• Mass Spectrometry Letters
• /
• v.4 no.4
• /
• pp.79-82
• /
• 2013

Various types of alkaloids observed in several herbal medicines were analyzed by electrospray ionization tandem mass spectrometry in positive ion mode. In the present study, MS/MS spectralpatterns were investigated for eight-types of alkaloids (aporpine, protoberberine, tetrahydroprotoberberine, benzylisoquinoline, protopine, phthalide, morpine, and bisbenzylisoquinoline). For aporpine- and protoberberine-type alkaloids, main fragmentations occurred at substituted groups on rigid ring structures, not showing ring fusion. Interesting fragmentations due to iminolization and retro-Diels-Alder (RDA) reaction were observed in MS/MS spectra of protopine- and tetrahydroprotobereberine-type alkaloids. Also, several types of fragmentations such as inductive cleavage and ${\alpha}$-cleavage, or bond cleavage between two ring structures were observed depending on their structural characteristics. These fragmentation patterns are expected to allow instant classification of the specific alkaloid type in various MS/MS spectra of alkaloids.

• The Bulletin of The Korean Astronomical Society
• /
• v.39 no.1
• /
• pp.45.1-45.1
• /
• 2014

We present the results of a time series analysis of the long-term radio lightcurves of four blazars: 3C 279, 3C 345, 3C 446, and BL Lacertae. We exploit the data base of the University of Michigan Radio Astronomy Observatory (UMRAO) monitoring program which provides densely sampled lightcurves spanning 32 years in time in three frequency bands located at 4.8, 8, and 14.5,GHz. Our sources show mostly flat or inverted (spectral indices -0.5 < alpha < 0) spectra, in agreement with optically thick emission. All lightcurves show strong variability on all time scales. Analyzing the time lags between the lightcurves from different frequency bands, we find that we can distinguish high-peaking flares and low-peaking flares in accord with the classification of Valtaoja et al. (1992). The periodograms (temporal power spectra) of the observed lightcurves are consistent with random-walk powerlaw noise without any indication of (quasi-)periodic variability. The fact that all four sources studied are in agreement with being random-walk noise emitters at radio wavelengths suggests that such behavior is a general property of blazars.

• Proceedings of the Korean Geotechical Society Conference
• /
• 2010.03a
• /
• pp.777-784
• /
• 2010

In the current Korean seismic design guide, the site classification and the corresponding site coefficients were determined based on the UBC-1997 (Uniform Building Code). In order to develop the current site classification system, it is important to compare the local site conditions in Korea to other countries which have similar seismic design guides. In the eastern United States, New York City(40degrees 45minutes north latitude, 73degrees 59minutes west longitude) suggested that current design guidelines are unsuitable to shallow bedrock depth sites. So the 3-parameter methods are performed for new criteria in New York City. In this study, site response analyses were performed at 181 study sites using one-dimensional equivalent linear to evaluate the site-specific earthquake ground motions at inland areas in the Korean peninsula and reclassify the results according to similar ground motions using the 3-parameter methods. It is effective that multi-parameter methods for Korean site characteristics in comparison with single parameter method.

• Journal of the Institute of Electronics Engineers of Korea CI
• /
• v.49 no.1
• /
• pp.16-22
• /
• 2012

In this paper, we proposed a method of baseline correction for analysis of Raman spectra of platelets from Alzheimer's disease (AD) transgenic mice. Measured Raman spectra include the meaningful information and unnecessary noise which is composed of baseline and additive noise. The Raman spectrum is divided into the local region including several peaks and the spectrum of the region is modeled by curve fitting using Gaussian model. The additive noise is clearly removed from the process of replacing the original spectrum with the fitted model. The baseline correction after interpolating the local minima of the fitted model with linear, piecewise cubic Hermite and cubic spline algorithm. The baseline corrected models extract the feature with principal component analysis (PCA). The classification result of support vector machine (SVM) and maximum $a$ posteriori probability (MAP) using linear interpolation method showed the good performance about overall number of principal components, especially SVM gave the best performance which is about 97.3% true classification average rate in case of piecewise cubic Hermite algorithm and 5 principal components. In addition, it confirmed that the proposed baseline correction method compared with the previous research result could be effectively applied in the analysis of the Raman spectra of platelet.

• Journal of the Korean Society of Tobacco Science
• /
• v.20 no.2
• /
• pp.191-197
• /
• 1998

Discriminant analysis using near infrared spectra derived from Korean Flue-cured(KF) and American Flue-cured(AF), and also Korean Burley(KB) and American Burley(AB) tobacco was done to classify flue-cured and burley tobacco as either grown in Korea or grown in the USA. Samples were scanned in the wavelength of 400 ～ 2500 nm by near infrared analyzer(NIRSystem Co., model 6500). The discrimination equations for flue-cured and burley tobacco were developed using partial least square 2 method in Infrasoft International NIRS 3 software package. KF samples used for the development of the discrimination equations were higher contents of total sugar, crude ash and chlorine, and higher value of leaf density and brightness, but lower contents of nicotine, total nitrogen and ether extracts, and higher value of redness than those of AF samples. KB samples were higher contents of nicotine, crude ash and chlorine, but lower contents of ether extracts and value of brightness than those of AB samples. On 3 dimensional graph drawn with 3 principal component scores calculated with 3 principal component from KF and KB sample spectra, KF sample spectra were significantly different from AF, and also KB sample spectra were significantly different from AB. The discrimination equations of flue-cured and burley were developed with 3 principal component, respectively. The discrimination equations for flue-cured and burley had a standard error of 0.03 and 0.04, and a R2 of 0.88 and 0.84, respectively. The tobacco samples used for the development of discrimination equation were perfectly classified as KF and AF by flue-cured discrimination equation, and also perfectly classified KB and AB by burley discrimination equation, respectively. The correct classification rates of KF and AF samples not used for the development of discrimination equations were 9S % (828 out of 869 samples) and 98 % (98 out of 100 samples) by flue-cured discrimination equations, and KB and AB samples were 94%(345 out of 368 samples) and 100%(42 out of 42 samples) by burley discrimination equations, respectively.

• Phonetics and Speech Sciences
• /
• v.4 no.3
• /
• pp.103-110
• /
• 2012

In this paper, a target signal detection method using multiple signal classification (MUSIC) algorithm is proposed. The MUSIC algorithm is a subspace-based direction of arrival (DOA) estimation method. Using the inverse of the eigenvalue-weighted eigen spectra, the algorithm detects the DOAs of multiple sources. To apply the algorithm in target signal detection for GSC-based beamforming, we utilize its spectral response for the DOA of the target source in noisy conditions. The performance of the proposed target signal detection method is compared with those of the normalized cross-correlation (NCC), the fixed beamforming, and the power ratio method. Experimental results show that the proposed algorithm significantly outperforms the conventional ones in receiver operating characteristics (ROC) curves.

• Phonetics and Speech Sciences
• /
• v.9 no.4
• /
• pp.27-34
• /
• 2017

The purpose of this work is to examine the English and Korean voiceless plosives from the Buckeye[15] and Seoul[16] corpus in terms of their static spectral characteristics. The plosives were automatically extracted by a Praat script. In order to estimate the percent correctness in the classification of the plosives, discriminant analyses were performed whose trainings were based on four spectral moments, i.e. the center of gravity, variance, skewness and kurtosis as suggested in [6]. Another set of discriminant analyses were performed based on the spectral tilts. In the last set of analyeses, the spectral moments and tilts were both used in the training. Results showed that the correct classification rate did not exceed around 65% in the best case, which suggested that phonetic cues other than the release burst would be necessary including the dynamic spectral aspects and vowel-onset cues.

• Proceedings of the IEEK Conference
• /
• 2006.06a
• /
• pp.261-262
• /
• 2006

According to the previous work, various well known methods including maximum a posteriori probability classifier (MAP) and multi layer perceptron networks classifier (MLP) showed competitive results. Since even the small errors often leads to a fatal result, we investigated the method that reduces classification error perfectly by screening out some ambiguous patterns. Those ambiguous patterns can be examined by routine biopsy. We incorporated an ambiguous category in MAP and MLP. Classification results involving 216 spectra gave 100% sensitivity for the case of MLP.

• Journal of the Korean Chemical Society
• /
• v.63 no.2
• /
• pp.78-84
• /
• 2019

High-resolution $^1H$ NMR spectroscopic technique has been widely used as one of the most powerful analytical tools in food chemistry as well as to define molecular structure. The $^1H$ NMR spectra-based metabolomics has focused on classification and chemometric analysis of complex mixtures. The principal component analysis (PCA), an unsupervised clustering method and used to reduce the dimensionality of multivariate data, facilitates direct peak quantitation and pattern recognition. Using a combination of these techniques, the various green teas and black teas brewed were investigated via metabolite profiling. These teas were characterized based on the leaf size and country of cultivation, respectively.

• The Bulletin of The Korean Astronomical Society
• /
• v.44 no.2
• /
• pp.71.2-71.2
• /
• 2019

In order to gather clues to surface mineralogy of asteroids, we classify their taxonomy based on their reflected spectra. It is remarkable that a large number of asteroids plotted in the proper orbital element space with distinct colors according to their taxonomic types reveal the dynamical evolution and the structure in the near-Earth space, the main-belt and beyond. Although we have ~1×10⁶ known objects, no more than ~3×10³ of them are properly classified taxonomically as visible-near infrared spectroscopy is costly. On the other hand, multi-wavelength broadband photometry in the visible region provides a rather inexpensive alternative tool for approximate taxonomy. Thus we have conducted multi-band observations systematically using Korea Microlensing Telescope Network (KMTNet) with BVRI and griz filters since back in 2015. We then applied aperture photometry with elliptical apertures to fit the trails of objects during the exposures, and classified them with the principle component indices of Ivezic et al. (2001). We will make use of our new, three dimensional asteroid classification scheme for the next step.