• Journal of Welding and Joining
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• 제11권4호
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• pp.91-102
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• 1993

The plasma sprayed $Cr_3C_2$-NiCr coatings are widely used as wear-resistant and corrosion-resistant materials. The mechanical and wear properties of the plasma sprayed $Cr_3C_2$-NiCr coating on steel plate were examined in this study. The pore in the coatings could be classified into two types, the one is the intrinsic pore originated from the spraying powder, the other is the extrinsic pore formed during spraying. During the tensile adhesion test, the fracture occured at the interface of top coating and bond coating. It is though that the compressive residual stress increases with the increase of the top coating thickness. From the wear test, it was found that the wear rate increased with the increase of the sliding velocity regardless of the temperature. It is thought that the fracture toughness reduces with the increase of the sliding velocity at $30^{\circ}C$ and that the adhesion amount increases with the increase of the sliding velocity at $400^{\circ}C$ It is concluded that the wear mechanism at $30^{\circ}C$ is the fracture and pull-out of the carbide particles due to the fatigue on sliding surface, while the wear mechanism at $400^{\circ}C$ is the adhesion of the smeared layer formed during wear process.

• 생물환경조절학회지
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• 제10권1호
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• pp.10-14
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• 2001

포그냉방시스템의 냉방효과는 온실 내부의 상대습도, 공기유동과 밀접한 관계가 있다. 냉방설계용 VETH선도에서 냉발효율은 환기회수의 증가와 그에 상응하는 분무수량의 증가로 인하여 개선될 수 있다. 시간제어방식을 이용한 무차광 실험온실에서 분당 환기회수가 평균 0.77회, 분무수량이 2,009g 일 때 온실 내부의 기온이 31$^{\circ}C$로 외부기온과 거의 같게 나타났으며, 이 때의 증발효율은 82%이다. 분당 환기회수가 평균 0.26회, 분무수량이 1.256g인 경우 무냉방 온실의 기온과 비슷한 37.1$^{\circ}C$였다. 차광율 70%인 실험온실의 분당 환기환수가 평균 2.59회, 분무수량이 2,009g 일 때, 내부의 상대습도는 증가하나 기온은 하강하지 못했다. 그러나 분당 환기회수가 평균 2.33회, 분무수량이 2,009g인 경우 내부의 기온이 31.4$^{\circ}C$로 이 때 온실의 유입구 풍속은 최고 1.9m.s$^{-1}$였다. 시간제어의 경우 일정간격으로 일정한 수량을 분무하기 때문에 분무입자가 모두 증발하지 못하고 온실 내부에 누적되어 온실 내부의 상대습도를 증가시켜 냉방효율을 감소 시키는 원인이 되고 차광망이 온실내부의 공기흐름을 차단하여 증발효율을 감소시키는 것으로 나타났다. 포그냉방시스템의 냉방효율을 높이기 위해서는 온실 내부의 상대습도에 의한 제어방식과 내부 공기의 순환에 대한 연구가 필요하다.

• 한국윤활학회:학술대회논문집
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• 한국윤활학회 1997년도 제26회 추계학술대회
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• pp.93-99
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• 1997

High Temperature wear behavior of plasma sprayed ZrO$_2$ and MoS$_2$, $Fe_2O_3$ coatings were investigated for high temperature wear resistance applications. The MoS$_2$, $Fe_2O_3$ added powders containing 2.5, 5.0, 7.5, 10.0 mol% of $MoS_2$, $Fe_2O_3$ for plasma spray were made by spray drying method. Wear test were performed at temperature ranges from room temperature to 600$\circ$C. The microstructural change of coatings and the worn. surface were examined by SEM and XRD. In ZrO$_2$ coating, the coefficient of friction and wear amount of room temperature to 400$\circ$C was increased with temperature and decreased with temperature over 400$\circ$C. The coefficient of friction and wear amount of MoS$_2$ added coatings were increased with temperature, but those of $Fe_2O_3$ added coatings had lower coefficient of friction and higher wear resistance than ZrO$_2$ coating.

• 한국세라믹학회지
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• 제31권10호
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• pp.1176-1180
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• 1994

The sliding wear behavior of the plasma-sprayed zirconia containing 3 mol% yttria was investigated after the annealing at room temperature to 80$0^{\circ}C$ in various concentrations of humid atmosphere as laboratory, humid, dry argon atmosphere. Both of the friction coefficient and the wear loss increased with increasing temperature up to 80$0^{\circ}C$. Surface morphology of the worn samples changed with annealing temperature. The change of monoclinic/tetragonal (m/t) x-ray peak intensity ratio effected the wear behavior. The m/t ratio had maximum value at 20$0^{\circ}C$ and decreased with increased temperature in laboratory and humid atmosphere. In argon atmosphere the m/t ratio had no maximum value and decreased with increasing temperature. At all the annealing temperature humid atmosphere had more the m/t ratio value than any other atmosphere. The change of toughness was showed the inversed result of m/t ratio change. The results indicated that the resudial stress which was induced by the different amount of phase transformation takes a detrimental role in wear behavior.

• 한국윤활학회:학술대회논문집
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• 한국윤활학회 1998년도 제28회 추계학술대회
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• pp.265-271
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• 1998

High temperature wear behavior of plasma sprayed zirconia based coating sealing with zirconia sol were investigated for high temperature wear resistance application. The zirconia powders containing 2.5, 5.0, 7.5, 10.0 mol% of MoS$_2$, $Fe_2O_3$ for plasma spray were made by spray drying method. As-sprayed coating was sealed by zirconia-sol to fill up the pore and crack in coating. wear test were performed at temperature ranges from room temperature to 600$\circ$C. The microstructural changes of before and after sealing process were examined by SEM, XRD and EPMA. After sealing process, the porosity was decreased and micro-hardness was increased. The wear properties of coating after sealing process were improved by sealing of pores and cracks. The behavior of wear amount and coefficient of friction were same tendency to before sealing process.

• Journal of Plant Biology
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• 제7권1호
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• pp.11-14
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• 1964

Change of the amount of carbohydrates in relations with nitrogen metabolism was studied under the different manners of supply and with different sources of nitrogen. In barley plant supplied with nitrogen through root, the depression periods of glucose and sucrose content occurred at 2 days after, but the amounts of both sugars were different with the different sources of nitrogen; there were in sequence diminished by treatment of NO3, NH4 and urea. In sunflower leaves sprayed with urea both sugar contents were inversely related to the urea concentration sprayed, and depressing periods of the sugars appeared immediately in the N-deficient plant but late in the N-abundant one.

• 한국재료학회지
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• 제14권2호
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• pp.110-114
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• 2004

High velocity oxy-fuel sprayed NiCoCrAlY coatings were oxidized between 1000 and $1200^{\circ}C$ in air, and the oxide scales were examined by XRD, SEM/EDS, and EPMA. The unoxidized coatings consisted mainly of ${\gamma}$'$-Ni_3$Al, with some ${\gamma}$-Ni. The major oxide formed on the coatings was $\alpha$ $-Al_2$$O_3$. Additionally, (CoCr$_2$$O_4$, $CoAl_2$$O_4$) spinels and $Al_{5}$ $Y_3$$O_{12}$ coexisted. NiO was not found, despite of high amount of Ni in the coating. Below the oxide layer, internally formed $Al_2$$O_3$ existed.

• 대한금속재료학회지
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• 제47권5호
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• pp.290-296
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• 2009

We report on the effects of mixing of powders with various particle sizes on fracture toughness and wear resistance of thermally sprayed WC-10Co-4Cr coating layers fabricated by HVOF (high-velocity oxygen fuel) process. The size and the mixing ratio of powders were changed in order to get high fracture toughness and wear resistance. The mixing of small amount of coarse powders with fine powders resulted in the highest fracture toughness and wear resistance due to the lowest porosity in coating layers.

• 한국산업보건학회지
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• 제5권2호
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• pp.137-146
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• 1995

Twenty(20) large commercial buildings located in Seoul with friable sprayed-on surface insulation material on ceilings were investigated for asbestos content in bulk material by polarized light microscopy and for airborne fiber concentrations in buildings by phase contrast microscopy. In addition, such building-related variables as building age, numbers of traffic, airflow, surface conditions of the ceiling, temperature, and humidity were studied for any correlation with airborne fiber concentrations. The results were as follows: 1. Chrysotile asbestos was found in two bulk samples with 3-5% content and with <1%in one sample out of total 20 bulk samples collected. Glass fiber and mineral wool were the two major constituents of the bulk samples. 2. The ceiling surfaces were very friable in 16 buildings and were relatively hard in 4 buildings. The friability of the surface material was dependent upon the type and the amount of binder that had been mixed with the sprayed-on surface material. 3. Airborne fiber concentrations were log-normally distributed and the geometric mean(geometric standard deviation) fiber concentrations in the underground parking lots, inside buildings, and outdoor ambient air were 0.0063(1.97)f/cc, 0.0068(2.29)f/cc, and 0.0033(2.36)f/cc, respectively. 4. No significant relationship of airborne fiber concentrations and all building-related variables studied except humidity was found. The results of this study suggest that the sprayed-on surface insulation material found in some commercial buildings may possibly be contaminated with asbestos. Since most of the ceiling surfaces surveyed were very friable and poorly maintained and the airborne fiber concentrations were relatively high, there is a possibility of asbestos fiber contamination in these buildings, particularly at those buildings with asbestos-contaminated surface material. Since poorly maintained surface conditions were thought to be a source of high airborne fiber concentrations, there is a urgent need of a systematic operation and maintenance program. Further study of non-occupational asbestos exposure in general population utilizing advanced analytical technique such as transmission electron microscopy is highly recommended.

• 농약과학회지
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• 제7권4호
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• pp.258-263
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• 2003

국내 과수용 농약에 대한 농가사용실태를 파악하여 농산물의 안전성과 농약관리를 위한 자료로 활용하고자 국내 주요 과수류인 사과, 감률, 포도, 복숭아, 배, 감 등 6종의 과수를 대상으로 재배면적별 35지역 150농가를 선정하여 국내 과수재배 환경중 농약의 사용량을 조사 분석하였다. 과수용 농약의 년간 살포 회수는 배가 15.2회로 가장 많았고, 감은 7회로 가장 적었다. 단위면적당 농약사용량은 감률 39.5, 사과 22.1, 배 21.5, 복숭아 11.9, 감 10.8, 포도 6.7 a.i. kg/ha이었으며, 사과, 감률, 포도, 감의 사용량은 1999년도 사용량 다 약간 감소하였다. 주요 사용농약은 살균제는 mancozeb, propineb, dithianon 등, 살충제는 fenitrothion, chlorpyrifos, methidathion 등이었다. 조사대상 과수 6종에 사용된 농약의 총 주성분량을 계산한 결과는 2,834.7 M/T으로 2002년도 원예용 농약 출하량 대비 18.3%를 차지하였다. 또한, 국내 과수별 단위면적당 농 약사용량을 2001년도 미국의 농약사용량과 비교한 결과 사과는 22.la.i. kg/ha로 한국이 많았으나 감률 등 나머지 작물에서는 미국의 사용량이 많은 편이었다. 본 시험에서 얻어진 결과는 농약의 위해성 감소, 농업환경 보존 및 농약관리를 위해 유용한 자료로 활용될 수 있을 것으로 기대된다.