• Korean Chemical Engineering Research
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• 제59권3호
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• pp.326-332
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• 2021

본 연구에서는 수열 합성법을 이용하여 나노 실리콘이 포함된 구형의 탄소 복합체를 합성하고, 석유계 피치로 코팅하여 제조된 음극 소재의 전기화학 특성을 조사하였다. 수크로스의 몰 농도를 변화시켜 수열합성한 후, 유기 용매로 THF를 사용하여 피치로 코팅된 음극 복합소재를 제조하였다. 제조된 음극 소재는 SEM, EDS, XRD 및 TGA를 사용하여 물리적 특성을 분석하였으며, 1.0 M LiPF₆ (EC : DMC : EMC = 1 : 1 : 1 vol%) 전해액에서 사이클, 율속, 순환전압전류 및 임피던스 테스트를 통해 리튬이차전지의 전기화학 성능을 조사하였다. 1.5 M의 수크로스와 피치를 사용하여 제조된 실리콘/탄소 소재는 구형 형태를 보였으며, 1756 mAh/g의 높은 초기 용량, 50 사이클 후 82 %의 용량 유지율 및 2 C/0.1 C에서 81%의 우수한 속도 특성을 확인할 수 있었다.

• 자원환경지질
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• 제12권2호
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• pp.95-104
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• 1979

The position of any point on the earth's surface can be. represented in the spherical coordinates by surface spherical harmonics. Since geomagnetic field is a function of position on the earth, it can be also expressed by spherical harmonic analysis as spherical harmonics of trigonometric series of $a_m({\theta})$ cos $m{\phi}$ and $b_m({\theta})$ sin $m{\phi}$. Coefficients of surface spherical harmonics, $a_m({\theta})$ and $b_m({\theta})$, can be drawn from the components of the geomagnetic field, declination and inclination, and vice versa. In this paper, components of geomagnetic field, declination and inclination in the Korean peninsula are obtained by spherical harmonic analysis using the Gauss coefficients calculated from the world-wide magnetic charts of 1960. These components correspond to the values of normal geomagnetic field having no disturbances of subsurface mass, structure, and so on. The vertical and total components offer the zero level for the interpretation of geomagnetic data obtained by magnetic measurement in the Korean peninsula. Using this zero level, magnetic anomaly map is obtained from the data of airborne magnetic. prospecting carried out during 1958 to 1960. The conclusions of this study are as follows; (1) The intensity of horizontal component of normal geomagnetic field in Korean peninsula ranges from $2{\times}10^4$ gammas to $2.45{\times}10^4$ gammas. It decreases about 500 with the increment of $1^{\circ}$ in latitude. Along the same. latitude, it increases 250 gammas with the increment of $1^{\circ}$ in longitude. (2) Intensity of vertical component ranges from $3.85{\times}10^4$ gammas to $5.15{\times}10^4$ gammas. It increases. about 1000 gammas with the increment of $1^{\circ}$ in latitude. Along the same latitude, it decreases. 150~240 gammas with the increment of $1^{\circ}$ in longitude. Decreasing rate is considerably larger in higher latitude than in lower latitude. (3) Total intensity ranges from $4.55{\times}10^4$ gammas to $5.15{\times}10^4$ gammas. It increases 600~700 gammas with the increament of $1^{\circ}$ in latitude. Along the same latitude, it decreases 10~90 gammas. with the increment of $1^{\circ}$ in longitude. Decreasing rate is considerably larger in higher latitude as the case of vertical component. (4) The declination ranges from $-3.8^{\circ}$ to $-11.5^{\circ}$. It increases $0.6^{\circ}$ with the increment of $1^{\circ}$ in latitude. Along the same latutude, it increases $0.6^{\circ}$ with the increment of l O in longitude. Unlike the cases of vertical and total component, the rate of change is considerably larger in lower latitude than in higher latitude. (5) The inclination ranges from $57.8^{\circ}$ to $66.8^{\circ}$. It increases about $1^{\circ}$ with 'the increment of $1^{\circ}$ in latitude Along the same latitude, it dereases $0.4^{\circ}$ with the increment of $1^{\circ}$ in longitude. (6) The Boundaries of 5 anomaly zones classified on the basis of the trend and shape of anomaly curves correspond to the geologic boundaries. (7) The trend of anomaly curves in each anomaly zone is closely related to the geologic structure developed in the corresponding zone. That is, it relates to the fault in the 3rd zone, the intrusion. of granite in the 1st and 5th zones, and mountains in the 2nd and 4th zones.

• 대한기계학회논문집B
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• 제23권9호
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• pp.1139-1150
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• 1999

The evolution of silica aggregate particles in coflow diffusion flames has been studied experimentally using light scattering and thermophoretic sampling techniques. The measurements of scattering cross section from $90^{\circ}$ light scattering have been utilized to calculate the aggregate number density and volume fraction using with combination of measuring the particle size and morphology through the localized sampling and a TEM image analysis. Aggregate or particle number densities and volume fractions were calculated using Rayleigh-Debye-Gans and Mie theory for fractal aggregates and spherical particles, respectively. Of particular interests are the effects of flame temperature on the evolution of silica aggregate particles. As the flow rate of $H_2$ increases, the primary particle diameters of silica aggregates have been first decreased, but, further increase of $H_2$ flow rate causes the diameter of primary particles to increase and for sufficiently larger flow rates, the fractal aggregates finally become spherical particles. The variation of primary particle size along the upward jet centerline and the effect of burner configuration have also been studied.

• 한국지구과학회지
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• 제38권3호
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• pp.173-181
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• 2017

The stability of the steady Rossby-Haurwitz wave (R-H wave) in the nondivergent barotropic model (NBM) on the sphere was investigated with the normal mode method. The linearized NBM equation with respect to the R-H wave was formulated into the eigenvalue-eigenvector problem consisting of the huge sparse matrix by expanding the variables with the spherical harmonic functions. It was shown that the definite threshold R-H wave amplitude for instability could be obtained by the normal mode method. It was revealed that some unstable modes were stationary, which tend to amplify without the time change of the spatial structure. The maximum growth rate of the most unstable mode turned out to be in almost linear proportion to the R-H wave amplitude. As a whole, the growth rate of the unstable mode was found to increase with the zonal- and total-wavenumber. The most unstable mode turned out to consist of more-than-one zonal wavenumber, and in some cases, the mode exhibited a discontinuity over the local domain of weak or vanishing flow. The normal mode method developed here could be readily extended to the basic state comprised of multiple zonalwavenumber components as far as the same total wavenumber is given.

• 콘크리트학회논문집
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• 제12권4호
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• pp.103-111
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• 2000

The influence of the improvement of grain shape of the coarse aggregate to the unit powder content of concrete and the fine aggregate ratio for the increase of the flowability and segregation resistance of high performance concrete was examined. According to the experimental results, flowability and compacting of concrete presents best states in the S/a which has the smallest 패야 ratio. The coarse aggregate after improvement of grain shape, that has changed from the 0.68 of spherical rate of disk shape to 0.73, led fine aggregate ratio to be down 6% (i.e from 47% to 41%). The improvement of grain shape of the coarse aggregate also led the lowest unit powder content to be down 60kg/㎥ (ie from 530kg/㎥ to 470kg/㎥). And approximate 10% of unit water content has been reduced as unit powder content was down. However, the compressive strength after the improvement of grain shape of the coarse aggregate decreased to 5% due to decrease of adhesiveness of the aggregate and cement paste.

• 한국재료학회지
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• 제11권9호
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• pp.763-768
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• 2001

Molybdenum-based thermal spray powder is widely used for coating the moving parts of the internal combustion engines due to its excellent wear resistance. A composite powder of the $Mo_{40}(Al_{1-x}Si_x)_{60}$ system was synthesized using the SHS method. The synthesized bulk was pulverized and specially treated to produce thermal spray powder. It was found that the synthesis reaction consisted of two-steps: the formation of $Al_8/Mo_3$ and the formation of Mo(Al,Si)$_2$. Both the temperature and the rate of the SHS reaction linearly increased with the increase of the value of x in $Mo_{40}(Al_{1-x}Si_x)_{60}$, The temperature and the rate of the reaction were also affected by the compacting density of the specimens, exhibiting the maximum valves at 62% and 60%, respectively. Since spherical shape is advantageous to the thermal spraying process, shape-control of the powder was attempted with PVA as a binding additive, resulting in the successful production of almost perfectly spherical powder of 80 $\mu\textrm{m}$ Ø$(d_{50})$ mean particle size.

• 전기화학회지
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• 제10권4호
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• pp.252-256
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• 2007

A series of spherical porous carbons were prepared via resorcinol-formaldehyde (RF) sol-gel polymerization in the presence of cationic surfactant (CTAB, cetyltrimethylammonium bromide), wherein the carbon sphere size was controlled by varying the CTAB introduction time after a pre-determined period of addition reaction (termed as "pre-curing"). The sphere size gradually decreases with an increase in the pre-curing time within the range of 30-150 nm. The carbons possess two types of pores; one inside carbon spheres (intra-particle pores) and the other at the interstitial sites made by carbon spheres (inter-particle pores). Of the two, the surface exposed on the former was dominant to determine the electric double-layer capacitor (EDLC) performance of porous carbons. As the intra-particle pores were generated inside RF gel spheres by gasification, the pore diameter was similar for all these carbons, thereby the pore length turned out to be a decisive factor controlling the EDLC performance. The charge-discharge voltage profiles and complex capacitance analysis consistently illustrate that the smaller-sized RF carbons deliver a better rate capability, which must be the direct result of facilitated ion penetration into shorter pores.

• Geomechanics and Engineering
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• 제31권3호
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• pp.281-289
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• 2022

Bio-CaCO₃ is a blowout environment-friendly materials for soil improvement and sealing of rock fissures. To evaluate the chemical characteristics, shape, size and productivity of soybean urease induced CaCO₃ precipitates (SUICP), experimental studies were conducted via EDS, XRD, FT-IR, TGA, BET, and SEM. Also, the conversion rate of SUICP reaction at different time were determined and analyzed. The Bio-CaCO₃ product obtained by SUICP is comprehensively judged as calcite based on the results of EDS, XRD and FT-IR. The SUICP calcite precipitates are detected as spherical or ellipsoidal particles 3-6 ㎛ in diameter with nanoscale pores on their surface, and this morphology is novel. The median secondary particle size d₅₀ is 39-88 ㎛, indicating the agglomeration of the primary calcite particles. The Bio-calcite decomposes at 650-780℃, representing a medium thermal stability. The conversion rate of SUICP reaction can reach 80% in 24h, which is much more efficient than microbially induced CaCO₃ precipitation. These results reveal the knowledges of SUICP, and further direct its engineering applications. Moreover, we show an economic channel to obtain porous spherical calcite.

• 한국지구과학회지
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• 제37권2호
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• pp.107-116
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• 2016

전구영역 수치모델을 이용하여 순압 로스비-하우어비츠 파동의 안정성을 조사하였다. 본 연구에서 조사한 로스비-하우어비츠 파동은 강체 회전하는 동서 기본류와 유한한 진폭을 가지는 구면조화 파동으로 구성된다. 로스비-하우어비츠 파동은 강체 회전하는 동서 평균류의 강도에 따라 정상 또는 비정상의 구조로 나타난다. 수치 실험을 통해 임의의 다른 두 시간에서 섭동장의 진폭을 비교하여 파동의 안정성뿐만 아니라 성장률을 결정하였다. 로스비-하우어비츠 파동의 불안정 모드는 다양한 동서 파수 성분이 결합된 형태로 나타났다. 파동의 속도가 느린 지역에서 와도 섭동장은 불연속적인 형태를 보이는데, 이는 모델의 수평 해상도와 관계가 없는 것으로 밝혀졌다. 푸리에-유한 요소 모델에서 더 이른 적분 시간에 불안정 모드가 나타났는데, 이는 구면조화 스펙트럴 모델 대비 더 낮은 수치 정확도를 가지기 때문인 것으로 보인다. 모델의 전체적인 정확도를 고려하여, 불안정 모드가 구면 조화 파동을 전체적으로 지배하기 시작하는 시간을 추정하였다.

• 대한기계학회논문집A
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• 제37권10호
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• pp.1229-1237
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• 2013

본 연구에서는 증분소성이론에 기초한 구형압입이론을 크리프 물성을 평가하기 위한 압입이론으로 확장했다. 먼저 크리프변형률 기울기가 일정한 지점을 유효 응력-변형률속도 최적 관측지점으로 선정했다. 구형압입시험 전산모사를 이용해 크리프 지수와 계수를 변화시켜 가면서 이에 따른 재료의 거동을 무차원 변수들 (${\xi}$, ${\psi}$)의 회귀식으로 표현해 크리프 물성평가를 위한 새로운 수치 접근법을 구축했다. 이를 토대로 구형압입시험으로부터 재료의 크리프지수 및 계수를 예측하는 물성평가 프로그램을 개발했다. 압입 하중-변위 곡선으로부터 크리프지수는 평균 1.5%, 크리프계수는 평균 1.0% 이내의 오차범위에서 물성치들을 얻을 수 있다.