• 한국화재소방학회논문지
• /
• 제28권6호
• /
• pp.108-113
• /
• 2014

유해물질처리를 효율적으로 개선하기 위해 슬라이딩아크방전(sliding arc plasma)과 corona dielectric barrier discharge(CDBD공정)의 복합공정을 이용하였다. 이장치는 OH 라디칼과 음이온을 생성하여 강력한 산화력으로 탈취 및 살균 효과를 가진다. 실험결과 SAP 반응기의 크기를 80 A를 50 A로 축소하여도 유해물질의 농도는 큰 변화가 없는 것으로 나타나 반응기의 규모를 최소화할 수 있을 것으로 판단된다. 그리고 CDBD 반응기에서 생성된 음이온과 오존은 유해물질과 반응한 후 음이온은 510,000 ppb에서 470 ppb, 오존은 98 ppb에서 22 ppb로 낮아짐을 확인하였다. 또한 플라즈마 발생장치의 안정성 및 내구성이 우수한 것으로 판단되었다. 따라서 본 연구를 통하여 향후 플라즈마복합공정을 이용하여 실내공기중에 존재하는 유해물질 제거를 효율적으로 할 수 있을 것으로 생각된다.

• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2011년도 제40회 동계학술대회 초록집
• /
• pp.409-409
• /
• 2011

All solid-state thin film lithium batteries have many applications in miniaturized devices because of lightweight, long-life, low self-discharge and high energy density. The research of cathode materials for thin film lithium batteries that provide high energy density at fast discharge rates is important to meet the demands for high-power applications. Among cathode materials, lithium manganese oxide materials as spinel-based compounds have been reported to possess specific advantages of high electrochemical potential, high abundant, low cost, and low toxicity. However, the lithium manganese oxide has problem of capacity fade which caused by dissolution of Mn ions during intercalation reaction and phase instability. For this problem, many studies on effect of various transition metals have been reported. In the preliminary study, the Sn-substituted LiMn2O4 thin films prepared by pulsed laser deposition have shown the improvement in discharge capacity and cycleability. In this study, the thin films of LiMn2O4 and LiSn0.0125Mn1.975O4 prepared by RF magnetron sputtering were studied with effect of deposition parameters on the phase, surface morphology and electrochemical property. And, all solid-state thin film batteries comprised of a lithium anode, lithium phosphorus oxy-nitride (LiPON) solid electrolyte and LiMn2O4-based cathode were fabricated, and the electrochemical property was investigated.

• 한국표면공학회지
• /
• 제42권3호
• /
• pp.133-138
• /
• 2009

Effects of bipolar pulse driving frequency between 50 kHz and 250 kHz on the discharge shapes were analyzed by measuring plasma characteristics by OES (Optical Emission Spectroscopy) and Langmuir probe. Plasma characteristics were modeled by a simple electric field analysis and fluid plasma modeling. Discharge shapes by a continuous dc and bipolar pulsed dc were different as a dome-type and a vertical column-type at the cathode. From OES, the intensity of 811.5 nm wavelength, the one of the main peaks of Ar, decreased to about 43% from a continuous dc to 100 kHz. For increasing from 100 kHz to 250 kHz, the intensity of 811.5 nm wavelength also decreased by 46%. The electron density decreased by 74% and the electron temperature increased by 36% at the specific position due to the smaller and denser discharge shape for increasing pulse frequency. Through the numerical analysis, the negative glow shape of a continuous dc were similar to the electric potential distribution by FEM (Finite Element Method). For the bipolar pulsed dc, we found that the electron temperature increased to maximum 10 eV due to the voltage spikes by the fast electron acceleration generated in pre-sheath. This may induce the electrons and ions from plasma to increase the energetic substrate bombardment for the dense thin film growth.

• 한국분말재료학회지
• /
• 제19권3호
• /
• pp.210-214
• /
• 2012

Mass production-capable $Li_2MnSiO_4$ powder was synthesized for use as cathode material in state-of-the-art lithium-ion batteries. These batteries are main powder sources for high tech-end digital electronic equipments and electric vehicles in the near future and they must possess high specific capacity and durable charge-discharge characteristics. Amorphous silicone was quite superior to crystalline one as starting material to fabricate silicone oxide with high reactivity between precursors of sol-gel type reaction intermediates. The amorphous silicone starting material also has beneficial effect of efficiently controlling secondary phases, most notably $Li_xSiO_x$. Lastly, carbon was coated on $Li_2MnSiO_4$ powders by using sucrose to afford some improved electrical conductivity. The carbon-coated $Li_2MnSiO_4$ cathode material was further characterized using SEM, XRD, and galvanostatic charge/discharge test method for morphological and electrochemical examinations. Coin cell was subject to 1.5-4.8 V at C/20, where 74 mAh/g was observed during primary discharge cycle.

• International Journal of Fluid Machinery and Systems
• /
• 제4권1호
• /
• pp.179-190
• /
• 2011

The swirling flow developing in Francis turbine draft tube under part load operation leads to pressure fluctuations usually in the range of 0.2 to 0.4 times the runner rotational frequency resulting from the so-called vortex breakdown. For low cavitation number, the flow features a cavitation vortex rope animated with precession motion. Under given conditions, these pressure fluctuations may lead to undesirable pressure fluctuations in the entire hydraulic system and also produce active power oscillations. For the upper part load range, between 0.7 and 0.85 times the best efficiency discharge, pressure fluctuations may appear in a higher frequency range of 2 to 4 times the runner rotational speed and feature modulations with vortex rope precession. It has been pointed out that for this particular operating point, the vortex rope features elliptical cross section and is animated of a self-rotation. This paper presents an experimental investigation focusing on this peculiar phenomenon, defined as the upper part load vortex rope. The experimental investigation is carried out on a high specific speed Francis turbine scale model installed on a test rig of the EPFL Laboratory for Hydraulic Machines. The selected operating point corresponds to a discharge of 0.83 times the best efficiency discharge. Observations of the cavitation vortex carried out with high speed camera have been recorded and synchronized with pressure fluctuations measurements at the draft tube cone. First, the vortex rope self rotation frequency is evidenced and the related frequency is deduced. Then, the influence of the sigma cavitation number on vortex rope shape and pressure fluctuations is presented. The waterfall diagram of the pressure fluctuations evidences resonance effects with the hydraulic circuit. The influence of outlet bubble cavitation and air injection is also investigated for low cavitation number. The time evolution of the vortex rope volume is compared with pressure fluctuations time evolution using image processing. Finally, the influence of the Froude number on the vortex rope shape and the associated pressure fluctuations is analyzed by varying the rotational speed.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2000년도 하계학술대회 논문집
• /
• pp.444-447
• /
• 2000

The spinel L $i_{1-x}$ M $n_2$ $O_4$has been synthesized by the solid-state reaction. L $i_{l-x}$M $n_2$ $O_4$which includes a mixture of LiOH . $H_2O$ and Mn $O_2$prepared by preliminary heating at 35$0^{\circ}C$ for 12hr. L $i_{l-x}$M $n_2$ $O_4$fired at temperature range from 75$0^{\circ}C$ for 48hr. The structure and the electrochemical characteristics of spinel to L $i_{1-x}$ M $n_2$ $O_4$which is fabricated by changing sintering condition from starting materials are investigated. The cyclic voltammetric measurement was performed using 3 electrode cells. Electrode specific capacity and cycle life behavior were tested in a 3.0~4.2V range at a constant current density of 0.45mA/c $m^2$. To improve the cycle performance of spinel L $i_{l-x}$M $n_2$ $O_4$as the cathode of 4V class lithium secondary batteries, spinel phases L $i_{1-x}$ M $n_2$ $O_4$were Prepared at various lithium. The results showed that discharge capacity of L $i_{l-x}$M $n_2$ $O_4$varied at lithium quantity decrease with increasing lithium add quantity. The discharge capacities of L $i_{0.925}$M $n_2$ $O_4$and LiM $n_2$ $O_4$revealed 108 and 117mAh/g, respectively.spectively.y.

• 한국추진공학회지
• /
• 제25권5호
• /
• pp.65-72
• /
• 2021

소형위성의 궤도조정 및 궤도유지에 활용될 수 있는 700 W급 홀추력기 랩모델을 개발하였다. 스케일링 방정식을 사용하여 방전채널의 크기를 선정하였으며, 자기장이 방전채널 중심선을 기준으로 대칭성을 가지면서 방전채널 바깥에서 최대가 되도록 설계하였다. 개발된 홀추력기의 방전시험은 2.0×10^-5 Torr 이하의 배경압력을 갖는 진공 환경에서 수행되었으며 추력 스탠드를 이용하여 추력을 측정하였다. 양극전압을 300 V로 고정하고 양극유량과 코일전류를 변수로 하여 추력을 측정하였으며, 양극유량 2.36 mg/s, 코일전류 2.4 A 조건에서 양극전력 620 W에서 추력 38 mN, 통합비추력 1,540 s, 양극효율 50 %로 가장 높은 성능을 보였다.

• 전기화학회지
• /
• 제7권3호
• /
• pp.131-137
• /
• 2004

Sol-gel method which provides better electrochemical and physiochemical properties compared to the solid-state method was used to synthesize the material of $LiFe_yMn_{2-y}O_4$. Fe was substituted to increase the structural stability so that the effects of the substitution amount and sintering temperature were analyzed. XRD was used for the structural analysis of produced material, which in turn, showed the same cubic spinel structure as $LiMn_2O_4$ despite the substitution of $Fe^{3+}$. During the synthesis of $LiFe_yMn_{2-y}O_4$, as the sintering temperature and the doping amount of Fe(y=0.05, 0.1, 0.2)were increased, grain growth proceeded which in turn, showed a high crystalline and a large grain size, certain morphology with narrow specific surface area and large pore volume distribution was observed. In order to examine the ability for the practical use of the battery, charge-discharge tests were undertaken. When the substitution amount of $Fe^{3+}\;into\;LiMn_2O_4$ increased, the initial discharge capacity showed a tendency to decrease within the region of $3.0\~4.2V$ but when charge-discharge processes were repeated, other capacity maintenance properties turned out to be outstanding. In addition, when the sintering temperature was $800\~850^{\circ}C$, the initial capacity was small but showed very stable cycle performance. According to EVS(electrochemical voltage spectroscopy) test, $LiFe_yMn_{2-y}O_4(y=0,\;0.05,\;0.1,\;0.2)$ showed two plateau region and the typical peaks of manganese spinel structure when the substitution amount of $Fe^{3+}$ increased, the peak value at about 4.15V during the charge-discharge process showed a tendency to decrease. From the previous results, the local distortion due to the biphase within the region near 4.15V during the lithium extraction gave a phase transition to a more suitable single phase. When the transition was derived, the discharge capacity decreased. However the cycle performance showed an outstanding result.

• 한국수자원학회논문집
• /
• 제44권12호
• /
• pp.991-1000
• /
• 2011

저수지 탁수 모델링에서 실측자료가 없는 경우 유입하천 부유사 농도(SS) 산정을 위해 유량(Q)과 SS 관계식이 자주 사용된다. 일반적으로 하천을 통과하는 SS 부하율은 유량에 의해 변동된다는 가정 하에 유량과 SS의 멱함수(SS=aQb) 관계가 가장 빈번히 적용되고 있다. 그러나 Q-SS 관계는 측정 지점에 따라 배타적 특성을 가지며, 동일 지점에 대해서도 연중 계절적 변동성이 있다. 더욱이, Q-SS 관계는 동일한 수문곡선에서도 유량 상승기와 하강기에 이격현상을 보이기도 한다. 본 연구의 목적은 용담댐 저수지와 소양강댐 저수지 유입 하천에서 강우시 연속 실측한 자료를 바탕으로 Q-SS 관계의 이격현상을 고찰하고, SS 부하율 산정 오차에 미치는 영향을 분석하는데 있다. 연구결과, Q-SS 관계는 홍수사상 동안 높은 분산도와 시계방향의 이격현상을 보였으며, 동일한 유량에 대해 유량 상승기가 하강기보다 SS 농도가 높게 나타났다. 이러한 이격현상은 저수지로 유입하는 SS 부하량 산정에 있어 유의할 만한 오차로 작용하였으며 Q-SS 멱함수는 실측 부하량을 과소평가하는 결과를 가져왔다. 이것은 저수지 탁수모델링에서 중요하게 고려해야 할 사항이다. 본 연구에서는 Q-SS 관계식의 대안으로 탁도-SS관계가 제시되었다. 탁도-SS 관계는Q-SS 관계보다 분산도가 작았으며 실측 부하량과의 오차를 획기적으로 줄였다. 따라서 저수지로 유입하는 SS 부하율의 보다 정확한 산정과 탁수모델링의 신뢰도를 높이기 위해서는 유입 탁도에 대한 실시간모니터링이 필요하다.

• 한국농림기상학회지
• /
• 제8권3호
• /
• pp.174-182
• /
• 2006

이 연구는 임분구조가 다른 3가지 임상에서 장기 증발산량과 유출량의 변화를 분석하여 증발산량, 첨두유출량 및 유출량에 미치는 장기 임상변화의 효과를 밝히기 위하여 수행하였다. 시험지는 경기도 광릉에 소재한 국립산림과학원 유역수문시험지로서 인공침엽수 유령림과 천연활엽수 장령림 그리고 경기도 양주에 소재한 혼효 사방복구림을 대상으로 하였다. 수문자료는 1982년부터 1999년까지 양수댐에서 측정한 유출량과 강수량을 분석하여 각 시험지별로 약 110개의 홍수수 문곡선을 선별한 후 첨두유출량과 그 시점까지의 강수량 합계를 분석하였다. 강수량과 유출량의 관계로부터 증발산량을 추정한 결과, 증발산량은 인공침엽수 유령림에서 679mm, 천연활엽수 장령림에서 580mm이었으며 혼효 사방복구림에서는 368mm이었다. 또한, 유역의 유출량조절효과를 보여주는 유출량-지속기간 곡선에 대한 분석 결과, 임상이 가장 불량한 혼효 사방복구림에서 곡선의 기울기가 가장 급한 것으로 나타났으나, 산림이 생장함에 따라 그 기울기가 감소하는 것으로 분석되었다. 강수량과 첨두유출량의 관계를 분석한 결과, 인공침엽수 유령림과 혼효 사방복구림의 경우 각각 강수량 100mm 및 50mm에서 첨두유출량의 증가율이 높아지는 역치값을 보이는 반면에 천연활엽수 장령림은 200mm로 나타났다. 장기간에 걸친 홍수수 문곡선의 비교 결과, 인공침엽수 유령림에서는 10년이 경과한 후 첨두유출량이 감소한 것으로 나타나, 산림이 생장함에 따라 홍수유출조절 효과가 커지는 것으로 분석되었다.