• Journal of the Korea Concrete Institute
• /
• v.16 no.1 s.79
• /
• pp.79-87
• /
• 2004

The qualify of lightweight aggregate made from waste PET bottle(WPLA) and the workability, the unit weight and strength property of concrete with WPLA were investigated for the purpose of recycling the waste PET bottles as lightweight concrete fine aggregate. This study indicated a good result that WPLA should be replaced with less than $50\%$ of natural fine aggregate. When WPLA was replaced with $50\%$ of natural fine aggregate, the specific gravity and water absorption of mixed fine aggregate were greatly reduced about 23 and $75\%$ respectively in comparison with those of river sand. The quality of WPLA affected on the properties of lightweight aggregate concrete. The workability of fresh concrete with WPLA(WPLAC) was improved with increasing the replacement ratio of WPLA and water cement ratio. Slump increasing ratio of the former showed about $45 {\~} 120\%$ because that a specific gravity of fine aggregate was decreased from 2.6 to 1.7. The unit weight of concrete with $75\%$ WPLA was decreased about $17\%$ in comparison with that of control concrete. Furthermore, the compressive strength of concrete with 25 and $50 \%$ WPLA at the age of 28 days increased higher than 30 MPa regardless with water cement ratio (W/C=45, 49 and $53\%$) of this study. Specific strength of concrete with $25\%$ WPLA, $15.11{\times}10^3 MPa{\cdot}m^3/kg$, was higher than that of contro concrete in water cement ratio of $49\%$. The compressive strength-splitting tensile strength ratio and compressive strength-modulus of elasticity ratio of WPLAC were similar to that of nomal lightweight aggregate concrete. This results showed a good estimation that WPLA will be able to recycled as a fine aggregate for lightweight concrete.

• Transactions of the Korean hydrogen and new energy society
• /
• v.16 no.1
• /
• pp.40-48
• /
• 2005

Until recently, only perfluorinated ionomer membrane such as Nation and Aciflex practically could be successfully used in water splitting. However, these membrane are limited by high cost and loss of membrane performance such as proton conductivity at elevated temperature above 80$^{\circ}C$. The sulfonated aromatic polymers such as PEEK and PSf, polyimides, and polybenzimidazoles are expected to have lower production cost as well as satisfactory chemical and electrochemical properties. HPAs and sulfonated polymers could have a significant influence on water electrolysis performance at elevated temperatures above 80$^{\circ}C$, but these phenomena have received relatively little attention until now. Therefore, it would be desirable to investigate the interrelation between the HPA and sulfonated polymer, such as SPEEK. The SPEEK membrane were prepared by the sulfonation of PEEK, and HPA was blended with SPEEK to increase the mechanical strength and electrochemical characteristics. As a results, electrochemical characteristics such as proton conductivity and ion exchange capacity were improved with the addion of 0.5 g HPA. And the properties of polymer electrolyte, SPEEK/HPA were better than Nation membrane at elevated temperature above 80$^{\circ}C$.

• Advances in concrete construction
• /
• v.6 no.4
• /
• pp.345-362
• /
• 2018

In this paper, mechanical and short-term durability properties of fly ash and slag based geopolymer concretes (FAGPC-SGPC) were investigated. The alkaline solution was prepared with a mixture of sodium silicate solution ($Na_2SiO_3$) and sodium hydroxide solution (NaOH) for geopolymer concretes. Ordinary Portland Cement (OPC) concrete was also produced for comparison. Main objective of the study was to examine the usability of geopolymer concretes instead of the ordinary Portland cement concrete for structural use. In addition to this, this study was aimed to make a contribution to standardization process of the geopolymer concretes in the construction industry. For this purpose; SGPC, FAGPC and OPC specimens were exposed to sulfuric acid ($H_2SO_4$), magnesium sulfate ($MgSO_4$) and sea water (NaCl) solutions with concentrations of 5%, 5% and 3.5%, respectively. Visual inspection and weight change of the specimens were evaluated in terms of durability aspects. For the mechanical aspects; compression, splitting tensile and flexural strength tests were conducted before and after the chemical attacks to investigate the residual mechanical strengths of geopolymer concretes under chemical attacks. Results indicated that SGPC (100% slag) is stronger and durable than the FAGPC due to more stable and strong cross-linked alumina-silicate polymer structure. In addition, FAGPC specimens (100% fly ash) showed better durability resistance than the OPC specimens. However, FAGPC specimens (100% fly ash) demonstrated lower mechanical performance as compared to OPC specimens due to low reactivity of fly ash particles, low amount of calcium and more porous structure. Among the chemical environments, sulfuric acid ($H_2SO_4$) was most dangerous environment for all concrete types.

• Journal of Conservation Science
• /
• v.26 no.3
• /
• pp.325-334
• /
• 2010

In order to clarify the effect of consolidant, the artificial porous material with low intensity was manufactured using granite powder and Portland cement. We have prepared four kinds of alkoxysilane system consolidants, a acrylic resin and a epoxy resin and investigated about characteristics before and after consolidation. As a result of the research, Silres BS OH 100 was effective for density and surface hardness. SS-101 with hydrophobicity and Site SX-RO with hydrophilicity had the good durability over salts weathering. On the other hand, Syton HT-50 and Paraloid B72 were easily destructed by salt weathering because they were concentrated on surface area by the low penetration depth. Araldite 2020 was the most effective consolidant for improvement of physical properties.

• Journal of the Korean Chemical Society
• /
• v.40 no.1
• /
• pp.65-71
• /
• 1996

The chemical behaviour of the Eu(Ⅲ) complexes with organic ligands(tris[3-(trifluoromethylhydroxymethylene-camphorato)]) and tris[3-heptafluoropropylhydroxymethylene-camphorato)] has been investigated by the UV/vis-spectrophotometric, magnetic, and electrochemcial methods. The two or three energy absorption bands are observed by the spectra of these complexes. The magnitude of crystal field splitting energy, the spin pair energy and strength were obtained from the spectra of the complexes. These complexes are found to be delocalization, low-spin state, and strong bonding strenth of electron configuration. The magnetic dipolemoment are found to be diamagnetic. The redox reaction processes of complexes were investigated by cyclic voltammetry in aprotic solvent. The redox reaction processes of complexes are turned out to be single or double reaction with respect to one electron diffusion current.

• Journal of the Korea Concrete Institute
• /
• v.18 no.5 s.95
• /
• pp.649-656
• /
• 2006

In this study, powered superplasticizer(PSP) agents to improve the slump loss rate of recycled aggregate concrete were developed. To evaluate the variation of fluidity against elapsed time and the mechanical properties, twenty four specimens whose main variables had the mixing condition of aggregates, such as natural and recycled gravels, and natural and recycled fine aggregates, were tested. The concrete slump with a liquid superplasticizer greatly decreased against the elapsed time and dropped by less than 50% of initial slump after two hours. However the concrete slump with the PSP agents hardly varied until after half an hour and maintained more than 85% of initial slump even after an hour. Also the PSP agents made the compressive, splitting tensile, and flexural strength of concrete increased and the shrinkage strain decreased. Considering the properties improvement of concrete, it can be recommended that optimum mixing amount of the PSP agents should be 5% of the amount of cement.

• Journal of the Korea Concrete Institute
• /
• v.22 no.5
• /
• pp.651-658
• /
• 2010

Sixteen concrete mixes reinforced with hybrid steel-polybinyl alcohol (PVA) fibers and a control concrete mix with no fiber were tested in order to examine the effect of the micro and macro fibers on the slump and different mechanical properties of concrete. Main variables investigated were length and volume fraction of steel and PVA fibers. The measured mechanical properties of hybrid fiber reinforced concrete were analyzed using the fiber reinforcing index and compared with those recorded from monolithic steel or PVA fiber reinforced concrete. The initial slump of hybrid fiber reinforced concrete decreased with the increase of the aspect ratio and the volume fraction of fibers. In addition, splitting tensile strength, modui of rupture and elasticity, and flexural toughness index of concrete increased with the increase of the fiber reinforcement index. Modulus of rupture and flexural toughness index of hybrid fiber reinforced concrete were higher than those of monolithic fiber reinforced concrete, though the total volume fraction of hybrid fibers was lower than that of monolithic fiber. For enhancing the flexural toughness index of hybrid fiber reinforced concrete, using the steel fiber of 60 mm length was more effective than using the steel fibers combined with 60 mm and 30 mm lengths.

• Geomechanics and Engineering
• /
• v.14 no.1
• /
• pp.9-17
• /
• 2018

Brazilian splitting tests, uniaxial compression tests and triaxial compression tests are carried out on the coal samples cored from Shanxi group $II_1$ coal seam of Jiaozuo coal mine, Henan province, China, to obtain their property parameters. Considering the bedding has notable effect on the property parameter of coal, the samples with different bedding angles are prepared. The effects of bedding on the anisotropic characteristics of the coal seam are investigated. A geological geomechanical model is built based on the geology characteristics of the Jiaozuo coal mine target reservoir to study the effects of bedding on the fracture propagations during hydraulic fracturing. The effects of injection pressure, well completion method, in-situ stress difference coefficient, and fracturing fluid displacement on the fracture propagations are investigated. Results show bedding has notable effects on the property parameters of coal, which is the key factor affecting the anisotropy of coal. The hydraulic cracks trends to bifurcate and swerve at the bedding due to its low strength. Induced fractures are produced easily at the locations around the bedding. The bedding is beneficial to form a complicated fracture network. Experimental and numerical simulations can help to understand the effects of bedding on hydraulic fracturing in coalbed methane reservoirs.

• Health Policy and Management
• /
• v.26 no.4
• /
• pp.289-304
• /
• 2016

Background: Rehabilitations in subacute phase are different from acute treatments regarding the characteristics and required resource consumption of the treatments. Lack of accuracy and validity of the Korean Diagnosis Related Group and Korean Out-Patient Group for the acute patients as the case-mix and payment tool for rehabilitation inpatients have been problematic issues. The objective of the study was to develop the Korean Rehabilitation Patient Group (KRPG) reflecting the characteristics of rehabilitation inpatients. Methods: As a retrospective medical record survey regarding rehabilitation inpatients, 4,207 episodes were collected through 42 hospitals. Considering the opinions of clinical experts and the decision-tree analysis, the variables for the KRPG system demonstrating the characteristics of rehabilitation inpatients were derived, and the splitting standards of the relevant variables were also set. Using the derived variables, we have drawn the rehabilitation inpatient classification model reflecting the clinical situation of Korea. The performance evaluation was conducted on the KRPG system. Results: The KRPG was targeted at the inpatients with brain or spinal cord injury. The etiologic disease, functional status (cognitive function, activity of daily living, muscle strength, spasticity, level and grade of spinal cord injury), and the patient's age were the variables in the rehabilitation patients. The algorithm of KRPG system after applying the derived variables and total 204 rehabilitation patient groups were developed. The KRPG explained 11.8% of variance in charge for rehabilitation inpatients. It also explained 13.8% of variance in length of stay for them. Conclusion: The KRPG version 1.0 reflecting the clinical characteristics of rehabilitation inpatients was classified as 204 groups.

• Journal of the Korean Chemical Society
• /
• v.38 no.8
• /
• pp.590-597
• /
• 1994

The chemical behavior of the trivalent lanthanide$(Pr^{3+}, Eu^{3+}, Gd^{3+} 그리고 Yb^{3+})$complexes with organo-ligand (2,2,6,6-tetramethyl-3,5-heptanedione) has been investigated by the use of UV/Vis-spectrophotometric, magnetics, and electrochemical method. The two or three energy absorption bands are observed by the spectra of these complexes. The magnetitude of crystal field splitting energy, the spin pairing energy and bond stength was obtained from the spectra of the complexes. These are found to be localization, low-spin (or high-spin state, and strong bonding strength. The magnetic dipole moment are found to be diamagnetic complexes (or paramagnetic). The electrochemical behavior of complexes was observed by the use of cyclic voltammetry in aprotic media. These reduction peaks were irreversible two and three step reduction processes by electron transfer.