• Title/Summary/Keyword: specific surface area

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A Study on Geotechnical Properties of Deep-Sea Sediments, NE Equatorial Paciflc of KODOS Area (북동태평양 KODOS 지역 심해저 퇴적물의 지질공학적 특성)

  • Kim, Ki-Hyun;Moon, Jai-Woon;Lee, Kyeong-Yong;Son, Seung-Kyu;Oh, Jae-Kyung;Chi, Sang-Bum
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.5 no.4
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    • pp.320-334
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    • 2000
  • Deep-sea surface sediment were analyzed for their geotechnical properties, and the sediment samples were collected with a multiple-corer from 31 stations along the track line (131$^{\circ}$30'W, 5-12$^{\circ}$N) in the northeast equatorial Paciflc. Most of the sediments from the northern part (8-12$^{\circ}$N) showed typical properties of siliceous sediments, whereas the southern part (5-6$^{\circ}$N) showed calcareous characteristics due to high biogenic carbonate productivity in the surface waters, where its water depth was shallower than the carbonate compensation depth (CCD: 4,400 m). Geotechnical properties changed sharply at the boundary of 7$^{\circ}$N. Calcareous sediments from the southern part had low water contents, low porosity, low shear strength, high bulk density and high specific grain density, whereas siliceous sediments from the northern part attained high water content, high porosity, high shear strength, low bulk density and low specific grain density. Higher sediment activities were observed in the northern sediment samples than the southern sediment samples. The core samples of the northern sediments were divided into a semi-liquid upper layer and a consolidated lower layer with a boundary at 5-8 cm. These sediment samples showed a rapid increasing pattern along the downcore in original shear strength when an opposite trend was observed in the southern samples. The results showed that sediment variabilities in geotechnical properties between the northern and southern parts such as productivities of surface water, grain solubility due to water depth variation, sedimentation rate, erosion and redistribution of sediment, and combined sedimentary processes were distinctly different along the latitude.

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Geoscientific land management planning in salt-affected areas* (염기화된 지역에서의 지구과학적 토지 관리 계획)

  • Abbott, Simon;Chadwick, David;Street, Greg
    • Geophysics and Geophysical Exploration
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    • v.10 no.1
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    • pp.98-109
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    • 2007
  • Over the last twenty years, farmers in Western Australia have begun to change land management practices to minimise the effects of salinity to agricultural land. A farm plan is often used as a guide to implement changes. Most plans are based on minimal data and an understanding of only surface water flow. Thus farm plans do not effectively address the processes that lead to land salinisation. A project at Broomehill in the south-west of Western Australia applied an approach using a large suite of geospatial data that measured surface and subsurface characteristics of the regolith. In addition, other data were acquired, such as information about the climate and the agricultural history. Fundamental to the approach was the collection of airborne geophysical data over the study area. This included radiometric data reflecting soils, magnetic data reflecting bedrock geology, and SALTMAP electromagnetic data reflecting regolith thickness and conductivity. When interpreted, these datasets added paddock-scale information of geology and hydrogeology to the other datasets, in order to make on-farm and in-paddock decisions relating directly to the mechanisms driving the salinising process. The location and design of surface-water management structures such as grade banks and seepage interceptor banks was significantly influenced by the information derived from the airborne geophysical data. To evaluate the effectiveness ofthis planning., one whole-farm plan has been monitored by the Department of Agriculture and the farmer since 1996. The implemented plan shows a positive cost-benefit ratio, and the farm is now in the top 5% of farms in its regional productivity benchmarking group. The main influence of the airborne geophysical data on the farm plan was on the location of earthworks and revegetation proposals. There had to be a hydrological or hydrogeological justification, based on the site-specific data, for any infrastructure proposal. This approach reduced the spatial density of proposed works compared to other farm plans not guided by site-specific hydrogeological information.

Epoxy/BaTiO3 (SrTiO3) composite films and pastes for high dielectric constant and low tolerance embedded capacitors fabrication in organic substrates

  • Paik Kyung-Wook;Hyun Jin-Gul;Lee Sangyong;Jang Kyung-Woon
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 2005.09a
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    • pp.201-212
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    • 2005
  • [ $Epoxy/BaTiO_3$ ] composite embedded capacitor films (ECFs) were newly designed fur high dielectric constant and low tolerance (less than ${\pm}15\%$) embedded capacitor fabrication for organic substrates. In terms of material formulation, ECFs are composed of specially formulated epoxy resin and latent curing agent, and in terms of coating process, a comma roll coating method is used for uniform film thickness in large area. Dielectric constant of $BaTiO_3\;&\;SrTiO_3$ composite ECF is measured with MIM capacitor at 100 kHz using LCR meter. Dielectric constant of $BaTiO_3$ ECF is bigger than that of $SrTiO_3$ ECF, and it is due to difference of permittivity of $BaTiO_3\;and\;SrTiO_3$ particles. Dielectric constant of $BaTiO_3\;&\;SrTiO_3$ ECF in high frequency range $(0.5\~10GHz)$ is measured using cavity resonance method. In order to estimate dielectric constant, the reflection coefficient is measured with a network analyzer. Dielectric constant is calculated by observing the frequencies of the resonant cavity modes. About both powders, calculated dielectric constants in this frequency range are about 3/4 of the dielectric constants at 1 MHz. This difference is due to the decrease of the dielectric constant of epoxy matrix. For $BaTiO_3$ ECF, there is the dielectric relaxation at $5\~9GHz$. It is due to changing of polarization mode of $BaTiO_3$ powder. In the case of $SrTiO_3$ ECF, there is no relaxation up to 10GHz. Alternative material for embedded capacitor fabrication is $epoxy/BaTiO_3$ composite embedded capacitor paste (ECP). It uses similar materials formulation like ECF and a screen printing method for film coating. The screen printing method has the advantage of forming capacitor partially in desired part. But the screen printing makes surface irregularity during mask peel-off, Surface flatness is significantly improved by adding some additives and by applying pressure during curing. As a result, dielectric layer with improved thickness uniformity is successfully demonstrated. Using $epoxy/BaTiO_3$ composite ECP, dielectric constant of 63 and specific capacitance of 5.1nF/cm2 were achieved.

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Performance of Northern Exposure Index in Reducing Estimation Error for Daily Maximum Temperature over a Rugged Terrain (북향개방지수가 복잡지형의 일 최고기온 추정오차 저감에 미치는 영향)

  • Chung, U-Ran;Lee, Kwang-Hoe;Yun, Jin-I.
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.9 no.3
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    • pp.195-202
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    • 2007
  • The normalized difference in incident solar energy between a target surface and a level surface (overheating index, OHI) is useful in eliminating estimation error of site-specific maximum temperature in complex terrain. Due to the complexity in its calculation, however, an empirical proxy variable called northern exposure index (NEI) which combines slope and aspect has been used to estimate OHI based on empirical relationships between the two. An experiment with real-world landscape and temperature data was carried out to evaluate performance of the NEI - derived OHI (N-OHI) in reduction of spatial interpolation error for daily maximum temperature compared with that by the original OHI. We collected daily maximum temperature data from 7 sites in a mountainous watershed with a $149 km^2$ area and a 795m elevation range ($651{\sim}1,445m$) in Pyongchang, Kangwon province. Northern exposure index was calculated for the entire 166,050 grid cells constituting the watershed based on a 30-m digital elevation model. Daily OHI was calculated for the same watershed ana regressed to the variation of NEI. The regression equations were used to estimate N-OHI for 15th of each month. Deviations in daily maximum temperature at 7 sites from those measured at the nearby synoptic station were calculated from June 2006 to February 2007 and regressed to the N-OHI. The same procedure was repeated with the original OHI values. The ratio sum of square errors contributable by the N-OHI were 0.46 (winter), 0.24 (fall), and 0.01 (summer), while those by the original OHI were 0.52, 0.37 and 0.15, respectively.

Mean viscous drift forces on a fixed vertical cylinder in waves and currents (파랑과 조류에 의한 고정된 수직 실린더 구조물에 작용하는 평균 점성 표류력)

  • Shin, Dong Min;Kim, Yuncheol;Moon, Byung Young
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.2
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    • pp.521-527
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    • 2020
  • In offshore structures, the mean viscous drift force due to drag is considered to be a design part that has not been considered until recently. In particular, it is most important to calculate the drift force acting on a vertical cylinder considering both waves and currents in the low frequency region. This paper presents a process for deriving analytical solutions for the drift forces acting on a fixed vertical cylinder considering waves and currents. The area of the cylinder was considered by dividing it into a splash zone above the free surface and a submerged zone below the free surface. The presence of waves is considered only in the Splash Zone, and in the case of waves and currents, the equations were obtained for both the splash and submerged zones. The results show that drift forces occur due to the significant viscous effects in both the splash zone and the submerged zone. Therefore, the analytical solutions derived in this study can be used to calculate the drift force using the given design variables and form a theoretical basis for judging whether the magnitude of the drift force in each case has a dominant influence within a specific physical range.

Zooplankton Community in the Front Zone of the East Sea of Korea (the Sea of Japan) : 1. Species List, Distribution of Dominant Taxa, and Species Association (동해 전선역 동물플랑크톤 군집 : 1. 종 목록, 우점종 분포, 종간 유연관계)

  • PARK Chul;CHOI Joong Ki
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.30 no.2
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    • pp.225-238
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    • 1997
  • Zooplankton distribution in the front zone was investigated in the East Sea of Korea (Sea of Japan). More than 100 taxa appeared in the study area, which was far diverse appearance being compared with those in West (Yellow Sea) and South Sea of Korea. In Nov. 1994, Paracalanus parvus, Oikopleura spp., and Noctiluca scintillans, which preferred warmer environment, predominated at the collection sites in the front zone, especially at warmer surface layer. But in Nov. 1995, when the surface water temperatures were about $2^{\circ}C$ lower than those of the previous year, cold water species of copepod Metridia lucens, immature forms of Calanus and Sagitta, and crustacean eggs dominated in the collection sites in front zone, which were geographically not Identical with those of the previous year. Vertical distributional patterns were not coincide among the taxa. This suggests that zooplankton has different specific habitat characteristics with temperatures. In general, those taxa with preference of warmer environments showed high probability of co-occurrance with low abundances while those that preferring colder environments showed low probability of co-occurrance with high abundances. It seems that warm water contributes to the high diversity of zooplankton in the front zone while cold water does to the high biomass.

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A New Algorithm for the Interpretation of Joint Orientation Using Multistage Convergent Photographing Technique (수렴다중촬영기법을 이용한 새로운 절리방향 해석방법)

  • 김재동;김종훈
    • Tunnel and Underground Space
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    • v.13 no.6
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    • pp.486-494
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    • 2003
  • When the orientations of joints are measured on a rock exposure, there are frequent cases that are difficult to approach by the surveyor to the target joints or to set up scanlines on the slope. In this study, to complement such limit and weak points, a new algorithm was developed to interpret joint orientation from analyzing the images of rock slope. As a method of arranging the multiple images of a rock slope, the multistage convergent photographing system was introduced to overcome the limitation of photographing direction which existing method such as parallel stereophotogrammetric system has and to cover the range of image measurement, which is the overlapping area between the image pair, to a maximum extent. To determine camera parameters in the perspective projection equation that are the main elements of the analysis method, a new method was developed introducing three ground control points and single ground guide point. This method could be considered to be very simple compared with other existing methods using a number of ground control points and complicated analysis process. So the global coordinates of a specific point on a rock slope could be analyzed with this new method. The orientation of a joint could be calculated using the normal vector of the joint surface which can be derived from the global coordinates of several points on the joint surface analyzed from the images.

Electrochemical Characteristics of PFO pitch Anode prepared by Chemical Activation for Lithium Ion Battery (리튬이온전지용 화학적 활성화로 제조된 석유계 피치 음극소재의 전기화학적 특성)

  • Hwang, Jin Ung;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.55 no.3
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    • pp.307-312
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    • 2017
  • In this study, the electrochemical performance of surface modified carbon using the PFO (pyrolyzed fuel oil) was investigated by chemical activation with KOH and $K_2CO_3$. PFO was heat treated at $390{\sim}400^{\circ}C$ for 1~3h to prepared the pitch. Three carbon precursors (pitch) prepared by the thermal reaction were 3903 (at $390^{\circ}C$ for 3h), 4001(at $400^{\circ}C$ for 1h) and 4002 (at $400^{\circ}C$ for 2h). Also, the effect of chemical activation catalysts and mixing time on the development of porosity during carbonization was investigated. The prepared carbon was analyzed by BET and FE-SEM. It was shown that chemical activation with KOH could be successfully used to develop carbon with specific surface area ($3.12m^2/g$) and mean pore size (22 nm). The electrochemical characteristics of modified carbon as the anode were investigated by constant current charge/discharge, cyclic voltammetry and electrochemical impedance tests. The coin cell using pitch (4002) modified by KOH has better initial capacity (318 mAh/g) than that of other pitch coin cells. Also, this prepared carbon anode appeared a high initial efficiency of 80% and the retention rate capability of 2C/0.1 C was 92%. It is found that modified carbon anode showed improved cycling and rate capacity performance.

Study on Applicability of Passive Infrared Thermography Analysis for Blistering Detection of Stone Cultural Heritage (석조문화유산의 박리검출을 위한 수동적 적외선 열화상분석의 적용성 연구)

  • Jo, Young Hoon;Lee, Chan Hee;Yoo, Ji Hyun
    • Journal of Conservation Science
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    • v.29 no.1
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    • pp.55-67
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    • 2013
  • This study focused on analysis condition and application method of the passive infrared thermography according to the direction and time to nondestructively detect the blistering zone of stone cultural heritage. As a result, the passive thermographic images showed different temperature characteristics by time because it sensitively reacts to air temperature, insolation and sunshine direction. In particular, the insolation and sunshine direction, which are periodically changed from 6:00 to 17:00, irregularly made surface temperature. In addition, surface temperature differences were brought on fresh zones and blistering zones except specific time since blistering causes erratic thermal transfer. As a result of examining the detection characteristics of blistering by time, the blistering was well detected between 9:00 and 10:00 when there was rapid increase in air temperature and insolation in all direction except the north. However, this study isn't considered effects of four seasons because it is carried out in autumn, and the passive thermography has difficulty to analyze the quantitative area of blistering zone. Therefore, an additional study for synthetic consideration of the passive thermography analysis about four seasons and quantitative modeling of blistering zone using the active thermography are needed.

Preparation and Electrochemical Properties of PANI/TiO2 Composites for Supercapacitor Electrodes (수퍼커패시터 전극을 위한 폴리아닐린/TiO2 복합체의 제조 및 전기화학적 성질)

  • Park, Sukeun;Kim, Kwang Man;Lee, Young-Gi;Jung, Yongju;Kim, Seok
    • Korean Chemical Engineering Research
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    • v.50 no.1
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    • pp.50-54
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    • 2012
  • In this study, PANI and PANI/$TiO_2$ composites were prepared as electrode materials for a supercapacitor application. Cyclic voltammetry (CV) was performed to investigate the supercapacity properties of these electrodes in an electrolyte solution of 6 M KOH. The PANI/$TiO_2$ composites were polymerized by amount of various ratios through a simple in-situ method. The morphological properties of composites were analyzed by SEM and TEM method. The crystallinity of the composite and $TiO_2$ particle size were identified using X-ray diffraction (XRD). In the electrochemical test, The electrode containing 10 wt% $TiO_2$ content against aniline units showed the highest specific capacitance (626 $Fg^{-1}$) and delivered a capacitance of 286 $Fg^{-1}$ reversibly at a 100 $mVs^{-1}$ rate. According to the surface morphology, the increased capacitance was related to the fact that nano-sized $TiO_2$ particles (~6.5 nm) were uniformly connected for easy charge transfer and an enhanced surface area for capacitance reaction of $TiO_2$ itself.