• The Journal of Engineering Geology
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• v.22 no.2
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• pp.173-183
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• 2012

The nature of surface deformation of Tono granite was investigated using a confocal laser scanning microscope (CLSM) under water-saturated stress relaxation conditions. A new apparatus was developed for this experiment, enabling continuous measurements of stress-strain and simultaneous observations of surface deformation by CLSM. The amounts of grain contact deformation and intra-granular surface deformation were calculated using a finite element method. The results reveal that intense grain contact deformation and intra-granular surface deformation occurred during the period of stress relaxation, and that the intensity of this deformation increased with increasing applied stress. Finite element method (FEM) results show that the strain of grain boundary was greater than strain of inter-granular surface. Contour maps of these local strains were compiled for individual grains and their boundaries, revealing intense deformation at the boundaries between biotite and quartz under compressional stress. This result was a consequence of the mechano-chemical effect of biotite and quartz minerals. Biotite in granite has a layered structure of iron-magnesium-aluminum silicate sheets that are weakly bonded together by layers of potassium ions. In contrast, quartz occurs as stable spherical grains.

• Journal of Korean Ophthalmic Optics Society
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• v.10 no.1
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• pp.35-40
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• 2005

Subjective and objective visions were measured on young adults(mean 21 yrs, 126 eyes) who were free of any ocular diseases and laser surgery and none wore contact lenses. The aim of this study was to investigate the diurnal variation of vision through subjective and objective measurements. Subjective visual acuity were measured at 5 m three times a day, morning(8:00 AM-10:00 AM), noon(12:00 PM-2:00 PM) and afternoon(4:00 PM-6:00 PM). The instrument used for objective refraction right after visual acuity measurement was Nvision-K 5001(shin-nippon) which unique in being able to disregard subject's accommodation because of its unrestricted viewing conditions. Also, we measured that three times and then calculated the average values. The result showed that an average subjective visual acuity in the morning, noon, afternoon were 0.256(${\pm}0.263$), 0.266(${\pm}0.276$), 0.242(${\pm}0.249$) respectively. Average spherical equivalent power in objective refraction of right eyes showed -3.416 D(${\pm}2.907$), -3.359 D(${\pm}2.735$), -3.297 D(${\pm}2.709$) respectively and dioptric power was decreased from morning to afternoon. Vision changed throughout the day in both subjective and objective measurements nevertheless its variations were statistically insignificant(p<0.05). Therefore it does not seem to matter of time for either visual acuity test or refraction.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.20 no.7
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• pp.46-52
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• 2006

The effects of surface treatment on the hydrogen storage properties of a $Mg_2Ni$ alloy particle were investigated by the microvoltammetric technique, in which a carbon-filament microelectrode was manipulated to make electrical contact with the particle in a KOH aqueous solution. It was found that the hydrogen storage properties of $Mg_2Ni$ at room temperature were improved by the surface treatment with a nickel plating solution. The sodium salts(sodium phosphate and sodium dihydrogen citrate) contained in the nickel plating solution made the alloy form an amorphous-like state, resulting in an improved hydrogen charge/discharge capacity at room temperature as high as about 150[mAh/g] from the original value of 17[mAh/g]. Potential-step experiment was carried out to determine the apparent chemical diffusion coefficient of hydrogen atom($D_{app}$) in the alloy. Since the alloy particle we used here was a dense, conductive sphere, the spherical diffusion model was employed for data analysis. $D_{app}$ was found to vary the order between $10^{-8}{\sim}10^{-9}[cm^2/s]$ over the course of hydrogenation and dehydrogenation process.

• Applied Chemistry for Engineering
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• v.9 no.5
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• pp.634-638
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• 1998

Monodisperse, spherical $PMSQ/TiO_2$ composite fine powders were prepared by modified sol-gel process where 300 nm $TiO_2$ fine powders were used as seed particles for hetero-condensation with hydrolyzed MTMS (Methyltrimethoxysilane). The reaction was carried out under $N_2$ atmosphere at ambient temperature using $NH_3$ as a catalyst. Methanol was used as a solvent. Powder was obtained by the filtration of the solution with a glass filter and washing with acetone. The stirring rate, reaction temperature, $[H_2O]/[MTMS]$ and $[MTMS]/[TiO_2]$ ratio were varied to investigate shapes and sizes of particles. Monodisperse particles of $1-2{\mu}m$ diameter were obtained with [MTMS]=0.2 M, $[NH_3]=0.6M$, $[H_2O]/[MTMS]=100$, $[MTMS]/[TiO_2]=10-50$ at ambient temperature with mild stirring condition. These composite particles had a contact angle of almost 180 degree contact angle with water, which proves their excellent hydrophobicity. The study of UV absorption spectra showed that they have UV protecting effect.

• Polymer(Korea)
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• v.26 no.3
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• pp.326-334
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• 2002

The purpose of this work was the producing of a biodegradable poly($\varepsilon$-caprolactone) (PCL) microcapsule and the analyzing of form and features for the manufacturing conditions which could be observed in a prospective drug delivery systems (DDS) through drug release. The effects of different stirring rates, stirring times and concentrations of emulsifier for the diameter and form of the microcapsules were observed using image analyzer (IA) and scanning electron microscopy (SEM). As a result, the microcapsules were made in wrinkle and spherical forms with a mean particle size of 40~300$\pm$20 $mu extrm{m}$. PCL microcapsules containing drugs were confirmed using FT-IR spectra. The role of interfacial adhesion between PCL and drug was determined by contact angle measurements. The drug release test of PCL microcapsules was characterized by UV/vis. spectra. It was found that the drug release rate of the microcapsules prepared with high concentration emulsifier was significantly fast.

• Explosives and Blasting
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• v.23 no.3
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• pp.27-42
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• 2005

An explosion modeling technique was developed by using the spherical discrete element code, $PFC^{3D}$, which can be used to model the dynamic stress wave propagation phenomenon. The modeling technique is simply based on an idea that the explosion pressure should be applied to a $PFC^{3D}$ particle assembly not in the form of an external force (body force), but in the form of a contact force (surface force). The stress wave propagation modeling was conducted by simulating the experimental approach based on the Hopkinson's effect combined with the spatting phenomenon that had previously been developed to determine the dynamic tensile strength of Inada granite. As a result, the stress wave velocity obtained by the proposed modeling technique was 4167 m/s, which is merely $3\%$ lower than the actual wave velocity of 4300 m/s for an Inada granite.

• Journal of the Korean Society of Hazard Mitigation
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• v.10 no.5
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• pp.17-25
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• 2010

We studied on the watertightness improvement of cementitious material for durability enhancement of concrete. For improvement of watertightness of OPC and OPC with fly ash, we used various materials with watertightness properties to OPC and OPC with fly ash. The performance of watertightness improvement of cementitious materials closely related to formation of CSH by pozzolanic reaction and to reducing of size of contact angle in cement pore by using organic fatty acid. And volume of CSH formation at early hydration have an influence of watertightness improvement and reduction of long-term water absorption rate. In using of fly ash, improvement of workability by using the spherical fly ash caused to densify on the structures of cement material and CSH formation by pozzolanic reaction and cement using fly ash also caused watertightness improvement of cementitious materials. For improvement of concrete durability by watertightness, cementitious materials need using watertightness materials and at using fly ash, also it have to the effect of improvement of watertightness of cementitious materials by pozzolanic reaction.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.20 no.2
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• pp.24-28
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• 2006

Electrochemical hydrogenation/dehydrogenation properties were studied for a single particle of a Mm-based(Mm : misch metal) hydrogen storage alloy($MmNi_{3.55}Co_{0.75}Mn_{0.4}Al_{0.3}$) for the anode of Ni-MH batteries. A carbon fiber microelectrode was manipulated to make electrical contact with an alloy particle, and the cyclic voltammetry and the galvanostatic charge/discharge experiments were performed. A single particle of the alloy showed the discharge capacity of 280[mAh/g], the value being 90[%] of the theoretical capacity. Data were compared with that of the composite film consisting of the alloy particles and a polymer binder, which is more practical form for Ni-MH batteries. Additionally, pulverization of the alloy particles are directly observed. Compared with the conventional composite film electrodes, the single particle measurements using the microelectrode gave more detailed, true information about the hydrogen storage alloy.

• Korean Journal of Materials Research
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• v.23 no.8
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• pp.453-461
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• 2013

Controlling the stick and slip motions of the contact lines in a confined geometry comprised of a spherical lens with a flat substrate is useful for manufacturing polymer ring patterns. We used a sphere on a flat geometry, by which we could control the interfaces of the solution, vapor and substrate. By this method, hundreds of concentric ring-pattern formations of a linear conjugated polymer, poly [2-methoxy-5-(2-thylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV), were generated with excellent regularity over large areas after complete solvent evaporation. Subsequently, the MEH-PPV ring patterns played a role as a directed template to organize highly regular concentric rings of single-walled carbon nanotubes(SWCNTs); when a droplet of the SWCNT suspension in water was casted onto the prepared substrate, hydrophobic polymer patterns confined the water dispersed SWCNTs in between the hydrophilicized $SiO_2/Si$ substrate. As the solvent evaporated, SWCNT-rings were formed in between MEH-PPV rings with controlled density. Finally, we used a lift-off process to produce SWCNT patterns by the removal of a sacrificial polymer template with organic solvent. We also fabricated a field effect transistor using self-assembled SWCNT networks on a $SiO_2/Si$ substrate.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.9 no.4
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• pp.135-143
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• 1989

The experimental study on the shape and behavior of bubbles in U-tube deep shaft of 32m has been performed. According to the results in this paper, the equivalent spherical diameter of bubbles was 0.422-0.722cm and the shape of bubbles was almost ellipsoidal for bubbles to be generated ta single-orifice of diameter 0.06cm in the downcomer of the deep shaft system. Gas hold-up and gas-liquid contact area of bubbles in the deep shaft was decreased in accordance with depth, Also downcomer velocity of bubbles was slower than circulation velocity of liquid and riser velocity of bubbles was fast than circulation velocity. The bubble-size-distribution of bubbles in the deep shaft was the logarithmic probability distribution. The number of bubbles in the deep shaft was decreased in accordance with depth and the number of bubbles in the downcomer is more than the bubbles in the riser.