• Journal of the Korean earth science society
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• v.42 no.6
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• pp.623-631
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• 2021

The increased transport of marine hazardous and noxious substances (HNS) has resulted in frequent HNS spill accidents domestically and internationally. There are about 6,000 species of HNS internationally, and most of them have toxic properties. When an accidental HNS spill occurs, it can destroys the marine ecosystem and can damage life and property due to explosion and fire. Constructing a spectral library of HNS according to wavelength and developing a detection algorithm would help prepare for accidents. In this study, a ground HNS spill experiment was conducted in France. The toluene spectrum was determined through hyperspectral sensor measurements. HNS present in the hyperspectral images were detected by applying the spectral mixture algorithm. Preprocessing principal component analysis (PCA) removed noise and performed dimensional compression. The endmember spectra of toluene and seawater were extracted through the N-FINDR technique. By calculating the abundance fraction of toluene and seawater based on the spectrum, the detection accuracy of HNS in all pixels was presented as a probability. The probability was compared with radiance images at a wavelength of 418.15 nm to select abundance fractions with maximum detection accuracy. The accuracy exceeded 99% at a ratio of approximately 42%. Response to marine spills of HNS are presently impeded by the restricted access to the site because of high risk of exposure to toxic compounds. The present experimental and detection results could help estimate the area of contamination with HNS based on hyperspectral remote sensing.

• Journal of Navigation and Port Research
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• v.36 no.10
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• pp.857-864
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• 2012

Reviewing the statistics of harbor shipment of hazardous and noxious substance and the past spill accidents of HNS enabled us to assess the potential risks of transportation of HNS through the major harbors in Korea. Ulsan, Yeosu, Daesan port are relatively evaluated high risk in fire, health and environment disaster. Through the analysis of domestic preparedness to HNS accidents, the supplement of expertise resource to respond the vulnerability of the explosion, the fire and the physiological hazard, is required. Based on this risk assessment and review of the advanced case of Japan in building up HNS response system, a resource model at a national level was proposed which differentiates the sea areas for the proper allocation of resources to respond effectively to HNS accidents in the future.

• Fire Science and Engineering
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• v.30 no.6
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• pp.23-30
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• 2016

This study analyzed the characteristics of chemical accidents, including the accidents occurring each year according to status, type of accident, accident cause for chemical substance transporting accidents. The major aim of this study was to provide information on the chemical accidents that occurred involving chemical substance transporting accidents from 2013 to July - 2016. The total incidence of chemical transporting accidents was 77 cases; 74 cases occurred by the spill & leakage type. The main cause of the accidents analyzed was traffic accidents (41 cases). Forty-six accidents were related to hazardous chemical substances. Among the 46 hazardous chemical substances involved in transporting chemical accidents, 46% of the accident substances were hydrogen chloride. For the prevention and response to accidents occurring during the transportation of chemicals, it is necessary to complement the precautions for chemical accidents caused by transportation accidents and chemical spills and leaks of chemicals. In addition, when the chemical transport of an accident occurs, it is necessary to apply a chemical transport safety system for chemical transfer.

• Journal of Convergence for Information Technology
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• v.11 no.7
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• pp.84-90
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• 2021

98.8% of accidents occurring in domestic companies are concentrated in small-sized workplaces with fewer than 50 employees. Therefore, this study developed a disaster safety program that can be implemented by small and medium-sized enterprises by comparing and analyzing the safety management system actively used with the laws and regulations related to industrial safety and facilities. The disaster and safety program included the scope of application, organizational structure, risk assessment, emergency response system, education and training, safety equipment provision and program evaluation, and detailed preparation methods and procedures for each item. In addition, items to be aware of when operating a disaster safety program and operational strategies were presented. After that, it was proposed to introduce the research results into the Occupational Safety and Health Act.

• Journal of the Korean Society of Safety
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• v.21 no.1 s.73
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• pp.86-91
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• 2006

Oil spills caused by the accidents have been occurred from house and factory waste, grounded tanker, the rupture of storage tank and oil pipelines, the deterioration of various industrial facilities, etc. Many oil spills result in contamination of shorelines and workplace. Fire and explosion may happen from these spills. There are several technologies used for clean-up application, which include use of oil dispersing agents, absorbents, solidifiers, booms and skimmers by physical, chemical, and biological methods. Methods for oil spill clean-up operation are classified into the absorption type, gel type and self-swelling type. Porous materials with oil absorptive properties are classified into micropore, mesopore, and macropore depending on their pore sizes. Recently, new porous materials with smaller size have been developed, but the selective oil absorption in water-in-oil interface demonstrates the macro pore size. In this study oil absorption effects were evaluated using the organic porous materials with a complex function of gel type and swelling type. Samples were subjected to analysis by FT-IR spectroscopy and were characterized in terms of gel formation and morphologies. Oil sorption capacity, pressure retention force and gel strength were also measured. From these results, the physicochemical reactivity before and after gelation was verified and the industrial applications of clean-up operation were suggested.

• Journal of the Korean Society of Marine Environment & Safety
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• v.28 no.spc
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• pp.1-10
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• 2022

As the volume of marine hazardous and noxious substances (HNSs) transported in domestic and overseas seas increases, the risk of HNS spill accidents is gradually increasing. HNS leaked into the sea causes destruction of marine ecosystems, pollution of the marine environment, and human casualties. Secondary accidents accompanied by fire and explosion are possible. Therefore, various types of HNSs must be rapidly detected, and a control strategy suitable for the characteristics of each substance must be established. In this study, the ground HNS spill experiment process and application result of detection algorithms were presented based on hyperspectral remote sensing. For this, styrene was spilled in an outdoor pool in Brest, France, and simultaneous observation was performed through a hyperspectral sensor. Pure styrene and seawater spectra were extracted by applying principal component analysis (PCA) and the N-Findr method. In addition, pixels in hyperspectral image were classified with styrene and seawater by applying spectral matching techniques such as spectral distance similarity (SDS), spectral correlation similarity (SCS), spectral similarity value (SSV), and spectral angle mapper (SAM). As a result, the SDS and SSV techniques showed good styrene detection results, and the total extent of styrene was estimated to be approximately 1.03 m². The study is expected to play a major role in marine HNS monitoring.

• Journal of the Korean Institute of Gas
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• v.15 no.2
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• pp.82-87
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• 2011

Heat transfer oils are used in applications such as heating systems of chemical plant, refinery heat exchange systems, gas plant process, injection molding systems, and pulp and paper processing. These oils are extremely stable and resistance to thermal and oxidative degradation. In the event of a spill or accidental release of heat transfer oils, it can be ignite easily when there is an ignition source. This paper discusses the flammability and thermal stabilities of new and used oils. The flammability of the oils are assessed by measuring changes in flash point and auto ignition temperature. The thermal stability of oils are evaluated by the thermal screening unit ($TS^u$) and the differential scanning calorimeter (DSC). From the experimental results, it is suggested to give fire hazard characteristics to safe precautions for the proper use and treatment of heat transfer oils.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.18 no.11
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• pp.104-109
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• 2017

The flooding and deterioration of water quality caused by urbanization and climate change are becoming more serious. In order to respond to this, studies on low impact development (LID) technology, which is designed to restore the hydrological system of the urban basin to its natural state, have been actively pursued all over the world, The announcement of the low carbon green growth law, hydrophilic area special law, etc., highlights the importance of technology such as the LID method. However, whereas various developments have been made in relation to the current LID element technology, there has been little research designed to verify its effectiveness. In this study, we analyzed the optimum spatial distribution of pitcher fire pitcher packing in parking lots using the K - LIDM model to verify the effectiveness of the low impact development (LID) method in the early stages. Using the eight package scenario and the three rain intensity scenarios, it was found that the lower 40% pitcher packaging results in an approximately 90% spill reduction effect, as in the case of the whole pitcher's package. The confirmation of these analyses and experimental verification is expected to ensure that the actual pitcher packaging will be used as a basis for arranging LID facilities such as urban planning and housing development in the future.