• Fire Science and Engineering
• /
• v.28 no.6
• /
• pp.108-113
• /
• 2014

The combined process of Sliding Arc Plasma and corona dielectric barrier discharge process (CDBD) was used to efficiently improve harmful substance, which convert into OH radicals which have strong oxidation potential, and so have deodorization and sterilizing effects, by generating specific radicals and anion and then reacting with the moisture contained in harmful substance. As a result of experiment, even if the size of SAP reactor is reduced from 80 A to 50 A, there is no much change and therefore it is judged the size of reactor may be minimized. And it was confirmed that after the anion and ozone generated from CDBD rector react with harmful substance, a anion was reduced from 510,000 ppb to 470 ppb and ozone from 98 ppb to 22 ppb. It was also judged the stability and durability of plasma producer are excellent. Accordingly, it is considered the harmful substances which exist in indoor air quality will be efficiently improved and removed by using further plasma combined process through this study.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2011.02a
• /
• pp.409-409
• /
• 2011

All solid-state thin film lithium batteries have many applications in miniaturized devices because of lightweight, long-life, low self-discharge and high energy density. The research of cathode materials for thin film lithium batteries that provide high energy density at fast discharge rates is important to meet the demands for high-power applications. Among cathode materials, lithium manganese oxide materials as spinel-based compounds have been reported to possess specific advantages of high electrochemical potential, high abundant, low cost, and low toxicity. However, the lithium manganese oxide has problem of capacity fade which caused by dissolution of Mn ions during intercalation reaction and phase instability. For this problem, many studies on effect of various transition metals have been reported. In the preliminary study, the Sn-substituted LiMn2O4 thin films prepared by pulsed laser deposition have shown the improvement in discharge capacity and cycleability. In this study, the thin films of LiMn2O4 and LiSn0.0125Mn1.975O4 prepared by RF magnetron sputtering were studied with effect of deposition parameters on the phase, surface morphology and electrochemical property. And, all solid-state thin film batteries comprised of a lithium anode, lithium phosphorus oxy-nitride (LiPON) solid electrolyte and LiMn2O4-based cathode were fabricated, and the electrochemical property was investigated.

• Journal of the Korean institute of surface engineering
• /
• v.42 no.3
• /
• pp.133-138
• /
• 2009

Effects of bipolar pulse driving frequency between 50 kHz and 250 kHz on the discharge shapes were analyzed by measuring plasma characteristics by OES (Optical Emission Spectroscopy) and Langmuir probe. Plasma characteristics were modeled by a simple electric field analysis and fluid plasma modeling. Discharge shapes by a continuous dc and bipolar pulsed dc were different as a dome-type and a vertical column-type at the cathode. From OES, the intensity of 811.5 nm wavelength, the one of the main peaks of Ar, decreased to about 43% from a continuous dc to 100 kHz. For increasing from 100 kHz to 250 kHz, the intensity of 811.5 nm wavelength also decreased by 46%. The electron density decreased by 74% and the electron temperature increased by 36% at the specific position due to the smaller and denser discharge shape for increasing pulse frequency. Through the numerical analysis, the negative glow shape of a continuous dc were similar to the electric potential distribution by FEM (Finite Element Method). For the bipolar pulsed dc, we found that the electron temperature increased to maximum 10 eV due to the voltage spikes by the fast electron acceleration generated in pre-sheath. This may induce the electrons and ions from plasma to increase the energetic substrate bombardment for the dense thin film growth.

• Journal of Powder Materials
• /
• v.19 no.3
• /
• pp.210-214
• /
• 2012

Mass production-capable $Li_2MnSiO_4$ powder was synthesized for use as cathode material in state-of-the-art lithium-ion batteries. These batteries are main powder sources for high tech-end digital electronic equipments and electric vehicles in the near future and they must possess high specific capacity and durable charge-discharge characteristics. Amorphous silicone was quite superior to crystalline one as starting material to fabricate silicone oxide with high reactivity between precursors of sol-gel type reaction intermediates. The amorphous silicone starting material also has beneficial effect of efficiently controlling secondary phases, most notably $Li_xSiO_x$. Lastly, carbon was coated on $Li_2MnSiO_4$ powders by using sucrose to afford some improved electrical conductivity. The carbon-coated $Li_2MnSiO_4$ cathode material was further characterized using SEM, XRD, and galvanostatic charge/discharge test method for morphological and electrochemical examinations. Coin cell was subject to 1.5-4.8 V at C/20, where 74 mAh/g was observed during primary discharge cycle.

• International Journal of Fluid Machinery and Systems
• /
• v.4 no.1
• /
• pp.179-190
• /
• 2011

The swirling flow developing in Francis turbine draft tube under part load operation leads to pressure fluctuations usually in the range of 0.2 to 0.4 times the runner rotational frequency resulting from the so-called vortex breakdown. For low cavitation number, the flow features a cavitation vortex rope animated with precession motion. Under given conditions, these pressure fluctuations may lead to undesirable pressure fluctuations in the entire hydraulic system and also produce active power oscillations. For the upper part load range, between 0.7 and 0.85 times the best efficiency discharge, pressure fluctuations may appear in a higher frequency range of 2 to 4 times the runner rotational speed and feature modulations with vortex rope precession. It has been pointed out that for this particular operating point, the vortex rope features elliptical cross section and is animated of a self-rotation. This paper presents an experimental investigation focusing on this peculiar phenomenon, defined as the upper part load vortex rope. The experimental investigation is carried out on a high specific speed Francis turbine scale model installed on a test rig of the EPFL Laboratory for Hydraulic Machines. The selected operating point corresponds to a discharge of 0.83 times the best efficiency discharge. Observations of the cavitation vortex carried out with high speed camera have been recorded and synchronized with pressure fluctuations measurements at the draft tube cone. First, the vortex rope self rotation frequency is evidenced and the related frequency is deduced. Then, the influence of the sigma cavitation number on vortex rope shape and pressure fluctuations is presented. The waterfall diagram of the pressure fluctuations evidences resonance effects with the hydraulic circuit. The influence of outlet bubble cavitation and air injection is also investigated for low cavitation number. The time evolution of the vortex rope volume is compared with pressure fluctuations time evolution using image processing. Finally, the influence of the Froude number on the vortex rope shape and the associated pressure fluctuations is analyzed by varying the rotational speed.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2000.07a
• /
• pp.444-447
• /
• 2000

The spinel L $i_{1-x}$ M $n_2$ $O_4$has been synthesized by the solid-state reaction. L $i_{l-x}$M $n_2$ $O_4$which includes a mixture of LiOH . $H_2O$ and Mn $O_2$prepared by preliminary heating at 35$0^{\circ}C$ for 12hr. L $i_{l-x}$M $n_2$ $O_4$fired at temperature range from 75$0^{\circ}C$ for 48hr. The structure and the electrochemical characteristics of spinel to L $i_{1-x}$ M $n_2$ $O_4$which is fabricated by changing sintering condition from starting materials are investigated. The cyclic voltammetric measurement was performed using 3 electrode cells. Electrode specific capacity and cycle life behavior were tested in a 3.0~4.2V range at a constant current density of 0.45mA/c $m^2$. To improve the cycle performance of spinel L $i_{l-x}$M $n_2$ $O_4$as the cathode of 4V class lithium secondary batteries, spinel phases L $i_{1-x}$ M $n_2$ $O_4$were Prepared at various lithium. The results showed that discharge capacity of L $i_{l-x}$M $n_2$ $O_4$varied at lithium quantity decrease with increasing lithium add quantity. The discharge capacities of L $i_{0.925}$M $n_2$ $O_4$and LiM $n_2$ $O_4$revealed 108 and 117mAh/g, respectively.spectively.y.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.25 no.5
• /
• pp.65-72
• /
• 2021

700 W class laboratory model Hall thruster, which can be used for the orbit control or station keeping of small satellites, was developed. The size of the discharge channel was determined using a scaling law, and the magnetic field was designed to be symmetric with respect to the midline of the discharge channel and to be maximized outside the discharge channel. Base pressure of a vacuum chamber was maintained below 2.0×10^-5 Torr during experiments, and the thrust was measured by a thrust stand. The anode flow rate and coil current were varied with the fixed anode voltage at 300 V. Under the operation condition at 2.36 mg/s anode flow rate and 2.4 A coil current, performance was optimized as 38 mN thrust, 1,540 s total specific impulse, and 50 % anode efficiency at 620 W anode power.

• Journal of the Korean Electrochemical Society
• /
• v.7 no.3
• /
• pp.131-137
• /
• 2004

Sol-gel method which provides better electrochemical and physiochemical properties compared to the solid-state method was used to synthesize the material of $LiFe_yMn_{2-y}O_4$. Fe was substituted to increase the structural stability so that the effects of the substitution amount and sintering temperature were analyzed. XRD was used for the structural analysis of produced material, which in turn, showed the same cubic spinel structure as $LiMn_2O_4$ despite the substitution of $Fe^{3+}$. During the synthesis of $LiFe_yMn_{2-y}O_4$, as the sintering temperature and the doping amount of Fe(y=0.05, 0.1, 0.2)were increased, grain growth proceeded which in turn, showed a high crystalline and a large grain size, certain morphology with narrow specific surface area and large pore volume distribution was observed. In order to examine the ability for the practical use of the battery, charge-discharge tests were undertaken. When the substitution amount of $Fe^{3+}\;into\;LiMn_2O_4$ increased, the initial discharge capacity showed a tendency to decrease within the region of $3.0\~4.2V$ but when charge-discharge processes were repeated, other capacity maintenance properties turned out to be outstanding. In addition, when the sintering temperature was $800\~850^{\circ}C$, the initial capacity was small but showed very stable cycle performance. According to EVS(electrochemical voltage spectroscopy) test, $LiFe_yMn_{2-y}O_4(y=0,\;0.05,\;0.1,\;0.2)$ showed two plateau region and the typical peaks of manganese spinel structure when the substitution amount of $Fe^{3+}$ increased, the peak value at about 4.15V during the charge-discharge process showed a tendency to decrease. From the previous results, the local distortion due to the biphase within the region near 4.15V during the lithium extraction gave a phase transition to a more suitable single phase. When the transition was derived, the discharge capacity decreased. However the cycle performance showed an outstanding result.

• Journal of Korea Water Resources Association
• /
• v.44 no.12
• /
• pp.991-1000
• /
• 2011

The relationship between discharge (Q) and suspended sediment (SS) concentration often is used for the estimation of inflow SS concentration in reservoir turbidity modeling in the absence of actual measurements. The power function, SS=aQb, is the most commonly used empirical relation to determine the SS load assuming the SS flux is controlled by variations of discharge. However, Q-SS relation typically is site specific and can vary depending on the season of the year. In addition, the relation sometimes shows hysteresis during rising limb and falling limb for an event hydrograph. The objective of this study was to examine the hysteresis of Q-SS relationships through continuous field measurements during flood events at inflow rivers of Yongdam Reservoir and Soyang Reservoir, and to analyze its effect on the bias of SS load estimation. The results confirmed that Q-SS relations display a high degree of scatter and clock-wise hysteresis during flood events, and higher SS concentrations were observed during rising limb than falling limb at the same discharge. The hysteresis caused significant bias and underestimation of SS loading to the reservoirs when the power function is used, which is important consideration in turbidity modeling for the reservoirs. As an alternative of Q-SS relation, turbidity-SS relation is suggested. The turbidity-SS relations showed less variations and dramatically reduced the bias with observed SS loading. Therefore, a real-time monitoring of inflow turbidity is necessary to better estimate of SS influx to the reservoirs and enhance the reliability of reservoir turbidity modeling.

• Korean Journal of Agricultural and Forest Meteorology
• /
• v.8 no.3
• /
• pp.174-182
• /
• 2006

This study was to clarify the effects of forest stand changes on hydrological components of evapotranspiration and discharge. The forest-hydrological experimental stations in Gwangneung and Yangju, Gyeonggido near metropolitan Seoul have been operated by the Korea Forest Research Institute since 1979 to clarify the effects of forest types and practices on the water resources and nutrient cycling and soil loss. The hydrological regime of the forested catchments may change as forests develop. The ranges of change may be different depending on forest types. Evapotranspiration can be estimated to 679mm, 580mm and 368mm in planted young coniferous (PYC), natural old-growth deciduous (NOD) and rehabilitated young mixed (RYM), respectively. The slope of the discharge-duration curve shows the capacity of discharge control in a specific catchment. The slope tended to be steeper in RYM than NOD, the better forest condition. The slope in RYM became more gentle as the forest stand developed. Forests can modulate peak flows through interception, evapotranspiration and soil storage opportunity. PYC and RYM showed 100 and 50mm of threshold rainfall for modulating peak flows, respectively. The deciduous forest did not represent sudden changes of peak flow rates to rainfall, even 200 mm rainfall Forest development in PYC may play an important role in modulation of peak flows because peak flow rates reduced after 10 years.