• Resources Recycling
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• v.9 no.4
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• pp.16-27
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• 2000

In order to produce raw material powder of advanced magnetic material by spray roasting process, newly modified spray roasting system was developed in this work. In this spray roasting system, raw material solution was effectively atomized and sprayed into the reaction furnace. Also, uniform temperature distribution inside reaction furnace made thermal decomposition process fully completed, and produced powder was effectively collected in cyclone and bag filter. This system equipped with apparatus which can purify hazard produced gas. In this study complex acid solution was prepared by dissolution of mill scale and ferro-Mn into the acid solution, and the pH of this complex acid solution was controlled about to 4. It was conformed that mill scale and ferro-Mn containing a lot of impurities such as $SiO_2$, P and Al could be used as raw material by reducing the impurities content of complex acid solution below 20 ppm. Complex oxide powder of Fe-Mn system was produced by spraying purified complex acid solution into the spray roaster through nozzle, and the variations of produced powder characters were studied by changing he reaction conditions such as reaction temperature, the injection velocity of solution and air, nozzle tip size and concentration of solution. The morphology of produced powder had spherical shape under the most experimental conditions, and concentration of solution. The morphology of produced powder has spherical shape under the most experimental conditions, and the composition and the particle size distribution were almost uniform, which tells the excellence of this spray roasting system. The grain size of most produced powder was below 100 nm. From the above results, it will be possible to produce ultra fine oxide powder from the chloride of Fe, Mn, Ni, Cu and rare earth by using this spray roasting system, and also to produce ultra fine pure metal powder by changing reaction atmosphere.

• Korean Chemical Engineering Research
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• v.53 no.5
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• pp.632-637
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• 2015

Mesoporous $TiO_2$ granules were prepared by spray pyrolysis using nano-sized titania particles which were synthesized by a hydrothermal method, and they were evaluated as the photoanode of dye-sensitized solar cells. To enhance the cell efficiency, nanoparticles within granules were chemically interconnected by adding titanium ethoxide (TEOT) to colloidal spray solution. The resulting titania particles had anatase phase without forming rutile. $TiO_2$ granules obtained showed about 400 nm in size, the specific surface area of $74-77m^2/g$, and average pore size of 13-17 nm. The chemical modification of $TiO_2$ granules by adding TEOT initially to the colloidal spray solution was proved to be an effective way in terms of increasing both the light scattering within photoanode and the lifetimes of photo-excited electrons. Consequently, the light-harvesting efficiency of TEOT-modified granules (${\eta}=6.72%$) was enhanced about 14% higher than primitive nanoparticles.

• Journal of ILASS-Korea
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• v.6 no.1
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• pp.25-34
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• 2001

Several efforts to meet the exhaust gas regulation have been undertaken by many researchers in recent years. Main researches are on development of design techniques of intake port and combustion chamber, atomisation of fuel and precise control of air-fuel ratio, post-treatment of exhaust gas and so on. Engine technology is changed from PFI to GDI to correspond with exhaust gas regulation. GDI technique makes it possible to preserve lean air-fuel ratio and control accurate air-fuel ratio. Nevertheless, It is not cleared that information of spray characteristics and atomization process are very dependent on fluctuation of pressure and change of temperature in intake stroke. In this study, a constant volume combustion chamber is manufactured to investigate various fluctuations of in-cylinder pressure for injection duration. It is taken photographs of injection process of conventional GDI injector using PMAS. Then, it was verified experimently that ambient conditions as temperature and pressure of combustion chamber have effects on process of spray growth and atomization of fuel.

• Journal of ILASS-Korea
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• v.11 no.4
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• pp.212-219
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• 2006

The initial film flow development of the high-pressure swirl spray was investigated at different injector operating conditions to analyze film flow development and to provide the input data for the modeling works. This result can be also useful to verify the previously simulated results. The initial flow conditions such as liquid film thickness, flow angle and flow divergence are obtained by visualizing the inside and near the nozzle flow with a microscopic imaging system. The visualized images are quantified using an image processing tool. From the information of liquid film thickness and flow angle, the initial axial and tangential velocity and the swirl number of the swirl spray are successfully determined at various operating conditions. The experimental results showed that the initial liquid film thickness, flow angle and flow divergence are remained constant when the injection pressure is increased. However, initial film conditions are severely changed when the fuel temperature is increased. The swirl number remained constant when the injection pressure is increased while it showed increased value at high fuel temperature condition.

• Journal of Mechanical Science and Technology
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• v.19 no.11
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• pp.2040-2052
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• 2005

The present paper centers on the establishment of a quantified relationship between the macroscopic visual parameters of a Diesel spray and its most influential factors. The factors considered are the ambient gas density, as an external condition relative to the injection system, and nozzle hole diameter and injection pressure as internal ones. The main purpose of this work is to validate and extend the different correlations available in the literature to the present state of the Diesel engine, i.e. high injection pressure, small nozzle holes, severe cavitating conditions, etc. Five mono-orifice, axi-symmetrical nozzles with different diameters have been studied in two different test rigs from which one can reproduce solely the real engine in-cylinder air density, and the other, both the density and the pressure. A parametric study was carried out and it enabled the spray tip penetration to be expressed as a function of nozzle hole diameter, injection pressure and environment gas density. The temporal synchronization of the penetration and injection rate data revealed a possible explanation for the discontinuity observed as well by other authors in the spray's penetration law. The experimental results obtained from both test rigs have shown good agreement with the theoretical analysis. There have been observed small but consistent differences between the two test rigs regarding the spray penetration and cone angle, and thus an analysis of the possible causes for these differences has also been included.

• Journal of Mechanical Science and Technology
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• v.18 no.12
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• pp.2310-2318
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• 2004

The effects of change in injection pressure on spray structure in high temperature and pressure field have been investigated. The analysis of liquid and vapor phases of injected fuel is important for emissions control of diesel engines. Therefore, this work examines the evaporating spray structure using a constant volume vessel. The injection pressure is selected as the experimental parameter, is changed from 400 bar to 800 bar by using a common rail injection system. Also, we conducted simulation study by modified KIVA-II code. The results of simulation study are compared with experimental results. The images of liquid and vapor phase for free spray were simultaneously taken by exciplex fluorescence method. As experimental results, the vapor concentration of injected fuel is leaner due to the increase of atomization in the case of the high injection pressure than in that of the low injection pressure. The calculated results obtained by modified KIVA-II code show good agreements with experimental results.

• Journal of ILASS-Korea
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• v.7 no.1
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• pp.14-20
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• 2002

It is well known that the flow and spray characteristics is critical factor on the performance and emission of a direct injection diesel engine. So this study aims to investigate the interaction of flow and spray characteristics. At first, in cylinder flow distributions in swirl adaptor for 4-valve cylinder head of DI Diesel engine were investigated under steady conditions for different SCV angles mounted on the cylinder head with steady rig test and 2-D LDV. And the in-cylinder flow was quantified in terms of mean flow coefficient and swirl ratio/tumble ratio. It was found that the swirl ratio is controlled between 2.3 and 3.8. Then spray characteristics of the intermittent injection were investigated. PDA system was utilized for measurement of a droplet size and velocity. The analyses of the PDA results are carried out with Time Dividing Method. It was found that there is a correlation between the swirl flow and SMD. The droplet size and the velocity were nearly constant value with each SCV angle. And the swirl ratio is higher, SMD smaller. The swirl ratio was helpful factor to the atomization of droplet.

• Journal of ILASS-Korea
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• v.20 no.1
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• pp.43-52
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• 2015

Experimental study was conducted to investigate the effects of ultra-high injection pressure and nozzle hole diameter on diesel flow and spray characteristics. Electronically controlled ultra-high pressure fuel injection system was made to supply the fuel of ultra-high pressure consistently. Three injection pressures, 80, 160, and 250MPa were applied. Four type of injectors with identical eight nozzle holes were used. The four injectors have nozzle hole diameters of 115, 105, 95, and $85{\mu}m$ respectively. Injection quantity and rate were measured to investigate flow characteristics according to injection pressures and nozzle hole diameters. Mie-scattering and shadowgraph were performed to visualize liquid and vapor phases of diesel spray in a constant volume combustion chamber (CVCC). Ambient conditions of high pressure and high temperature in a diesel engine were simulated by using CVCC.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.25 no.5
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• pp.688-696
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• 2001

Vaporizing characteristics of two GDI injectors with different spray angles were investigated using exciplex fluorescence method. Injector I has narrower spray angle, while injector II has wider one. The exciplex system of fluorobenzene and DEMA in a non-fluorescing base fuel of hexane was employed. In quantifying concentration of fuel vapor, quenching of concentration and temperature was corrected. Droplet size and velocity were also measured by PDPA under non-vaporizing condition. From obtaining the images of liquid and vapor phases, vaporizing GDI sprays could be divided as two regions: cone and mixing regions. For injector I, vortex region was not developed. High concentration of fuel vapor due to vaporization of many fine droplets was distributed near the spray axis. For injector II, droplets with the diameter of about 10 $\mu$m were distributed in the vortex region. The vortex region had high concentration of fuel vapor due to vaporization of these droplets. Particularly, higher and lower concentrations of fuel vapor were balanced at 2ms after the start of injection for injector II.

• International Journal of Automotive Technology
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• v.5 no.1
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• pp.9-16
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• 2004

An experimental study was carried out to characterize the spray atomization process of micro-machined port fuel injectors with a piezoelectric atomization device, which can generate pressure pulsations through vibration of a piezoelectric transducer. In this study, several types of micro-machined arrays such as 30∼200-microns of hole arrays were tested. Both a dual-stream and a central-port injectors with micro-machined arrays were tested and compared with normal port fuel injectors. The spray visualization was conducted to characterize overall spray structure and phase Doppler particle analyzer (PDPA) system was used to quantify the droplet size and velocity. In addition, the pressure history was recorded by using digitized signal from pressure transducer. The results showed that modulation is effective to the spray atomization for tested injectors and atomization performance depends on injector design factors, orifice sizes, and frequency and power of the modulator. A number of resonance frequencies of the modulator was modified by injector parameters and temperature. In addition, our results suggested that design of sufficient space among holes is critical to avoid droplet coalescence in the multi-hole micro-machined injectors.