• Title/Summary/Keyword: starch/glycerol film

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Relationship between RVA Properties and Film Physical Properties of Native Corn Starch and Hydroxypropylated Corn Starch (천연옥수수전분과 hydroxypropyl화 옥수수전분의 RVA특성과 필름 물성의 관계)

  • Han, Youn-Jeong;Kim, Suk-Shin
    • Korean Journal of Food Science and Technology
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    • v.34 no.6
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    • pp.1023-1029
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    • 2002
  • Relationship between RVA properties and physical properties of film made from native corn starch and hydroxypropylated corn starch at various levels of plasticizers was examinel. Tensile strength of the film decreased, but its elongation and water vapor permeability increased with increasing plasticizer concentration. The film with glycerol showed greater changes in physical properties than that with sorbitol. Hydroxypropylated starch film showed lower tensile strength, higher elongation, and higher water vapor permeability than the native starch film. Sorbitol resulted in films with relatively high tensile strength, whereas glycerol produced films with increased elongation. The most reliable parameters for the relationship between RVA properties and film properties were RVA peak viscosity, tensile strength, and water vapor permeability. Water vapor permeability and tensile strength had linear relationship with RVA properties. The tensile strength and water vapor permeability of film could be predicted using the RVA peak viscosity.

Relationship between Moisture Barrier Properties and Sorption Characteristics of Edible Composite Films

  • Ryu, Sou-Youn;Rhim, Jong-Whan;Lee, Won-Jong;Yoon, Jung-Ro;Kim, Suk-Shin
    • Food Science and Biotechnology
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    • v.14 no.1
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    • pp.68-72
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    • 2005
  • Moisture sorption characteristics of edible composite films were determined and compared against moisture barrier properties. Edible composite films were Z1 (zein film with polyethylene glycol(PEG) and glycerol), Z2 (zein film with oleic acid), ZA1 (zein-coated high amylose corn starch film with PEG and glycerol), and ZA2 (zein-coated high amylose corn starch film with oleic acid). Z2 film showed the lowest equilibrium moisture content (EMC), monolayer value ($W_m$), water vapor permeability (WVP), and water solubility (WS). Surface structure of Z2 was relatively denser and finer than that of other edible films. GAB $W_m$ and C values decreased, while K values increased with increasing temperature. Correlation coefficients of WS:EMC and WVP:EMC at Aw 0.75 were higher than those of WS: $W_m$ and WVP: $W_m$, respectively. EMC values at Aw 0.75 appeared useful for evaluating or predicting moisture barrier properties of edible films.

The Effects of Water-Proof Polyurethane Coating based on Castor oil and TDI on the Starch-Glycerol Film Under Humidity (Castor Oil과 TDI로 합성한 폴리우레탄 방수코팅이 전분-글리세롤 필름의 습도반응특성에 미치는 영향)

  • 양영준;신형철;김대현;나성기;박종신
    • Proceedings of the Korean Fiber Society Conference
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    • 2002.04a
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    • pp.289-292
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    • 2002
  • 전분을 이용한 환경친화성 고분자 플라스틱 재료에는 전분충진형, blend형 등이 있으나, 대체로 전분은 보조재료로 사용된다. 이에 반해 extruder를 이용한 전분발포체나 TPS (Thermoplastic starch) 등은 전분을 주재료로 사용하여 플라스틱 재료를 만드는 것이지만, TPS 필름의 Tg가 실온보다 높아 glassy 상태의 brittle한 성질로 인해 물성이 낮으며, 수분 친화적인 성질로 인해 플라스틱 재료로서의 사용이 제한되는 단점이 있다[1,2]. (중략)

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Effect of Nanocellulose and Aminated Starch on Tensile and Thermal Properties of Plasticized Starch Film (가소화 전분필름의 강도 및 열적 성질에 미치는 나노셀룰로오스 및 아민화전분의 첨가영향)

  • Kim, Bo-Yeon;Han, Song-Yi;Lee, Sung-Yong;Kim, Young-Kyoon;Kim, Nam-Hun;Lee, Seung-Hwan
    • Journal of the Korean Wood Science and Technology
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    • v.42 no.4
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    • pp.376-384
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    • 2014
  • This study investigated the effect of nanocellulose, such as microfibrillated cellulose (MFC) and cellulose nanocrystal (CNC), and aminated starch on tensile property and thermal stability of plasticized starch film. Glycerol (23 wt%) was used as a plasticizer and nanocelluloses of 1-30 parts per hundred parts of resin (phr) in the basis of plasticized starch were added. Tensile strength and elastic modulus increased with increasing nanocellulose addition amount, whereas elongation at break decreased. Tensile properties of MFC-reinforced starch film were higher than those of CNC-reinforced film. Optimum addition amount of aminated starch, which is commonly used for paper sizing, to improve tensile property of film, was found to be 5%. And 1% addition of aminated starch showed the best effect in the improvement of tensile property of the film. Thermal stability was improved with the addition of MFC to plasticized starch film with and without aminated starch.

Synthesis of biodegradable films obtained from rice husk and sugarcane bagasse to be used as food packaging material

  • Gupta, Himanshu;Kumar, Harish;Kumar, Mohit;Gehlaut, Avneesh Kumar;Gaur, Ankur;Sachan, Sadhana;Park, Jin-Won
    • Environmental Engineering Research
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    • v.25 no.4
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    • pp.506-514
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    • 2020
  • The current study stresses on the reuse of waste lignocellulose biomass (rice husk and sugarcane bagasse) for the synthesis of carboxymethyl cellulose (CMC) and further conversion of this CMC into a biodegradable film. Addition of commercial starch was done to form biodegradable film due to its capacity to form a continuous matrix. Plasticizers such as Glycerol and citric acid were used to provide flexibility and strength to the film. Biopolymer film obtained from sugarcane bagasse CMC showed maximum tensile strength and elongation in comparison to the film synthesized from commercial CMC and CMC obtained from rice husk. It has been observed that an increase in sodium glycolate/NaCl content in CMC imposed an adverse effect on tensile strength. Opacity, moisture content, and solubility of the film increased with a rise in the degree of substitution of CMC. Therefore, CMC obtained from sugarcane bagasse was better candidate in preparing biopolymer/biocomposite film.