• Bulletin of the Korean Chemical Society
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• v.19 no.4
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• pp.444-449
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• 1998

The kinetics of the formation of triplex $poly(dA){\cdot}[poly(dT)]_2$ from poly(dA)·poly(dT) and poly(dT) is examined by various optical spectroscopic methods, including absorption, circular and linear dichroism (LD) spectroscopy. In the pseudo first order condition, where the poly(dT) concentration is kept lower than that of duplex, the association of the poly(dT) is enhanced by the presence of ethidium; the rate constant is proportional to the amount of ethidium in the mixture. When the concentration of the duplex and the single strand is the same, a spectral change is explained by double exponential curves, indicating that at least two steps are involved, the fast association and slow rearrangement steps. In contrast to the pseudo first order kinetics, the association step in an equimolar condition is not affected by the presence of ethidium. In the rearrangement step, the magnitude of LD decreases with an increase in ethidium concentration, suggesting that the bending of polynucleotide around the intercalation site occurs in the rearrangement step.

• Bulletin of the Korean Chemical Society
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• v.5 no.6
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• pp.219-223
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• 1984

The 8-methoxypsoralen$<^{4',5'}_{5',6}>$ thymidine monoadducts are isolated from the irradiation mixture of 8-methoxypsoralen and thymidine in a dry film state by a flash column followed by lobar column chromatography. Some physical properties of the adducts were determined. The fluorescence maximum and quantum yield of the monoadduct are dependent on the solvent polarity and the phosphorescence to fluorescence quantum yield ratio was 2.10 which was significantly increased by external heavy atoms. The phosphorescence lifetime was 1.2s which is relatively large compared to other coumarin derivatives. Accurate spectral data of the monoadducts are presented.

• Bulletin of the Korean Chemical Society
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• v.18 no.3
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• pp.324-327
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• 1997

Water soluble iridium complex, IrCl(CO)(TPPTS)2·χH2O (1) (TPPTS=m-trisulfonated triphenylphosphine) has been prepared from the reaction of a water soluble complex, IrCl(COD)(TPPTS)2·6H2O (COD=l,5-cyclooctadiene) with CO and unambiguously characterized by electronic absorption, 31P NMR, 13C NMR and IR spectral data. Complex 1 catalyzes the hydration of terminal alkynes to give ketones in aqueous solutions at room temperature. The rate of PhC≡CH hydration dramatically increases with addition of MeOH to the reaction mixture in H2O, which is understood in terms of i) the excellent miscibility between H2O and MeOH and ii) the assumed catalytic hydration pathway involving the initial formation of (alkyne)IrCl(CO)(TPPTS)2.

• Bulletin of the Korean Chemical Society
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• v.5 no.4
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• pp.167-169
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• 1984

Analyses of $_1$H-NMR, infrared and electronic spectral data for $[Ir(CH_2 = CHCN)(CO)(P(C_6H_5)_3)_2]ClO_4 (1)$prepared by the reaction of $Ir(OClO_3)(CO)(P(C_6H_5)_3)_2$ with $CH_2 = CHCN$, agree with the suggestion that 1 is a mixture of the nitrogen-bonded acrylonitrile complex, $[(CO)(P(C_6H_5)_3)_2Ir-NCCH = CH_2]ClO_4$ and other compound which may be the C = C ${\Pi}$ -system-bonded acrylonitrile complex, "[(CO)(P(C6H5)3)2Ir-CHCN = CH2]ClO4.

• Proceedings of the PSK Conference
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• 2002.10a
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• pp.399.3-399.3
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• 2002

Near-infrared (NIR) system was used to determine rapidly and simply indomethacin in buffer solution for a dissolution test for tablets and capsules. Indomethacin standards were prepared ranging from 10 to 50ppm using mixture of phosphate buffer(pH 7,2) and water(1:4), The near infrared(NIR) transmittance spectra of indomethacin standard solutions were collected by using a quartz cell in 1 mm and 2mm pathlength, Partial least-square regression (PLSR) was explored to develop calibration models over the spectral range 1100-1700nm. (omitted)

• Proceedings of the PSK Conference
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• 2003.10b
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• pp.220.2-220.2
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• 2003

Many interference in blood should be considered for non-invasive blood glucose level monitoring by near-infrared spectroscopy because blood glucose concentration is about 0.1% (w/v) in normal state. In this study, we investigated the influence of other blood components on blood glucose level monitoring by near-infrared spectroscopy. It carried out by newly developed portable type-NIR system (1100∼2200 nm). Spectrum features of NIR diffuse spectral data were investigated for some blood compnents powder such as hemoglobin, blood serum albumin, urea, uric acid, ascorbate, glucose, cholesterol and as adding glucose powder into other blood components powder mixture. (omitted)

• Korean Journal of Remote Sensing
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• v.34 no.5
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• pp.787-799
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• 2018

Accurate and effective mapping is critical step to monitor the spatial distribution and change of flood inundated area in large scale flood event. In this study, we try to suggest methods to use low spatial resolution satellite optical imagery for flood mapping, which has high temporal resolution to cover wide geographical area several times per a day. We selected the Sebou watershed flood in Morocco that was occurred in early 2010, in which several hundred $km^2$ area of the Gharb lowland plain was inundated. MODIS daily surface reflectance product was used to detect the flooded area. The study area showed several distinct spectral patterns within the flooded area, which included pure turbid water and turbid water with vegetation. The flooded area was extracted by thresholding on selected band reflectance and water-related spectral indices. Accuracy of these flooding detection methods were assessed by the reference map obtained from Landsat-5 TM image and qualitative interpretation of the flood map derived. Over 90% of accuracies were obtained for three methods except for the NDWI threshold. Two spectral bands of SWIR and red were essential to detect the flooded area and the simple thresholding on these bands was effective to detect the flooded area. NIR band did not play important role to detect the flooded area while it was useful to separate the water-vegetation mixed flooded classes from the purely water surface.

• The Journal of the Acoustical Society of Korea
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• v.24 no.1
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• pp.29-37
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• 2005

This paper proposes an automatic genre classification system for Korean traditional music. The Proposed system accepts and classifies queried input music as one of the six musical genres such as Royal Shrine Music, Classcal Chamber Music, Folk Song, Folk Music, Buddhist Music, Shamanist Music based on music contents. In general, content-based music genre classification consists of two stages - music feature vector extraction and Pattern classification. For feature extraction. the system extracts 58 dimensional feature vectors including spectral centroid, spectral rolloff and spectral flux based on STFT and also the coefficient domain features such as LPC, MFCC, and then these features are further optimized using SFS method. For Pattern or genre classification, k-NN, Gaussian, GMM and SVM algorithms are considered. In addition, the proposed system adopts MFC method to settle down the uncertainty problem of the system performance due to the different query Patterns (or portions). From the experimental results. we verify the successful genre classification performance over $97{\%}$ for both the k-NN and SVM classifier, however SVM classifier provides almost three times faster classification performance than the k-NN.

• Journal of the Institute of Electronics Engineers of Korea SP
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• v.38 no.5
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• pp.576-582
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• 2001

The Multi-Band Excitation(MBE) speech coder uses a different approach for the representation of the excitation signal. It replaces the frame-based single voiced/unvoiced classification of a classical speech coder with a set of such decision over harmonic intervals in the frequency domain. This enables each speech segment to be a mixture of voiced and unvoiced, and improves the synthetic speech quality by reducing decision errors that might occur on the frame-based single voiced and unvoiced decision process when input speech is degraded with noise. The IMBE-LP, improved version of MBE with linear prediction, represents the spectral information of MBE model with linear prediction coefficients to obtain low bit rate of 2.4 kbps. In this Paper, we proposed a variable rate IMBE-LP vocoder that has lower bit rate than IMBE-LP without degrading the synthetic speech quality. To determine the LP order, it uses the spectral band information of the MBE model that has something to do with he input speech's characteristics. Experimental results are riven with our findings and discussions.

• The Journal of the Acoustical Society of Korea
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• v.26 no.6
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• pp.259-268
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• 2007

This paper contributes to an improvement of the statistical bandwidth extension(BWE) system based on Hidden Markov Model(HMM). First, the existing HMM training method for BWE, which is suggested originally by Jax, is analyzed in comparison with the general Baum-Welch training method. Next, based on this analysis, a new HMM-based BWE method is suggested which adopts the Baum-Welch re-estimation algorithm instead of the Jax's to train HMM model. Conclusionally speaking, the Baum-Welch re-estimation algorithm is a generalized form of the Jax's training method. It is flexible and adaptive in modeling the statistical characteristic of training data. Therefore, it generates a better model to the training data, which results in an enhanced BWE system. According to experimental results, the new method performs much better than the Jax's BWE systemin all cases. Under the given test conditions, the RMS log spectral distortion(LSD) scores were improved ranged from 0.31dB to 0.8dB, and 0.52dB in average.