• Title/Summary/Keyword: specific discharge

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Characteristics of Hydrogen Sulfide Removal by a Catalyst-assisted Plasma System (촉매-플라즈마 반응 시스템을 이용한 황화수소의 처리특성 연구)

  • Lee, Jeong-Keun;Kim, Hyeok-Gyu;Bong, Choon-Keun;Park, Seong-Jin;Lee, Myong-Hwa;Hwang, Ui-Hyun;Kim, Jong-Ho
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.4
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    • pp.379-386
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    • 2011
  • Catalyst-assisted plasma system with a DBD (Dielectric Barrier Discharge) reactor was used to remove hydrogen sulfide, which is one of the odorous species in this study. The ${\gamma}-Al_2O_3$ and ${\beta}$-Zeolite catalysts impregnated by Ag, Cu and Mn species were employed as catalysts and their $H_2S$ removal characteristics under plasma irradiation were investigated. From the experimental study, we found that the $H_2S$ removal efficiency increases with decreasing space velocity in the system and increasing specific input energy. Furthermore, ${\beta}$-Zeolite catalysts are efficient to remove $H_2S$ than ${\gamma}-Al_2O_3$ catalysts. Especially, the catalysts impregnated by Ag have higher removal efficiency than other catalysts (Cu, Mn).

Fabrication of Mesoporous Carbon from Polyvinylidene Chloride(PVDC)-resin Precursor with Mg(OH)2 Template for Supercapacitor Electrode (슈퍼 커패시터용 전극을 위한 Polyvinylidene chloride(PVDC)-resin과 Mg(OH)2 템플릿으로부터 메조기공 탄소의 제조)

  • Hwang, Beodl;Chun, Sang-Eun
    • Journal of the Korean institute of surface engineering
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    • v.52 no.6
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    • pp.326-333
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    • 2019
  • The microporous carbon derived from PVDC-resin by a simple heat-treatment under an inert atmosphere exhibits a reasonable specific capacitance for a supercapacitor's electrode. However, the capacitance was rapidly decreased at high charge/discharge rate. The micropores present in an electrode surface hinder the entrance of an electrolyte ion onto the entire surface. To induce the meso-sized pores during the carbonization of PVDC-resin, Mg(OH)2 was utilized as a hard template. The porous carbon made from the mixture of PVD-Cresin and Mg(OH)2 include mesopores as well as micropores. The induced mesopores does not homogeneously distributed on the entire surface of the synthesized carbon. The PVDC-resin and Mg(OH)2 are dissolved in the dimethylformamide for the hard template to evolve the pores on the synthesized carbon uniformly. The carbon made from PVDC-resin with solvent and a hard template contains mostly mesopores resulting in the high power performance. The reduced amount of solvent in the precursor derives the carbon with high specific surface area and high power density.

Charge-discharge Characteristics of $TiO_2$-Activated Carbon Composite Electrode using Electrospinning (전기방사법으로부터 제조된 $TiO_2$ 섬유 복합전극의 충방전 특성)

  • An, Mi-Sun;Kim, Han-Joo;Son, Won-Keun;Takahashi, Hideaki;Park, Soo-Gil
    • Proceedings of the KIEE Conference
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    • 2005.07c
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    • pp.2022-2024
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    • 2005
  • Electrical double-layer capacitor (EDLC) is an electrochemical energy storage device in which electric charges only accumulated by a pure electrostatic attraction force are stored on the electrolyte-electrode interface in a form of double layer and separated by the electrolyte. The composite was prepared by mixing nanosize $TiO_2$ and activated carbon through a means of ultrasonic vibration in ethanol solution for 30 min in various mass ratios of $AC:TiO_2$ to form activated carbone-semiconducting oxide composites. Either 1.0 M $LiClO_4/EC-DEC$ or $Et_4NBF_4$/EC-DEC was used as the electrolyte. It was found that with modification of $TiO_2$, the specific capacitance of activated carbon measured at $1mA/cm^2$ was increased from 40 to 50 F/g. This method is unique in comparison the conventional method because it uses semiconducting TiO2 other than electrochemically active materials such as $RuO_2$. The increase in specific capacitance could be attributed to the decrease in electric polarization, caused by the introduction of $RuO_2$.

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Philosophical Counseling in the Clinical Field of Korean Medicine: Applicaition and Case Analysis (한의학 임상현장에서의 철학 상담의 적용: 제언과 사례분석)

  • Kim, Jong-Woo;Kwak, Hui-Yong;Chung, Sun-Yong
    • Journal of Oriental Neuropsychiatry
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    • v.30 no.3
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    • pp.119-128
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    • 2019
  • Objectives: This study suggests the application of philosophical counseling in the clinical field of Korean medicine and analyze the specific case. Methods: Through the analysis of coexisting factors of Korean medicine and philosophical counseling, we establish the area of philosophical counseling that Korean medicine practitioner can apply in the medical field. We described effects of philosophical counseling on the patient's symptom and the progress after discharge through a counseling approach based on philosophical questions. Results: During philosophical counseling, the Korean medical doctor asks questions about the nature of suffering and encourages patients to gain insight into their problems. In answering the vital philosophical questions, the patient leads to a creative interpretation of future life directions. We described the method of specific approaches through the description of the two cases. Conclusions: The philosophical counseling is compatible with the concept of Korean medicine, therefore, a Korean medicine practitioner can induce the recovery of mind and body through the creative interpretation of the patient by asking the patient the appropriate question which causes reflective thinking.

Characterization of Electric Double-Layer Capacitors with Carbon Nanotubes Directly Synthesized on a Copper Plate as a Current Collector (구리 집전판에 직접 합성한 탄소나노튜브의 전기이중층 커패시터 특성)

  • Jung, Dong-Won;Lee, Chang-Soo;Park, Soon;Oh, Eun-Souk
    • Korean Journal of Metals and Materials
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    • v.49 no.5
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    • pp.419-424
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    • 2011
  • Carbon nanotubes (CNTs) were directly synthesized on a copper (Cu) plate as a current collector by the catalytic thermal vapor deposition method for an electric double-layer capacitor (EDLC) electrode. The diameters of vertically aligned CNTs grown on the Cu plate were 20~30 nm. From cyclic voltammetry (CV) results, the CNTs/Cu electrode showed high specific capacitance with typical profiles of EDLCs. Rectangularshaped CV curves suggested that the CNTs/Cu electrode could be an excellent candidate for an EDLC electrode. The specific capacitances were in a range of 25~75 F/g with a scan rate of 10~100 mV/s and KOH electrolyte concentration 1~6 M, and were maintained up to 1000 charge/discharge cycles due to strong adhesion between the Cu substrate and the CNTs.

Self-Supporting 3D-Graphene/MnO2 Composite Supercapacitors with High Stability

  • Zhaoyang Han;Sang-Hee Son
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.36 no.2
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    • pp.175-185
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    • 2023
  • A hybrid supercapacitor is a promising energy storage device in view of its excellent capacitive performance. Commercial three-dimensional foam nickel (Ni) can be used as an ideal framework due to an interconnected network structure. However, its application as an electrode material for supercapacitors is limited due to its low specific capacity. Herein, we report a successful growth of MnO2 on the surface of graphene by a one-step hydrothermal method; thus, forming a three-dimensional MnO2-graphene-Ni hybrid foam. Our results show that the mixed structure of MnO2 with nanoflowers and nanorods grown on the graphene/Ni foam as a hybrid electrode delivers the maximum specific capacitance of 193 F·g-1 at a current density 0.1 A·g-1. More importantly, the hybrid electrode retains 104% of its initial capacitance after 1,000 charge-discharge cycles at 1 A·g-1; thus, showing the potential application as a stable supercapacitor electrode.

A Survey on Patients도 Nursing Needs Following Discharge from Hospital (퇴원시 환자의 간호요구도 조사)

  • 이은옥;이선자;박성애
    • Journal of Korean Academy of Nursing
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    • v.11 no.2
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    • pp.33-54
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    • 1981
  • The purposes of this study were to determine the relevant nursing needs of patients following discharge; to identify the degree of their nursing needs; to identify types and status of discharge order and information given to patients; and to determine their specific nursing needs according to their diagnosis. In addition, opinions toward home care services provided by hospitals or by public health nurses and appointment plans with their physicians were also asked in order to determine the necessity of follow-up care for the patient after discharge. Nine hundred and eighty eight subjects were collected among patients being discharged from one national university hospital and four city hospitals. Data were collected from June,1979 to December,1979 using questionnaires and interviews. On the bases of these data the following findings were observed; 1) Almost 40 percents of total subjects discharged from the hospital with some or great degree of nursing needs in general. The most problematic nursing needs were needs for comfort which include needs for releaving pain, for sound sleep and rest, because these needs can only be met by professional help. More than 50% of total subjects have this problem. 2) Needs for mental health, general metabolism, general hygiene and activities and safety were observed in more than 20 percent of subjects. 3) Discharge orders on diet and oral medication were recorded in patients' charts in 70% of all cases. However, more than fifty percents of patients have not been told these information from doctors or nurses. Even though some of them might have had appointment plans with their physicians, they would not keep the appointments unless they completely understood the necessity of the follow-up care. If they have not had any appointment or would not visit the out-patient clinic, there is no method of caring them and prerenting funther discomfort or complications. Even in injection, ski care, dressing and bath, only one thirds of the subjects having recorded discharge orders understood what they need after discharge. The rest of cases have not known what to do for their further care. 4) More than 80 percents and 70 percents of total subjects agreed to a system of home care services provided by hospitals or public health nurses respectively. That is, regardless of sources of medical expenses, most of patients wanted to be taken care of at home following discharge. 5) While more than half of the patients having benefit of medical insurance or paying fully by themselves had appointment plans with their physicians, only one thirds of the patients fully or partially paid by government had appointment plans with their physicians. These results ex-plain that the appointment plan is directly associated with their economic power. This indicates that the home care services are more needed to the people with lower economical status. 6) Those who have been in the hospital more than 24 days wanted !o have home care services more than those who had less hospital days. They also had more appointment plans than other groups. 7) More than 70 percents of the subjects who had been in a university hospital and approximately 30 percents of the subjects in the city hospitals had appointment plans with their physicians. 8) Those who had the cerebrovascular disease, cancer or hypertension demanded more nursing needs such as needs for comfort, for general metabolism and for mental health. 9) Factors which were associated with the degree of patients' nursing needs were age, duration of hospitalization, opinion toward home care services given by public health nurses, hospital appointments and types of hospital. That is, the older they were and the longer the periods of hospitalization were, the higher were their nursing needs. The more they had nursing needs, the more they wanted to have nursing services and had appointment plans. It can be concluded that there is a great demand for a positive and systematic home care services to the people who have been discharged from hospitals following critical care. This program is definitely demanded for the low income groups of people with less education with the financial assistance of the government or other funding agencies.

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Electrical Discharge Plasma in a Porous Ceramic Membrane-supported Catalyst for the Decomposition of a Volatile Organic Compound (다공질 세라믹지지 촉매 상에서의 플라즈마 방전을 이용한 휘발성유기화합물의 분해)

  • Jo, Jin-Oh;Lee, Sang Baek;Jang, Dong Lyong;Mok, Young Sun
    • Applied Chemistry for Engineering
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    • v.24 no.4
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    • pp.433-437
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    • 2013
  • Electrical discharge plasma created in a multi-channel porous ceramic membrane-supported catalyst was applied to the decomposition of a volatile organic compound (VOC). For the purpose of improving the oxidation capability, the ceramic membrane used as a low-pressure drop catalyst support was loaded with zinc oxide photocatalyst by the incipient wetness impregnation method. Alternating current-driven discharge plasma was created inside the porous ceramic membrane to produce reactive species such as radicals, ozone, ions and excited molecules available for the decomposition of VOC. As the voltage supplied to the reactor increased, the plasma discharge gradually propagated in the radial direction, creating an uniform plasma in the entire ceramic membrane above a certain voltage. Ethylene was used as a model VOC. The ethylene decomposition efficiency was examined with experimental variables such as the specific energy density, inlet ethylene concentration and zinc oxide loading. When compared at the identical energy density, the decomposition efficiency obtained with the zinc oxide-loaded ceramic membrane was substantially higher than that of the bare membrane case. Both nitrogen and oxygen played an important role in initiating the decomposition of ethylene. The rate of the decomposition is governed by the quantity of reactive species generated by the plasma, and a strong dependence of the decomposition efficiency on the initial concentration was observed.

High Coulombic Efficiency Negative Electrode(SiO-Graphite) for Lithium Ion Secondary Battery (리튬이온이차전지용 고효율 음극(SiO-Graphite))

  • Shin, Hye-Min;Doh, Chil-Hoon;Kim, Dong-Hun;Kim, Hyo-Seok;Ha, Kyung-Hwa;Jin, Bong-Soo;Kim, Hyun-Soo;Moon, Seong-In;Kim, Ki-Won;Oh, Dae-Hui
    • Journal of the Korean Electrochemical Society
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    • v.11 no.1
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    • pp.47-50
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    • 2008
  • A new anode composition material comprising of SiO and Graphite has been prepared by adopting High energy ball milling (HEBM) technique. The anode material shows high initial charge and discharge capacity values of 1139 and 568 mAh/g, respectively. The electrode sustains reversible discharge capacity value of 719 mAh/g at 30th cycle with a high coulombic efficiency${\sim}99%$. Since the materials formed during initial charge process the nano silicon/$Li_4SiO_3$ and $Li_2O$ remains as interdependent, it may be expected that the composite exhibiting higher amount of irreversibility$(Li_2O)$ will deliver higher reversible capacity. In this study, constant current-constant voltage (CC-CV) charge method was employed in place of usual constant current (CC) method in order to convert efficiently all the SiO particles which resulted high initial discharge capacity at the first cycle. We improved considerably the initial discharge specific capacity of SiO/G composite by pretreatment(CC-CV).

An Improvement of the Characteristics of Pasted Cadmium Electrodes by Electrolytes in Ni/Cd Battery (Ni/Cd 전지에서 전해액에 의한 페이스트식 카드뮴 전극 특성 향상)

  • Han, Min-Young;Lee, Wan-Jin;Lee, Woo-Tai;Kim, Sun-Il;Kim, Jin-Hwan
    • Applied Chemistry for Engineering
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    • v.10 no.8
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    • pp.1192-1199
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    • 1999
  • The morphology changes of cadmium hydroxide into ${\gamma}$ phase by eletrolytes were carried out to improve the high rate charge and discharge efficiency of pasted cadmium electrodes. KOH solutions with different concentrations of NaOH were used as eletrolytes. It was found that the utilization of active material of cadmium electrode was the best in an electrolyte with 1.82 M NaOH. The amount of ${\gamma}-Cd(OH)_2$ increased in proportion to the concentration of NaOH. The surface area measurement showed that an active material which contained mainly ${\gamma}-Cd(OH)_2$ had a higher specific surface area than an active material of ${\beta}-Cd(OH)_2$. In a sealed cell, the discharge capacity was improved at high rate charge and discharge (1.0 C, 2.0 C) by using an electrolyte with NaOH. Furthermore, these improved performances were maintained up to 500 cycles at 1.0 C rate charge and discharge cycles.

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