Al7075 has been compared. The fiber length distribution, fiber breakage and fiber orientation are investiged to know the fiber behaviour in before and after hot extrusion. The tensile strength of the hot extruded billet are experimentally determined for different of extrusion ratios, and compared with theorically calculated strength.

The Effect of Pressure on Liquid Segregation in Direct Rheo-Forging Process of Aluminum Alloys (알루미늄 소재의 레오로지 직접단조공정에서 가압력이 액상 편석에 미치는 영향)

  • Oh, S.W.;Bae, J.W.;Kang, C.G.
    • Transactions of Materials Processing
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    • v.16 no.3 s.93
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    • pp.178-186
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    • 2007
  • Rheo-forging process of aluminum alloy is suitable for large parts of net shape without defects and excellent mechanical properties in comparison with conventional die casting and forging process. To control the microstructure of the product with high mechanical properties in rheo-forming, solid fraction is required to prevent porosity and liquid segregation. Therefore, in rheo-forging process, die shape, pressure type and solid fraction are very important parameters. The defects such as porosity, liquid segregation and unfitting phenomena occur during rheo-forging process. To prevent these defects, mechanical properties and microstructure analysis of samples versus the change of pressure are carried out and the problem and its solutions are proposed. Also, the mechanical properties versus various pressures were compared with and without heat treatment. The alloys used for rheo-forming are A356 and 2024 aluminum alloy. The rheology material is fabricated by electromagnetic process with controlling current and stirring time.

Effects of Freezing Conditions on the Concentration-Efficiency in the Progressive Freeze-Concentration (Progressive Freezing에 의한 동결 농축법에 있어서의 농축효과에 미치는 동결조건의 영향)

  • 배승권
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.24 no.6
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    • pp.984-989
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    • 1995
  • The concentration-efficiencyh of blue dextran solution in the progressive freeze-concentration was related to the freezing conditions such as the freezing speed and the stirring speed in the solution phase. From the theoreticla balance equation of heat and mass transfer at freezing front, the relationship between the freezing conditions and the ice structure at freezing front was drived. A high freeze-concentration efficiency was obtained under the operating conditions represented by a low speed of freezing and a high speed of stirring. The operating conditions were related to a smooth solid-liquid interface and these results were well explained by the theoretical equation. Effect of the solute component size on the concentration efficiency in the progressive freezeconcentration was also tested. The concentration efficiency of latex particles showed a lower value than that of blue dextran, however, its difference was insignificant.

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Separation of Chromium(VI) Ion in Industrial Waste Water throunh Liquid Surfactant Membrane (산업폐수중 유화액막에 의한 크롬(VI)의 분리)

  • 초민승;강안수;우인성;이영순
    • Journal of the Korean Society of Safety
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    • v.4 no.1
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    • pp.15-24
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    • 1989
  • The transport of Chromium(Vl) ion from waste water throughl the liquid surfactant membrane containing tri-n-octylamine as a carrier, was analyzed by a slab model and was investigated through experiments. For the experiment of membrane stability, concentrations of surfactant and liquid parafnn oil were analyzed. Extraction euperiments were carried out to observe the effect of system variables, such as stirring speed, concentration of carrier, and NaOH in internal aqueous phase, and concentrations of H$_2$SO$_4$and initial chromium(VI) ion in external aqueous phase at $25^{\circ}C$. It is concluded that the most stable formation of liquid membrane emulsion was obtained when surfactant concentration is above 3 wt. % and liquid parafnn oil concentration is 50 vol. %. The transport of chromium(VI) ion in bacth extractor increased with increasing carrier concentration, the volume ratio of emulsion to external aqueous phases, and initial concentration of chromium(VI) ion under the optimum stirring speed of chromium(VI) ion below 2 ppm. The theoretical equation on the transport of chromium(Vl) ion agreed well with the experimental results.

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Effect of Al-5Ti-B on the Microstructure of Rheology Material (Al-5Ti-B가 레오로지 소재의 미세조직에 미치는 영향)

  • Yang Z.;Seo P. K.;Kang C. G.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2005.05a
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    • pp.299-302
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    • 2005
  • Semisolid A356 slurries were prepared by electromagnetic stirring casting and by inoculation of Al-5Ti-B master alloy. As stirring time and addition of Al-5Ti-B are different, the grain size of the primary phase is different. Through the experiment of rheocast in a Buhler horizontal die casting machine, it was found that the finer the equiaxed primary dendrites, the smoother the die filling and better cast quality. Small equiaxed primary dendrite also results in less liquid segregation on the surface.

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