• 한국초전도학회:학술대회논문집
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• v.12
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• pp.36-36
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• 2002

• Journal of Magnetics
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• v.10 no.2
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• pp.63-65
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• 2005

The $^1H$ NMR spin-lattice relaxation in a series of the organic-inorganic hybrid systems $(C_nH_{2n+1}NH_3)_2SnCl_6$ (n = 8, 10, 12, 14) undergoing two successive phase transitions was studied. A discontinuity characteristic of a first order phase transition was observed at the high-temperature conformational transition. Besides, the spin-lattice relaxation rate below the conformational transition temperature was well fitted by four types of molecular motions, from which the chain-length dependence of the activation energies of the molecular groups was obtained.

• Proceeding of EDISON Challenge
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• 2014.03a
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• pp.183-195
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• 2014

Kinetically constrained models (KCM) have attracted interest as models that assign dynamic origins to the interesting dynamic properties of supercooled liquid. Signs of dynamic heterogeneity in the crossover model that linearly interpolates between the FA-like symmetric constraint and the East model constraint by asymmetric parameter b were investigated using Monte Carlo technique. When the asymmetry parameter was decreased sufficiently, smooth fragile-to-strong dynamic transition was observed in terms of the relaxation time, diffusion constant, Stokes-Einstein violation, and dynamic length scale. Competition between energetically favored symmetric relaxation mechanism and entropically favored asymmetric relaxation mechanism is behind such transition.

• Proceedings of the Korean Magnestics Society Conference
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• 2006.06a
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• pp.32-33
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• 2006

• Bulletin of the Korean Chemical Society
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• v.13 no.3
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• pp.296-306
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• 1992

$^{13}C$ spin-lattice relaxation times were measured for n-alkanes of moderate chain length, ranging from n-octane to n-dodecane, under the condition of proton broad-band decoupling within the temperature range of 248-318 K in order to gain some insight into basic features of segmental motions occurring in long chain ploymeric molecules. The NOE data showed that except for methyl carbon-13 dipole-dipole interactions between $^{13}C$ and directly bonded $^1H$ provide the major relaxation pathway, and we have analyzed the observed $T_1data$ on the basis of the internal rotational diffusion theory by Wallach and the conformational jump theory by London and Avitabile. The results show that the internal rotational diffusion constants about C-C bonds in the alkane backbone are all within the range of $10^9\;-10^10\;sec^{-1}$ in magnitude while the mean lifetimes for rotational isomers are all of the order of $10^{-11}\;-10^{-10}$ sec. Analysis by the L-A theory predicts that activation energies for conformational interconversion between gauche and trans form gradually increase as we move from the chain end toward the central C-C bond and they are within the range of 2-4 kcal/mol for all the compounds investigated.